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author:

Hua, Yanlong (Hua, Yanlong.) [1] | Chen, Jiahui (Chen, Jiahui.) [2] | Guo, Cuiling (Guo, Cuiling.) [3] | Chen, Shan-Ci (Chen, Shan-Ci.) [4] (Scholars:陈善慈) | He, Yu (He, Yu.) [5] (Scholars:何聿) | Yang, Huanghao (Yang, Huanghao.) [6] (Scholars:杨黄浩)

Indexed by:

EI Scopus SCIE

Abstract:

In recent years, metal halide perovskites have garnered significant attention in the field of X-ray detection due to their outstanding photoelectric properties, high X-ray attenuation coefficients, and the advantage of being able to be fabricated by low-cost solution processing methods. However, a major challenge in developing perovskite X-ray detectors lies in the low quality of films produced through solution processing. In this work, we introduce an efficient method that employs a straightforward blade-coating technique to successfully prepare MAPbI3 perovskite films with a thickness of tens of microns under ambient conditions. To further improve the quality of the MAPbI3 films, we incorporate the polymer polyvinylpyrrolidone (PVP) into the perovskite precursor solution. The addition of PVP promotes crystal growth, resulting in an enlarged grain size and a more uniform arrangement within the perovskite film. This enhancement leads to a reduction in defect density and subsequent improvement in the charge collection efficiency. Consequently, the detector manufactured using the PVP-optimized film exhibits an enhanced X-ray sensitivity of 2.6 x 103 mu C Gyair-1 cm-2 and achieves a low detection limit of 11 nGyair s-1 under 10 keV X-ray energy, surpassing those achieved with the original perovskite film which measured 0.60 x 103 mu C Gyair-1 cm-2 and 139 nGyair s-1 under the same conditions. This work unlocks new prospects for the straightforward and cost-effective manufacture of high-performance X-ray detectors.

Keyword:

Community:

  • [ 1 ] [Hua, Yanlong]Fuzhou Univ, Coll Chem, Fuzhou 350002, Peoples R China
  • [ 2 ] [Guo, Cuiling]Fuzhou Univ, Coll Chem, Fuzhou 350002, Peoples R China
  • [ 3 ] [He, Yu]Fuzhou Univ, Coll Chem, Fuzhou 350002, Peoples R China
  • [ 4 ] [Yang, Huanghao]Fuzhou Univ, Coll Chem, Fuzhou 350002, Peoples R China
  • [ 5 ] [Chen, Jiahui]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Peoples R China
  • [ 6 ] [Chen, Shan-Ci]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Peoples R China
  • [ 7 ] [Yang, Huanghao]Fuzhou Univ, Coll Chem, New Cornerstone Sci Lab, MOE Key Lab Analyt Sci Food Safety & Biol, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 陈善慈 何聿

    [He, Yu]Fuzhou Univ, Coll Chem, Fuzhou 350002, Peoples R China;;[Chen, Shan-Ci]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Peoples R China

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Source :

JOURNAL OF MATERIALS CHEMISTRY C

ISSN: 2050-7526

Year: 2025

Issue: 18

Volume: 13

Page: 9365-9373

5 . 7 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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