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Lanthanum (La) adsorbents are highly effective for phosphorus removal but are constrained by their high reagent cost because of their La content. By exploiting the similarity in ionic sizes between Ca2+ and La3+, we develop a low-cost composite adsorbent LCCa-5@Dia by doping La2(CO3)3 & sdot;8H2O with Ca2+. Our results indicate that the slow addition of NaHCO3 during the synthetic process facilitates the incorporation of Ca2+ into the La2(CO3)3 & sdot;8H2O lattice, leading to an adsorption behavior nearly identical to that of the undoped adsorbents. LCCa-5@Dia demonstrates a high adsorption capacity of 60.04 mg P/g, with stable performance across a pH range of 3 to 11. Its adsorption property also exhibits excellent stability under the interference of solution pH and competing ions. Materials characterization reveals that the adsorption occurs through electrostatic attraction and ligand exchange. In continuous column-adsorption experiments, the LCCa-5@Dia adsorbent treats up to 4000 bed volumes of simulated low concentration wastewater (1.7-2.7 mg P/L). This translates to a treatment cost as low as $0.0211/m3. Meanwhile, the adsorbent also maintains over 80 % of the adsorption capacity after three regeneration cycles. The excellent performance and low treatment cost of the calcium-doped lanthanum carbonate adsorbents highlight its practical potential in treating low concentration wastewater.
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SEPARATION AND PURIFICATION TECHNOLOGY
ISSN: 1383-5866
Year: 2025
Volume: 360
8 . 2 0 0
JCR@2023
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 6
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