Hypervalent iodine catalysis enabled iterative multi-fluorination: not just a simple alternative for the electrochemical approach - Details

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Ding, C.-L. (Ding, C.-L..) ^[1] | Li, H. (Li, H..) ^[2] | Zhong, Y. (Zhong, Y..) ^[3] | Lin, Y. (Lin, Y..) ^[4] | Ye, K.-Y. (Ye, K.-Y..) ^[5]

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Abstract：

Unlike　the　well-established　fluoroalkylation,　the　direct　incorporation　of　multiple　fluorine　atoms　into　small　molecules　via　iterative　fluorinations　has　been　much　less　investigated.　Herein,　we　report　a　hypervalent　iodine　catalytically　selective　multi-fluorination　in　which　the　fluorination　degree　is　controlled　by　the　delicate　balance　between　the　HF/amine　ratios.　The　pros　and　cons　of　hypervalent　iodine　catalysis　and　the　previously　established　electrochemical　approach　in　the　iterative　multi-fluorinations　are　also　provided.　©　2024　The　Royal　Society　of　Chemistry.

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[ 1 ] [Ding C.-L.]Key Laboratory of Molecule Synthesis and Function Discovery, Fujian Province University, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 2 ] [Li H.]Key Laboratory of Molecule Synthesis and Function Discovery, Fujian Province University, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 3 ] [Zhong Y.]Key Laboratory of Molecule Synthesis and Function Discovery, Fujian Province University, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 4 ] [Lin Y.]Key Laboratory of Molecule Synthesis and Function Discovery, Fujian Province University, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 5 ] [Ye K.-Y.]Key Laboratory of Molecule Synthesis and Function Discovery, Fujian Province University, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 6 ] [Ye K.-Y.]School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, 453007, China

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Chemical Communications

ISSN： 1359-7345

Year： 2024

Issue： 93

Volume： 60

Page： 13738-13741

4 . 3 0 0

JCR@2023

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