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author:

Lin, Y. (Lin, Y..) [1] | Dong, G. (Dong, G..) [2] | Lin, H. (Lin, H..) [3] | Wang, B. (Wang, B..) [4] | Wang, P. (Wang, P..) [5] | Xu, J. (Xu, J..) [6] | Cheng, Y. (Cheng, Y..) [7] | Xiong, Y. (Xiong, Y..) [8] | Wang, Y. (Wang, Y..) [9]

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Abstract:

The rise of laser diode (LD)-driven phosphor-converted near-infrared (NIR) lighting sources, offering unparalleled advantages in terms of brightness and imaging resolution, is hindered by a scarcity of color converters possessing desired properties. Herein, we synthesized a new Ca2YScAl2Si2O12:Cr3+ (CYSAS:Cr3+) broadband NIR-emissive garnet phosphor with a full width at half maximum (FWHM) of 165 nm, attributed to the presence of Cr3+ ions at two distinct crystallographic sites in CYSAS as verified through spectroscopic analyses. With the aid of a rapid infrared firing technique pioneered in our lab, a phosphor-in-glass film (PiGF) composite was then successfully sintered onto a sapphire plate (SP), showing minimal interfacial reactions during co-sintering and thus retention of luminescent properties. The saturation behavior of luminescence under intense blue laser irradiation was meticulously examined across different excitation modes. By incorporating a “phosphor wheel”, we achieved a peak NIR output power of 2626 mW (@17 W or 21.7 W mm−2), surpassing the majority of previously reported phosphor-converted lighting sources. The demonstration experiments highlighted the potential applications of the engineered laser-driven NIR light source in non-destructive detection, quantitative analysis of organic components, night vision and biological imaging. © 2025 The Royal Society of Chemistry.

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  • [ 1 ] [Lin Y.]College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350002, China
  • [ 2 ] [Lin Y.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 3 ] [Dong G.]College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350002, China
  • [ 4 ] [Dong G.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 5 ] [Lin H.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 6 ] [Lin H.]Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 7 ] [Wang B.]School of Applied Physics and Materials, Wuyi University, Guangdong, Jiangmen, 529020, China
  • [ 8 ] [Wang P.]Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 9 ] [Xu J.]Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 10 ] [Cheng Y.]Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 11 ] [Xiong Y.]Hubei Provincial Key Laboratory of Green Materials for Light Industry, Hubei University of Technology, Hubei, Wuhan, 430068, China
  • [ 12 ] [Wang Y.]Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China

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Source :

Journal of Materials Chemistry C

ISSN: 2050-7526

Year: 2025

Issue: 8

Volume: 13

Page: 4020-4030

5 . 7 0 0

JCR@2023

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ESI Highly Cited Papers on the List: 0 Unfold All

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