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author:

Chuai, Mingyan (Chuai, Mingyan.) [1] | Xing, Jidan (Xing, Jidan.) [2] | Zhang, Zichu (Zhang, Zichu.) [3] | Lin, Huihang (Lin, Huihang.) [4] | Chai, Guoliang (Chai, Guoliang.) [5]

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EI Scopus SCIE

Abstract:

Stair-structured Cu2-xHoxO is synthesized by gas-liquid phase chemical deposition and a subsequent heat treatment method. The UV-visible spectrum of the stair-structured Cu2O and Cu2-xHoxO exhibits strong absorption peaks in the UV region, and the Ho atom doping reduces the band gap of Cu2O. Photoluminescence spectroscopy demonstrates that the luminescence intensity of the stair-structured Cu2-xHoxO first increases with Ho addition and then decreases as the Ho3+ concentration increases further. The fluorescence lifetime curves show that the fluorescence lifetime of the stair-structured Cu2O samples is shortened by Ho3+ ion doping. Stair-structured Cu2-xHoxO exhibits distinct and stronger room-temperature ferromagnetism, and its saturation magnetization value shows a parabolic trend with the increase of Ho3+ ion doping concentration. The first-principles calculation results show that the magnetic properties of the staircase-structured Cu2O are mainly due to the splitting of spin-up and spin-down electrons near the Fermi energy. The density of states shows that the Ho atom doping contributes to the magnetism of the stair-structured Cu2-xHoxO sample, and the values of M-s of the samples can be regulated by the Ho atom doping concentration. The magnetic properties reflect a strong d-d exchange interaction between the Ho ions.

Keyword:

Community:

  • [ 1 ] [Chuai, Mingyan]Mindu Innovat Lab, Fujian Sci & Technol Innovat Lab Optoelect Inform, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Lin, Huihang]Mindu Innovat Lab, Fujian Sci & Technol Innovat Lab Optoelect Inform, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Chai, Guoliang]Mindu Innovat Lab, Fujian Sci & Technol Innovat Lab Optoelect Inform, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Chuai, Mingyan]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Lin, Huihang]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Chai, Guoliang]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [Xing, Jidan]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 8 ] [Zhang, Zichu]Chengdu Coll Arts & Sci, Coll Continuing Educ, Chengdu 610000, Sichuan, Peoples R China

Reprint 's Address:

  • [Lin, Huihang]Mindu Innovat Lab, Fujian Sci & Technol Innovat Lab Optoelect Inform, Fuzhou 350108, Fujian, Peoples R China;;[Chai, Guoliang]Mindu Innovat Lab, Fujian Sci & Technol Innovat Lab Optoelect Inform, Fuzhou 350108, Fujian, Peoples R China;;[Lin, Huihang]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China;;[Chai, Guoliang]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China;;

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Source :

CRYSTAL GROWTH & DESIGN

ISSN: 1528-7483

Year: 2024

Issue: 16

Volume: 24

Page: 6800-6808

3 . 2 0 0

JCR@2023

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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