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author:

Miao, Rongbin (Miao, Rongbin.) [1] | Niu, Qing (Niu, Qing.) [2] | Li, Liuyi (Li, Liuyi.) [3] (Scholars:李留义) | Yu, Yan (Yu, Yan.) [4] (Scholars:于岩)

Indexed by:

EI Scopus SCIE

Abstract:

Metal complex-based photocatalysts are promising for CO2 reduction. Their catalytic performances greatly rely on the synergy of ligands and metal ions. Here, we demonstrate an assembly of covalent organic cage (COC) and metal ions for photocatalytic CO2 reduction. The coordinated metal serves as catalytically active site for CO2 reduction, while the cage not only chelates the metal site, but also enhances the local concentration of CO2 around metal site, and decreases the key intermediate reaction energy barrier, thereby promoting the CO2 reduction reaction kinetically and thermodynamically. Accordingly, a Ni metalized COC exhibited outstanding photocatalytic performance in CO2-to-CO conversion under visible light irradiation. This study highlights the feasibility and advantage of organic cages for the construction of photocatalysts for artificial photosynthesis.

Keyword:

CO2 reduction Covalent organic cages Metal complex Metallization Photocatalysis

Community:

  • [ 1 ] [Miao, Rongbin]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Ecomat Adv Technol, Fuzhou 350108, Peoples R China
  • [ 2 ] [Niu, Qing]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Ecomat Adv Technol, Fuzhou 350108, Peoples R China
  • [ 3 ] [Li, Liuyi]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Ecomat Adv Technol, Fuzhou 350108, Peoples R China
  • [ 4 ] [Yu, Yan]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Ecomat Adv Technol, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • 李留义

    [Li, Liuyi]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Ecomat Adv Technol, Fuzhou 350108, Peoples R China

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Source :

CHEMSUSCHEM

ISSN: 1864-5631

Year: 2024

Issue: 5

Volume: 18

7 . 5 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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