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author:

Jia, Pingshan (Jia, Pingshan.) [1] | Guo, Junpo (Guo, Junpo.) [2] | Li, Qing (Li, Qing.) [3] | Liu, Yinan (Liu, Yinan.) [4] | Zheng, Yun (Zheng, Yun.) [5] | Guo, Yan (Guo, Yan.) [6] | Huang, Yike (Huang, Yike.) [7] | Shen, Yingying (Shen, Yingying.) [8] | Long, Lifen (Long, Lifen.) [9] | Zhang, Hebin (Zhang, Hebin.) [10] | Chen, Rong (Chen, Rong.) [11] | Zhang, Congcong (Zhang, Congcong.) [12] | Zhang, Zhiyuan (Zhang, Zhiyuan.) [13] | Shen, Jingjun (Shen, Jingjun.) [14] | Dong, Shengyang (Dong, Shengyang.) [15] | Jiang, Jiangmin (Jiang, Jiangmin.) [16] | Chang, Meinan (Chang, Meinan.) [17] | Liu, Xupo (Liu, Xupo.) [18] | Wang, Xiaobing (Wang, Xiaobing.) [19] | Tang, Yuxin (Tang, Yuxin.) [20] | Shao, Huaiyu (Shao, Huaiyu.) [21]

Indexed by:

EI Scopus SCIE

Abstract:

The successive introduction of silicon (Si) graphite composite anodes into the global market highlights the tremendous commercial potential of Si anodes. Good kinetic performance related to fast charging capability is the central topic of next-generation Si anodes. However, there is a lack of critical reviews exploring the fundamental limiting factors affecting the kinetics of Si and evaluating the effectiveness of the current strategies. In this review, we deconstruct the particle-interface-electrode integration to analyze key limiting factors of kinetics from a practical application perspective for the first time, including long Li+ diffusion distance and poor conductivity for particles, high Li+ migration impedance at the interface, and insufficient or even interrupted Li+ diffusion paths inside the electrodes. Then, the kinetics enhancement strategies for progressively addressing the above issues are systematically investigated and the quantitative relationships between kinetics and these strategies are deeply discussed. Accordingly, the challenges in quantification and balance for fast-charging Si anodes are identified as the remaining issues, and potential solutions are provided. This review provides valuable guidance on fast-charging Si anodes and suggests promising directions in commercial-oriented Si anode studies.

Keyword:

Community:

  • [ 1 ] [Jia, Pingshan]Univ Macau, Joint Key Lab, Inst Appl Phys & Mat Engn, Minist Educ, Ave Univ, Taipa 999078, Macao, Peoples R China
  • [ 2 ] [Li, Qing]Univ Macau, Joint Key Lab, Inst Appl Phys & Mat Engn, Minist Educ, Ave Univ, Taipa 999078, Macao, Peoples R China
  • [ 3 ] [Liu, Yinan]Univ Macau, Joint Key Lab, Inst Appl Phys & Mat Engn, Minist Educ, Ave Univ, Taipa 999078, Macao, Peoples R China
  • [ 4 ] [Zheng, Yun]Univ Macau, Joint Key Lab, Inst Appl Phys & Mat Engn, Minist Educ, Ave Univ, Taipa 999078, Macao, Peoples R China
  • [ 5 ] [Guo, Yan]Univ Macau, Joint Key Lab, Inst Appl Phys & Mat Engn, Minist Educ, Ave Univ, Taipa 999078, Macao, Peoples R China
  • [ 6 ] [Huang, Yike]Univ Macau, Joint Key Lab, Inst Appl Phys & Mat Engn, Minist Educ, Ave Univ, Taipa 999078, Macao, Peoples R China
  • [ 7 ] [Shen, Yingying]Univ Macau, Joint Key Lab, Inst Appl Phys & Mat Engn, Minist Educ, Ave Univ, Taipa 999078, Macao, Peoples R China
  • [ 8 ] [Long, Lifen]Univ Macau, Joint Key Lab, Inst Appl Phys & Mat Engn, Minist Educ, Ave Univ, Taipa 999078, Macao, Peoples R China
  • [ 9 ] [Zhang, Hebin]Univ Macau, Joint Key Lab, Inst Appl Phys & Mat Engn, Minist Educ, Ave Univ, Taipa 999078, Macao, Peoples R China
  • [ 10 ] [Chen, Rong]Univ Macau, Joint Key Lab, Inst Appl Phys & Mat Engn, Minist Educ, Ave Univ, Taipa 999078, Macao, Peoples R China
  • [ 11 ] [Zhang, Congcong]Univ Macau, Joint Key Lab, Inst Appl Phys & Mat Engn, Minist Educ, Ave Univ, Taipa 999078, Macao, Peoples R China
  • [ 12 ] [Zhang, Zhiyuan]Univ Macau, Joint Key Lab, Inst Appl Phys & Mat Engn, Minist Educ, Ave Univ, Taipa 999078, Macao, Peoples R China
  • [ 13 ] [Shen, Jingjun]Univ Macau, Joint Key Lab, Inst Appl Phys & Mat Engn, Minist Educ, Ave Univ, Taipa 999078, Macao, Peoples R China
  • [ 14 ] [Dong, Shengyang]Univ Macau, Joint Key Lab, Inst Appl Phys & Mat Engn, Minist Educ, Ave Univ, Taipa 999078, Macao, Peoples R China
  • [ 15 ] [Jiang, Jiangmin]Univ Macau, Joint Key Lab, Inst Appl Phys & Mat Engn, Minist Educ, Ave Univ, Taipa 999078, Macao, Peoples R China
  • [ 16 ] [Shao, Huaiyu]Univ Macau, Joint Key Lab, Inst Appl Phys & Mat Engn, Minist Educ, Ave Univ, Taipa 999078, Macao, Peoples R China
  • [ 17 ] [Guo, Junpo]Henan Normal Univ, Collaborat Innovat Ctr Henan Prov Green Mfg Fine, Sch Chem & Chem Engn, Key Lab Green Chem Media & React,Minist Educ,Sch M, Xinxiang 453007, Henan, Peoples R China
  • [ 18 ] [Chang, Meinan]Henan Normal Univ, Collaborat Innovat Ctr Henan Prov Green Mfg Fine, Sch Chem & Chem Engn, Key Lab Green Chem Media & React,Minist Educ,Sch M, Xinxiang 453007, Henan, Peoples R China
  • [ 19 ] [Liu, Xupo]Henan Normal Univ, Collaborat Innovat Ctr Henan Prov Green Mfg Fine, Sch Chem & Chem Engn, Key Lab Green Chem Media & React,Minist Educ,Sch M, Xinxiang 453007, Henan, Peoples R China
  • [ 20 ] [Wang, Xiaobing]Henan Normal Univ, Collaborat Innovat Ctr Henan Prov Green Mfg Fine, Sch Chem & Chem Engn, Key Lab Green Chem Media & React,Minist Educ,Sch M, Xinxiang 453007, Henan, Peoples R China
  • [ 21 ] [Tang, Yuxin]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China

Reprint 's Address:

  • [Shao, Huaiyu]Univ Macau, Joint Key Lab, Inst Appl Phys & Mat Engn, Minist Educ, Ave Univ, Taipa 999078, Macao, Peoples R China

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Source :

ENERGY & ENVIRONMENTAL SCIENCE

ISSN: 1754-5692

Year: 2025

Issue: 6

Volume: 18

Page: 2720-2746

3 2 . 4 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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