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author:

Tong, Xinbao (Tong, Xinbao.) [1] | Liu, Jiaying (Liu, Jiaying.) [2] | Zhao, Yanqi (Zhao, Yanqi.) [3] | Li, Jingjun (Li, Jingjun.) [4] | Tian, Ye (Tian, Ye.) [5] | Liu, Qingyi (Liu, Qingyi.) [6] | Gao, Shuiying (Gao, Shuiying.) [7] | Cao, Rong (Cao, Rong.) [8]

Indexed by:

SCIE

Abstract:

The growing environmental concerns regarding rare earth elements in fluorescent powders, along with high production costs, have increased the demand for sustainable alternatives. We propose a promising solution using luminescent metal-organic frameworks (LMOFs) with large surface areas and tunable pore structures, combined with organic carbon quantum dots (CQDs). This study develops a novel white light-emitting diode (WLED) fluorescent powder by incorporating yellow-fluorescent quantum dots (CQDs-Y) into blue-emitting LMOF (ZJU-28), forming the composite material CQDs-Y-n@ZJU-28. The composite exhibits excellent thermal and chemical stability, long-term storage performance, and emits warm white light (CIE: 0.3277, 0.3281) when subjected to excitation at 365 nm, along with an external quantum efficiency (EQE) of 8.85 %. Furthermore, it exhibits tunable emission characteristics and promising LED performance, showcasing a color rendering index (CRI) of 78 and a correlated color temperature of 3384 K. The emitted light undergoes minimal deviation in color towards the white end of the spectrum in the temperature range of 277-437 K, making it an ideal candidate for advanced WLED applications. (c) 2025 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.

Keyword:

Carbon quantum dots CIE Fluorescence resonance energy transfer Luminescent materials Metal organic frameworks White light-emitting diode

Community:

  • [ 1 ] [Tong, Xinbao]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 2 ] [Liu, Jiaying]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 3 ] [Zhao, Yanqi]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 4 ] [Liu, Qingyi]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 5 ] [Gao, Shuiying]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 6 ] [Cao, Rong]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 7 ] [Tong, Xinbao]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 8 ] [Liu, Jiaying]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 9 ] [Zhao, Yanqi]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 10 ] [Li, Jingjun]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 11 ] [Tian, Ye]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 12 ] [Liu, Qingyi]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 13 ] [Gao, Shuiying]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 14 ] [Cao, Rong]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 15 ] [Li, Jingjun]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
  • [ 16 ] [Tian, Ye]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
  • [ 17 ] [Gao, Shuiying]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
  • [ 18 ] [Cao, Rong]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
  • [ 19 ] [Li, Jingjun]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China
  • [ 20 ] [Cao, Rong]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • [Gao, Shuiying]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China;;[Cao, Rong]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China;;[Gao, Shuiying]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China;;[Cao, Rong]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China;;[Gao, Shuiying]Univ Chinese Acad Sci, Beijing 100049, Peoples R China;;[Cao, Rong]Univ Chinese Acad Sci, Beijing 100049, Peoples R China;;[Cao, Rong]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China

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Source :

CHINESE CHEMICAL LETTERS

ISSN: 1001-8417

Year: 2025

Issue: 7

Volume: 36

9 . 4 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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