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Copper foil roughness is widely regarded as an important factor affecting the performance of lithium-ion batteries, but relevant research still lacks systematic and in-depth analysis. In this paper, 6 mu m copper foil is prepared by electrodeposition and compared with purchased 6 mu m copper foil. The influence of different roughness on the battery performance is analyzed by the distribution of relaxation time (DRT). The results show that the roughness of homemade copper foil (1.69 mu m) is slightly higher than that of purchased copper foil (1.53 mu m). The initial charging specific capacity of the homemade copper foil electrode reaches 372.51 mAh g-1, significantly higher than that of the purchased copper foil electrode (323.89 mAh g-1). DRT is used to analyze the electrochemical reaction kinetics of the batteries, it is found that the copper foil with a certain roughness can enhance its binding with the active substance, ensure stable and rapid conductive contact, reduce the side reaction caused by uneven lithiation, and minimize the increase in the impedance of each part during the electrode cycle, thereby ensuring stable battery operation. This study provides new insights into the application of copper foil in batteries and verifies the feasibility of homemade 6 mu m copper foil.
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JOURNAL OF MATERIALS SCIENCE
ISSN: 0022-2461
Year: 2025
Issue: 18
Volume: 60
Page: 7641-7652
3 . 5 0 0
JCR@2023
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 1