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author:

Xuying Yu (Xuying Yu.) [1] | Jiarong Mi (Jiarong Mi.) [2] | Yulan Han (Yulan Han.) [3] | Cai Sun (Cai Sun.) [4] (Scholars:孙财) | Mingsheng Wang (Mingsheng Wang.) [5] | Guocong Guo (Guocong Guo.) [6]

Abstract:

Direct X-ray detectors,which directly convert X-rays into electrical signals through semiconductors,have higher space solution than scintillator-mediated indirect X-ray ones and are high desirable for early cancer detection and other applications,but the mainstream commercial α-Se detector is still largely limited by high production costs,large leakage current and low stability.This article reports an eas-ily prepared,stable radiochromic semiconductive metal-organic framework(MOF),(MV)[Cd3(tdc)4]-2H2O(RCS-1,H2tdc=2,5-thiophenedicarboxylic acid;MV2+=methyl viologen cation)with direct X-ray de-tecting ability.With a large bulk resistivity of 8.40 × 109 Ω cm,this material ensures minimal dark current and low noise for X-ray detection.Additionally,it exhibits higher sensitivity to W Kα X-rays(98.58 μC Gy-1 cm-2)than α-Se(~20 μC Gy-1 cm-2).Meanwhile,unlike most reported direct X-ray de-tecting semiconductors,compound RCS-1 shows remarkable color change upon X-ray irradiation owing to the presence of photochromism-active viologen cations.This feature offers an appealing visual detecting ability to direct X-ray detectors that provide only the electrical signals.

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  • [ 1 ] [Mingsheng Wang]State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350608,China
  • [ 2 ] [Guocong Guo]State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350608,China
  • [ 3 ] [Cai Sun]福州大学
  • [ 4 ] [Jiarong Mi]State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350608,China;College of Chemistry,Fuzhou University,Fuzhou 350108,China
  • [ 5 ] [Xuying Yu]State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350608,China;University of Chinese Academy of Sciences,Beijing 100049,China
  • [ 6 ] [Yulan Han]贝尔法斯特女王大学

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Source :

中国化学快报(英文版)

ISSN: 1001-8417

Year: 2024

Issue: 9

Volume: 35

Page: 437-441

9 . 4 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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