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author:

Liu, Jianhui (Liu, Jianhui.) [1] | Wang, Lina (Wang, Lina.) [2] | Cheng, Yong (Cheng, Yong.) [3] | Huang, Minyi (Huang, Minyi.) [4] | Zhao, Longze (Zhao, Longze.) [5] | Zheng, Chenxi (Zheng, Chenxi.) [6] | Li, Wangqin (Li, Wangqin.) [7] | Gao, Haowen (Gao, Haowen.) [8] | Li, Zhao (Li, Zhao.) [9] | Wen, Zhenhai (Wen, Zhenhai.) [10] | Luo, Guangfu (Luo, Guangfu.) [11] | Gong, Zhengliang (Gong, Zhengliang.) [12] | Yang, Yong (Yang, Yong.) [13] | Wang, Ming-Sheng (Wang, Ming-Sheng.) [14]

Indexed by:

Scopus SCIE

Abstract:

Solid-state lithium metal batteries (SSLMBs) are now under intensive research for their high energy density and excellent safety. However, the Li transport limitation in Li metal anode (LMA) leads to mass/stress accumulation, dendrite initiation and void formation at the interface, which seriously hinders the development of SSLMBs. Herein, it is demonstrated through in situ electron microscopies that a mixed ionic-electronic conducting (MIEC) 3D host can promote the Li transport in LMA by increasing the diffusion pathways along the carbonaceous framework, carbon/Li interface and Li metal surface, enabling a fast and long-distance (nearly 100 mu m) diffusion of Li atoms in LMA. Consequently, the spatio-temporal sequence of Li plating/stripping can be fundamentally changed. Specifically, both deposition and dissolution can occur far away from the interface, thereby mitigating the dendrite and void issues. Impressively, the resulting cells with carbonaceous hosts can achieve excellent cyclability and the highest capacity (28.8 mAh cm(-2)) so far. This work provides valuable insight for understanding Li transport and deposition/dissolution mechanisms in MIEC host-based LMAs, and a feasible solution for tackling the interface issues without involving stack pressure in SSLMBs.

Keyword:

3D host carbonaceous framework garnet electrolyte mixed ionic-electronic conduction solid-state lithium metal batteries

Community:

  • [ 1 ] [Liu, Jianhui]Xiamen Univ, Coll Mat, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
  • [ 2 ] [Cheng, Yong]Xiamen Univ, Coll Mat, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
  • [ 3 ] [Huang, Minyi]Xiamen Univ, Coll Mat, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
  • [ 4 ] [Li, Wangqin]Xiamen Univ, Coll Mat, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
  • [ 5 ] [Gao, Haowen]Xiamen Univ, Coll Mat, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
  • [ 6 ] [Li, Zhao]Xiamen Univ, Coll Mat, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
  • [ 7 ] [Wang, Ming-Sheng]Xiamen Univ, Coll Mat, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
  • [ 8 ] [Wang, Lina]Fuzhou Univ, Fujian Key Lab Green Extract & High Value Utilizat, Fuzhou 350108, Peoples R China
  • [ 9 ] [Wang, Lina]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 10 ] [Wen, Zhenhai]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 11 ] [Wang, Lina]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Mat & Tech Hydrogen Energy, Fuzhou 350002, Peoples R China
  • [ 12 ] [Wen, Zhenhai]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Mat & Tech Hydrogen Energy, Fuzhou 350002, Peoples R China
  • [ 13 ] [Wang, Lina]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China
  • [ 14 ] [Wen, Zhenhai]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China
  • [ 15 ] [Zhao, Longze]Longmen Lab, Luoyang 471000, Peoples R China
  • [ 16 ] [Zheng, Chenxi]Xiamen Univ, Coll Energy, Coll Chem & Chem Engn, Xiamen 361102, Peoples R China
  • [ 17 ] [Gong, Zhengliang]Xiamen Univ, Coll Energy, Coll Chem & Chem Engn, Xiamen 361102, Peoples R China
  • [ 18 ] [Yang, Yong]Xiamen Univ, Coll Energy, Coll Chem & Chem Engn, Xiamen 361102, Peoples R China
  • [ 19 ] [Luo, Guangfu]Southern Univ Sci & Technol, Dept Mat Sci & Engn, Shenzhen 518055, Peoples R China
  • [ 20 ] [Luo, Guangfu]Southern Univ Sci & Technol, Inst Innovat Mat, Shenzhen 518055, Peoples R China

Reprint 's Address:

  • [Cheng, Yong]Xiamen Univ, Coll Mat, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China;;[Wang, Ming-Sheng]Xiamen Univ, Coll Mat, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China;;[Luo, Guangfu]Southern Univ Sci & Technol, Dept Mat Sci & Engn, Shenzhen 518055, Peoples R China;;[Luo, Guangfu]Southern Univ Sci & Technol, Inst Innovat Mat, Shenzhen 518055, Peoples R China

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Source :

ADVANCED MATERIALS

ISSN: 0935-9648

Year: 2025

Issue: 20

Volume: 37

2 7 . 4 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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