Aqueous　zinc　metal　batteries　(ZMBs)　are　regarded　as　strong　contenders　in　secondary　battery　systems　due　to　their　high　safety　and　abundant　resources.　However,　the　cycling　performance　of　the　Zn　anode　and　the　overall　performance　of　the　cells　have　often　been　hindered　by　the　formation　of　Zn　dendrites　and　the　occurrence　of　parasitic　side　reactions.　In　this　paper,　a　surface　electron　reconfiguration　strategy　is　proposed　to　optimize　the　adsorption　energy　and　migration　energy　of　Zn2+　for　a　better　Zn2+　deposition/stripping　process　by　adjusting　the　electronic　structure　of　ceric　dioxide　(CeO2)　artificial　interface　layer　with　copper　atoms　(Cu)　doped.　Both　experimental　results　and　theoretical　calculations　demonstrate　that　the　Cu2Ce7Ox　interface　facilitates　rapid　transport　of　Zn2+　due　to　the　optimized　electronic　structure　and　appropriate　electron　density,　leading　to　a　highly　reversible　and　stable　Zn　anode.　Consequently,　the　Cu2Ce7Ox@Zn　symmetric　cell　exhibits　an　overpotential　of　only　24　mV　after　stably　cycling　for　over　1600　h　at　a　current　density　of　1　mA/cm2　and　a　capacity　of　1　mAh/cm2.　Additionally,　the　cycle　life　of　Cu/Zn　asymmetric　cells　exceeds　2500　h,　with　an　average　Coulombic　efficiency　of　99.9%.　This　paper　provides　a　novel　approach　to　the　artificial　interface　layer　strategy,　offering　new　insights　for　improving　the　performance　of　ZMBs.