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author:

Liu, Jin (Liu, Jin.) [1] | Hu, Cong (Hu, Cong.) [2] | Meng, Xiaoyan (Meng, Xiaoyan.) [3] | Sun, Ying (Sun, Ying.) [4] | Zhao, Bo (Zhao, Bo.) [5] | Lin, Zian (Lin, Zian.) [6]

Indexed by:

EI Scopus SCIE

Abstract:

Phenolic compounds are a kind of persistent organic pollutants (POPs), which are always a threat to human and environment due to their strong toxicity and low biodegradability. Therefore, developing a reliable method to simultaneously detect phenolic pollutants is of great importance to environmental safety and human health. Herein, we combined the advantages of metal organic frameworks (MOFs) and covalent organic frameworks (COFs) to prepare two cyclic trinuclear unit-based metal covalent organic framework (MCOFs, denoted as Cu3- TDH COF and Cu3-BDU COF) with large specific surface area, good stability and excellent laccase-like activity. Their oxidative degradation ability toward phenolic pollutants was verified, and a dual-channel nanozyme sensor array based on Cu3-TDH COF and Cu3-BDU COF was constructed for the identification of six phenolic pollutants. Notably, the sensor array can accurately distinguish between different concentrations of phenolic pollutants and different types of phenolic pollutants at the same concentration, even at levels as low as 1 mu M. Moreover, three real water samples (rainwater, tap water and wastewater) and 18 unknown samples were also distinguished and differentiated by the sensor array. This study opens up a potential avenue for the design of MCOFs-based nanozyme sensor arrays to simultaneously realize identification and detection of multiple phenolic pollutants.

Keyword:

Catalytic oxidation Laccase-like nanozymes Metal covalent organic frameworks Phenolic pollutants Sensor array

Community:

  • [ 1 ] [Liu, Jin]Fuzhou Univ, Coll Chem, Minist Educ,Key Lab Analyt Sci Food Safety & Biol, Fujian Prov Key Lab Anal & Detect Technol Food Saf, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Hu, Cong]Fuzhou Univ, Coll Chem, Minist Educ,Key Lab Analyt Sci Food Safety & Biol, Fujian Prov Key Lab Anal & Detect Technol Food Saf, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Meng, Xiaoyan]Fuzhou Univ, Coll Chem, Minist Educ,Key Lab Analyt Sci Food Safety & Biol, Fujian Prov Key Lab Anal & Detect Technol Food Saf, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Sun, Ying]Fuzhou Univ, Coll Chem, Minist Educ,Key Lab Analyt Sci Food Safety & Biol, Fujian Prov Key Lab Anal & Detect Technol Food Saf, Fuzhou 350108, Fujian, Peoples R China
  • [ 5 ] [Zhao, Bo]Fuzhou Univ, Coll Chem, Minist Educ,Key Lab Analyt Sci Food Safety & Biol, Fujian Prov Key Lab Anal & Detect Technol Food Saf, Fuzhou 350108, Fujian, Peoples R China
  • [ 6 ] [Lin, Zian]Fuzhou Univ, Coll Chem, Minist Educ,Key Lab Analyt Sci Food Safety & Biol, Fujian Prov Key Lab Anal & Detect Technol Food Saf, Fuzhou 350108, Fujian, Peoples R China

Reprint 's Address:

  • [Lin, Zian]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China

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Source :

JOURNAL OF HAZARDOUS MATERIALS

ISSN: 0304-3894

Year: 2025

Volume: 487

1 2 . 2 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 9

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