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author:

Fang, Jiachen (Fang, Jiachen.) [1] | Sun, Weixiao (Sun, Weixiao.) [2] | Huang, Kuan (Huang, Kuan.) [3] | Ge, Xiaohu (Ge, Xiaohu.) [4] | Chen, Wenyao (Chen, Wenyao.) [5] | Qian, Gang (Qian, Gang.) [6] | Cao, Yueqiang (Cao, Yueqiang.) [7] | Zeng, Jianrong (Zeng, Jianrong.) [8] | Ma, Jianbo (Ma, Jianbo.) [9] | Zhou, Xinggui (Zhou, Xinggui.) [10] | Duan, Xuezhi (Duan, Xuezhi.) [11] | Zhang, Jing (Zhang, Jing.) [12] | Jiang, Lilong (Jiang, Lilong.) [13]

Indexed by:

EI Scopus SCIE

Abstract:

Second-generation biodiesel is the dominant biomass-derived liquid fuel produced from nonedible natural or waste oils and fatty acids through selective oxygen removal. Here, we developed a highly selective sulfur-free NiMo/TiO2 catalyst by disentangling electronic and geometric effects to produce second-generation biodiesel via the hydrodeoxygenation of palmitic acid-one of the most common fatty acids in these feedstocks. An unprecedented hexadecane yield of 96.0% (on a mole basis) was achieved over the Ni1Mo1/TiO2 catalyst (with a Ni:Mo ratio of similar to 1:1) at 300 degrees C and 3 MPa H2. Kinetic studies reveal that the competition between hydrodeoxygenation (C-O scission) and decarbonylation (C-C scission) of the intermediate hexadecanol is key to optimizing selectivity. Furthermore, Mo incorporation markedly lowers the apparent activation energy of hydrodeoxygenation-especially in the Ni1Mo1/TiO2 catalyst, which has the lowest Ni-Ni coordination number. Combined with catalyst characterization, these findings elucidate a Mo-induced "Ni coordination environment"-directed reaction pathway: the superb hydrodeoxygenation activity and selectivity of Ni1Mo1/TiO2 stem from its abundant NiMo interfacial sites, where Mo-induced oxygen vacancies synergize with adjacent Ni sites to facilitate the adsorption of O-containing groups and subsequent C-O bond cleavage.

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Community:

  • [ 1 ] [Fang, Jiachen]East China Univ Sci & Technol, Sch Chem Engn, State Key Lab Chem Engn, Shanghai 200237, Peoples R China
  • [ 2 ] [Sun, Weixiao]East China Univ Sci & Technol, Sch Chem Engn, State Key Lab Chem Engn, Shanghai 200237, Peoples R China
  • [ 3 ] [Ge, Xiaohu]East China Univ Sci & Technol, Sch Chem Engn, State Key Lab Chem Engn, Shanghai 200237, Peoples R China
  • [ 4 ] [Chen, Wenyao]East China Univ Sci & Technol, Sch Chem Engn, State Key Lab Chem Engn, Shanghai 200237, Peoples R China
  • [ 5 ] [Qian, Gang]East China Univ Sci & Technol, Sch Chem Engn, State Key Lab Chem Engn, Shanghai 200237, Peoples R China
  • [ 6 ] [Cao, Yueqiang]East China Univ Sci & Technol, Sch Chem Engn, State Key Lab Chem Engn, Shanghai 200237, Peoples R China
  • [ 7 ] [Zhou, Xinggui]East China Univ Sci & Technol, Sch Chem Engn, State Key Lab Chem Engn, Shanghai 200237, Peoples R China
  • [ 8 ] [Duan, Xuezhi]East China Univ Sci & Technol, Sch Chem Engn, State Key Lab Chem Engn, Shanghai 200237, Peoples R China
  • [ 9 ] [Zhang, Jing]East China Univ Sci & Technol, Sch Chem Engn, State Key Lab Chem Engn, Shanghai 200237, Peoples R China
  • [ 10 ] [Huang, Kuan]Fuzhou Univ, Coll Chem Engn, Natl Engn Res Ctr Chem Fertilizer Catalyst NERC CF, Fuzhou 350116, Peoples R China
  • [ 11 ] [Jiang, Lilong]Fuzhou Univ, Coll Chem Engn, Natl Engn Res Ctr Chem Fertilizer Catalyst NERC CF, Fuzhou 350116, Peoples R China
  • [ 12 ] [Zeng, Jianrong]Chinese Acad Sci, Shanghai Adv Res Inst, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China
  • [ 13 ] [Ma, Jianbo]Chinese Acad Sci, Shanghai Adv Res Inst, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China

Reprint 's Address:

  • [Sun, Weixiao]East China Univ Sci & Technol, Sch Chem Engn, State Key Lab Chem Engn, Shanghai 200237, Peoples R China;;[Zhang, Jing]East China Univ Sci & Technol, Sch Chem Engn, State Key Lab Chem Engn, Shanghai 200237, Peoples R China

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Source :

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

ISSN: 0888-5885

Year: 2025

Issue: 11

Volume: 64

Page: 5962-5972

3 . 8 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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