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Abstract:
Gated photoswitching systems, which enable control over photochromic properties, play an important role in chemistry. Here, we present a novel gated system based on extended unsaturated 1,3-dicarbonyl derivatives of diarylethenes by manipulating keto-enol tautomerism. While the intramolecular charge transfer process blocked the photochromism, the creation of an ester enabled efficient bidirectional photoswitching. The use of acid/base further induced a shift of the keto-enol equilibrium. Finally, switchable multistep gating control of the photochrome was achieved, enhancing the complexity.
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ORGANIC LETTERS
ISSN: 1523-7060
Year: 2025
Issue: 9
Volume: 27
Page: 2174-2179
4 . 9 0 0
JCR@2023
Cited Count:
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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