Tuning the surface structure of an Fe-based catalyst for transfer hydrogenation of nitroarenes at near room temperature - Details

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An　Fe3C-based　catalyst　was　fabricated　via　a　facile　template-free　route.　Owing　to　surface　structure　modulation,　optimal　FeNC800　presented　well-dispersed　Fe3C　on　N-doped　carbon,　the　highest　surface　area,　a　mesoporous　structure,　most　defects　and　maximum　surface　content　of　Fe.　As　a　result,　FeNC800　exhibited　distinguished　catalytic　performance　for　transfer　hydrogenation　of　nitroarenes　with　hydrazine　hydrate　at　near　room　temperature.　©　2025　The　Royal　Society　of　Chemistry.

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[ 1 ] [Wu D.]School of Materials and Chemical Engineering, Ningbo University of Technology, 201 Fenghua Road, Ningbo, 315211, China
[ 2 ] [Wu S.]School of Materials and Chemical Engineering, Ningbo University of Technology, 201 Fenghua Road, Ningbo, 315211, China
[ 3 ] [Wu S.]Zhejiang Institute of Tianjin University, Ningbo, 315201, China
[ 4 ] [Wu S.]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350016, China
[ 5 ] [Liu J.]Key Laboratory of Advanced Carbon-Based Functional Materials, Fujian Province University, Fuzhou University, Fuzhou, 350016, China
[ 6 ] [Zhang X.]Key Laboratory of Advanced Carbon-Based Functional Materials, Fujian Province University, Fuzhou University, Fuzhou, 350016, China
[ 7 ] [Fang X.]Key Laboratory of Advanced Carbon-Based Functional Materials, Fujian Province University, Fuzhou University, Fuzhou, 350016, China
[ 8 ] [Li S.]Key Laboratory of Advanced Carbon-Based Functional Materials, Fujian Province University, Fuzhou University, Fuzhou, 350016, China
[ 9 ] [Chen Y.]Key Laboratory of Advanced Carbon-Based Functional Materials, Fujian Province University, Fuzhou University, Fuzhou, 350016, China
[ 10 ] [Xie Z.]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350016, China
[ 11 ] [Xie Z.]Key Laboratory of Advanced Carbon-Based Functional Materials, Fujian Province University, Fuzhou University, Fuzhou, 350016, China

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Chemical Communications

ISSN： 1359-7345

Year： 2025

Issue： 29

Volume： 61

Page： 5455-5458

4 . 3 0 0

JCR@2023

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