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author:

Huang, Jiongyuan (Huang, Jiongyuan.) [1] | Chen, Zhiyi (Chen, Zhiyi.) [2] | Luo, Yujie (Luo, Yujie.) [3] | Ai, Na (Ai, Na.) [4] | Jiang, Sanping (Jiang, Sanping.) [5] | Chen, Kongfa (Chen, Kongfa.) [6]

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Abstract:

Solid oxide cells (SOCs) are emerging devices for efficient energy storage and conversion. However, during SOC operation, gaseous chromium (Cr) species released from Fe-Cr alloy interconnect can lead to Cr deposition and poisoning of air electrodes, causing substantial degradation in electrochemical performance and compromising the longterm stability of SOCs. This mini-review examines the mechanism of Cr deposition and poisoning in air electrodes under both fuel-cell and electrolysis modes. Furthermore, emphasis is placed on the recent advancements in strategies to mitigate Cr poisoning, offering insights into the rational design and development of active and Cr-tolerant air electrodes for SOCs. © 2025 Science Press. All rights reserved.

Keyword:

Chromium metallography Chromium metallurgy Electrochemical electrodes Electrolysis Hard facing Iron alloys Lead alloys

Community:

  • [ 1 ] [Huang, Jiongyuan]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 2 ] [Chen, Zhiyi]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 3 ] [Luo, Yujie]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 4 ] [Ai, Na]Fujian College Association Instrumental Analysis Center, Fuzhou University, Fuzhou; 350108, China
  • [ 5 ] [Jiang, Sanping]National Energy Key Laboratory for New Hydrogen-Ammonia Energy Technologies & Foshan Xianhu Laboratory, Foshan; 528216, China
  • [ 6 ] [Jiang, Sanping]WA School of Mines: Minerals, Energy and Chemical Engineering, Curtin University, Perth; WA; 6102, Australia
  • [ 7 ] [Chen, Kongfa]College of Materials Science and Engineering, Fuzhou University, Fuzhou; 350108, China

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Source :

Journal of Fuel Chemistry and Technology

ISSN: 2097-213X

Year: 2025

Issue: 2

Volume: 53

Page: 249-261

Cited Count:

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ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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