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author:

Xia, Yuzhou (Xia, Yuzhou.) [1] | Xiao, Jilong (Xiao, Jilong.) [2] | Zhang, Jiacheng (Zhang, Jiacheng.) [3] | Huang, Renkun (Huang, Renkun.) [4] | Huang, Xiaohui (Huang, Xiaohui.) [5] | Yan, Guiyang (Yan, Guiyang.) [6] | Zheng, Liuping (Zheng, Liuping.) [7]

Indexed by:

EI Scopus SCIE

Abstract:

The construction of step-scheme (S-scheme) heterojunction has become an effective strategy for enhancing photocatalytic CO2 reduction. In this study, a sunflower-like S-scheme WO3/ZnIn2S4 heterostructure is fabricated through the in-situ growth of ZnIn2S4 nanosheets on WO3 hollow sphere, aimed at improving selective CO2 reduction. The constructed embedding configuration, featuring a WO3 hollow sphere core and an outer layer of ZnIn2S4 nanosheet, increases the contact interface and establishes a significant built-in electric field, thereby promoting the migration and separation of photogenerated carriers. The confined internal cavity of the threedimensional (3D) sunflower-like architecture aids in limiting the free diffusion of CO2, and enriching CO2 molecules at the surface of the photocatalyst, consequently enhancing reaction kinetics. Moreover, S vacancies on ZnIn2S4 nanosheets promote the chemisorption and activation of CO2. As a result, the optimized evolution rates for CH4 and CO of 58.7 mu mol g-1h- 1 and 51.3 mu mol g-1h- 1, respectively, are achieved for WO3/ZnIn2S4 heterojunction. The corresponding electron selectivity for CH4 reaches 82.1 %, which is 13 and 1.5 times higher than those of bare WO3 and ZnIn2S4, respectively. This provides valuable insights into the design of muti-functionalized S-scheme heterojunction photocatalysts.

Keyword:

Photocatalytic CO2 reduction S-scheme heterojunction Sunflower-like structure WO3

Community:

  • [ 1 ] [Xia, Yuzhou]Ningde Normal Univ, Fujian Prov Key Lab Featured Biochem & Chem Mat, Ningde 352100, Fujian, Peoples R China
  • [ 2 ] [Zhang, Jiacheng]Ningde Normal Univ, Fujian Prov Key Lab Featured Biochem & Chem Mat, Ningde 352100, Fujian, Peoples R China
  • [ 3 ] [Huang, Renkun]Ningde Normal Univ, Fujian Prov Key Lab Featured Biochem & Chem Mat, Ningde 352100, Fujian, Peoples R China
  • [ 4 ] [Huang, Xiaohui]Ningde Normal Univ, Fujian Prov Key Lab Featured Biochem & Chem Mat, Ningde 352100, Fujian, Peoples R China
  • [ 5 ] [Yan, Guiyang]Ningde Normal Univ, Fujian Prov Key Lab Featured Biochem & Chem Mat, Ningde 352100, Fujian, Peoples R China
  • [ 6 ] [Xia, Yuzhou]Xiamen Ocean Vocat Coll, Xiamen Key Lab Intelligent Fishery, Xiamen 361100, Fujian, Peoples R China
  • [ 7 ] [Xiao, Jilong]Fuzhou Univ, Coll Chem, Fuzhou 350116, Fujian, Peoples R China
  • [ 8 ] [Zheng, Liuping]Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350007, Peoples R China

Reprint 's Address:

  • [Huang, Renkun]Ningde Normal Univ, Fujian Prov Key Lab Featured Biochem & Chem Mat, Ningde 352100, Fujian, Peoples R China;;[Huang, Xiaohui]Ningde Normal Univ, Fujian Prov Key Lab Featured Biochem & Chem Mat, Ningde 352100, Fujian, Peoples R China;;[Zheng, Liuping]Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350007, Peoples R China

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Source :

FUEL

ISSN: 0016-2361

Year: 2024

Volume: 382

6 . 7 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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