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author:

Wu, Bo (Wu, Bo.) [1] | Zheng, Huijing (Zheng, Huijing.) [2] | Wu, Yan-Qi (Wu, Yan-Qi.) [3] | Huang, Zhicheng (Huang, Zhicheng.) [4] | Thong, Hao-Cheng (Thong, Hao-Cheng.) [5] | Tao, Hong (Tao, Hong.) [6] | Ma, Jian (Ma, Jian.) [7] | Zhao, Chunlin (Zhao, Chunlin.) [8] (Scholars:赵纯林) | Xu, Ze (Xu, Ze.) [9] | Liu, Yi-Xuan (Liu, Yi-Xuan.) [10] | Xing, Zhipeng (Xing, Zhipeng.) [11] | Liang, Naixin (Liang, Naixin.) [12] | Yao, Fang-Zhou (Yao, Fang-Zhou.) [13] | Wu, Chao-Feng (Wu, Chao-Feng.) [14] | Wang, Ke (Wang, Ke.) [15] | Han, Bing (Han, Bing.) [16]

Indexed by:

Scopus SCIE

Abstract:

Despite the pivotal role of stannum doping in achieving ultrahigh piezoelectric performance in barium titanate-based ceramics, the fundamental mechanisms underlying this enhancement remain elusive. Here, we introduce a single variable nonstoichiometric stannum strategy in lead-free barium titanate-based ceramics with giant piezoelectricity, revealing that stannum doping contributes intrinsically and extrinsically to enhance piezoelectricity. Density functional theory calculations elucidate the intrinsic enhancement of polarization arising from lattice distortion and increased space for titanium-oxygen bonds induced by optimal stannum doping, which is corroborated by Rayleigh analysis. A phase transition from ferroelectric multiphase coexistence to paraelectric phase is observed, alongside a rapid miniaturized and eventually disappeared domains with increasing stannum doping. This evolution in phase structure and domain configuration induces a nearly vanishing polarization anisotropy and low domain wall energy, facilitating easy polarization rotation and domain wall motion, thereby significantly contributing to the extrinsic piezoelectric response. Consequently, the origins of ultrahigh performance can be attributed to the synergistic effect of stannum-induced intrinsic and extrinsic contributions in barium titanate-based ceramics. This study provides fundamental insights into the role of doping elements and offers guidance for the design of high-performance piezoelectrics. The mechanisms of the enhancement of stannum doping in achieving high piezoelectric performance in barium titanate-based ferroelectric ceramics remain elusive. Here, the authors introduce a single variable nonstoichiometric stannum strategy to reveal the intrinsic and extrinsic contributions for enhancing piezoelectricity after stannum doping.

Keyword:

Community:

  • [ 1 ] [Wu, Bo]Southwest Minzu Univ, Sichuan Prov Key Lab Informat Mat, Sichuan Zoige Alpine Wetland Ecosyst Natl Observat, Chengdu, Peoples R China
  • [ 2 ] [Zheng, Huijing]Southwest Minzu Univ, Sichuan Prov Key Lab Informat Mat, Sichuan Zoige Alpine Wetland Ecosyst Natl Observat, Chengdu, Peoples R China
  • [ 3 ] [Tao, Hong]Southwest Minzu Univ, Sichuan Prov Key Lab Informat Mat, Sichuan Zoige Alpine Wetland Ecosyst Natl Observat, Chengdu, Peoples R China
  • [ 4 ] [Ma, Jian]Southwest Minzu Univ, Sichuan Prov Key Lab Informat Mat, Sichuan Zoige Alpine Wetland Ecosyst Natl Observat, Chengdu, Peoples R China
  • [ 5 ] [Wu, Bo]Tsinghua Univ, Sch Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing, Peoples R China
  • [ 6 ] [Wu, Yan-Qi]Tsinghua Univ, Sch Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing, Peoples R China
  • [ 7 ] [Thong, Hao-Cheng]Tsinghua Univ, Sch Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing, Peoples R China
  • [ 8 ] [Xu, Ze]Tsinghua Univ, Sch Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing, Peoples R China
  • [ 9 ] [Liu, Yi-Xuan]Tsinghua Univ, Sch Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing, Peoples R China
  • [ 10 ] [Xing, Zhipeng]Tsinghua Univ, Sch Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing, Peoples R China
  • [ 11 ] [Wang, Ke]Tsinghua Univ, Sch Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing, Peoples R China
  • [ 12 ] [Huang, Zhicheng]Peking Union Med Coll & Chinese Acad Med Sci, Peking Union Med Coll Hosp, Dept Thorac Surg, Beijing, Peoples R China
  • [ 13 ] [Liang, Naixin]Peking Union Med Coll & Chinese Acad Med Sci, Peking Union Med Coll Hosp, Dept Thorac Surg, Beijing, Peoples R China
  • [ 14 ] [Zhao, Chunlin]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou, Peoples R China
  • [ 15 ] [Yao, Fang-Zhou]Wuzhen Lab, Res Ctr Adv Funct Ceram, Jiaxing, Peoples R China
  • [ 16 ] [Wu, Chao-Feng]Tsinghua Univ, Ctr Adv Ceram Mat & Devices, Yangtze Delta Reg Inst, Jiaxing, Zhejiang, Peoples R China
  • [ 17 ] [Han, Bing]Peking Univ Sch & Hosp Stomatol, Dept Orthodont, Beijing, Peoples R China

Reprint 's Address:

  • [Zhao, Chunlin]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou, Peoples R China;;[Yao, Fang-Zhou]Wuzhen Lab, Res Ctr Adv Funct Ceram, Jiaxing, Peoples R China;;[Han, Bing]Peking Univ Sch & Hosp Stomatol, Dept Orthodont, Beijing, Peoples R China;;

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Source :

NATURE COMMUNICATIONS

Year: 2024

Issue: 1

Volume: 15

1 4 . 7 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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