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author:

Xin, Jiafan (Xin, Jiafan.) [1] | Xie, Mingyu (Xie, Mingyu.) [2] | Lu, Hanwei (Lu, Hanwei.) [3] | Ye, Hebo (Ye, Hebo.) [4] | You, Lei (You, Lei.) [5]

Indexed by:

Scopus SCIE

Abstract:

Gated photoswitching systems, which enable control over photochromic properties, play an important role in chemistry. Here, we present a novel gated system based on extended unsaturated 1,3-dicarbonyl derivatives of diarylethenes by manipulating keto-enol tautomerism. While the intramolecular charge transfer process blocked the photochromism, the creation of an ester enabled efficient bidirectional photoswitching. The use of acid/base further induced a shift of the keto-enol equilibrium. Finally, switchable multistep gating control of the photochrome was achieved, enhancing the complexity.

Keyword:

Community:

  • [ 1 ] [Xin, Jiafan]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 2 ] [Xie, Mingyu]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 3 ] [You, Lei]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 4 ] [Xin, Jiafan]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 5 ] [Xie, Mingyu]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 6 ] [Lu, Hanwei]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 7 ] [Ye, Hebo]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 8 ] [You, Lei]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 9 ] [Xin, Jiafan]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Peoples R China
  • [ 10 ] [Xie, Mingyu]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Peoples R China
  • [ 11 ] [You, Lei]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • [You, Lei]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China;;[Lu, Hanwei]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China;;[Ye, Hebo]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China;;[You, Lei]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China;;[You, Lei]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Peoples R China

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Source :

ORGANIC LETTERS

ISSN: 1523-7060

Year: 2025

Issue: 9

Volume: 27

Page: 2174-2179

4 . 9 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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