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author:

Wu, Lizhi (Wu, Lizhi.) [1] (Scholars:吴立志) | Zhang, Ying (Zhang, Ying.) [2] | Zou, Caixin (Zou, Caixin.) [3] | Sun, Qin (Sun, Qin.) [4] | Li, Baozhen (Li, Baozhen.) [5] | Zheng, Wenchun (Zheng, Wenchun.) [6] | Liu, Jiamin (Liu, Jiamin.) [7] | He, Juncheng (He, Juncheng.) [8] | Tang, Yu (Tang, Yu.) [9] (Scholars:汤禹) | Tan, Li (Tan, Li.) [10] (Scholars:谭理)

Indexed by:

Scopus SCIE

Abstract:

Ethane dehydrogenation to aromatics (EDA) is one of the most promising routes to produce aromatics. Herein, the tandem of dehydrogenation component and acidic zeolite are prepared and investigated for EDA. Pt/Fe-S-1 coupled with ZSM-5 of Si/Al of 14 via mixing homogeneously shows excellent EDA performance with 54.0% ethane conversion, 61.5% aromatics selectivity as well as a deactivation rate constant of 0.00010 h-1. According to catalysts characterizations and controlled experiments, it is confirmed the highly dispersed positive Pt delta+ species around Fe species over Pt/Fe-S-1 is the active sites for ethane dehydrogenation to ethylene and subsequent naphthenes dehydrogenation to aromatics, Br & oslash;nsted acid sites of ZSM-5 and MFI pore are responsible for ethylene oligomerization and cyclization to naphthenes and further naphthenes dehydrogenation to aromatics. The short spatial space between dehydrogenation active sites and acid sites is beneficial for EDA. And the ethylene generation rate is the rate-determining step of EDA.

Keyword:

dehydroaromatization Pt/Fe-S-1 the tandem catalysis ZSM-5

Community:

  • [ 1 ] [Wu, Lizhi]Fuzhou Univ, Coll Chem, Inst Mol Catalysis & In Situ Operando Studies, Fuzhou 350108, Peoples R China
  • [ 2 ] [Zhang, Ying]Fuzhou Univ, Coll Chem, Inst Mol Catalysis & In Situ Operando Studies, Fuzhou 350108, Peoples R China
  • [ 3 ] [Zou, Caixin]Fuzhou Univ, Coll Chem, Inst Mol Catalysis & In Situ Operando Studies, Fuzhou 350108, Peoples R China
  • [ 4 ] [Sun, Qin]Fuzhou Univ, Coll Chem, Inst Mol Catalysis & In Situ Operando Studies, Fuzhou 350108, Peoples R China
  • [ 5 ] [Li, Baozhen]Fuzhou Univ, Coll Chem, Inst Mol Catalysis & In Situ Operando Studies, Fuzhou 350108, Peoples R China
  • [ 6 ] [Zheng, Wenchun]Fuzhou Univ, Coll Chem, Inst Mol Catalysis & In Situ Operando Studies, Fuzhou 350108, Peoples R China
  • [ 7 ] [Liu, Jiamin]Fuzhou Univ, Coll Chem, Inst Mol Catalysis & In Situ Operando Studies, Fuzhou 350108, Peoples R China
  • [ 8 ] [He, Juncheng]Fuzhou Univ, Coll Chem, Inst Mol Catalysis & In Situ Operando Studies, Fuzhou 350108, Peoples R China
  • [ 9 ] [Tang, Yu]Fuzhou Univ, Coll Chem, Inst Mol Catalysis & In Situ Operando Studies, Fuzhou 350108, Peoples R China
  • [ 10 ] [Tan, Li]Fuzhou Univ, Coll Chem, Inst Mol Catalysis & In Situ Operando Studies, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • 吴立志 谭理

    [Wu, Lizhi]Fuzhou Univ, Coll Chem, Inst Mol Catalysis & In Situ Operando Studies, Fuzhou 350108, Peoples R China;;[Tan, Li]Fuzhou Univ, Coll Chem, Inst Mol Catalysis & In Situ Operando Studies, Fuzhou 350108, Peoples R China

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Source :

AICHE JOURNAL

ISSN: 0001-1541

Year: 2025

Issue: 5

Volume: 71

3 . 5 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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