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author:

Huang, Yao (Huang, Yao.) [1] | Huang, Junqi (Huang, Junqi.) [2] | Wang, Peng (Wang, Peng.) [3] | Liao, Saihu (Liao, Saihu.) [4]

Indexed by:

SCIE

Abstract:

In this study, a visible-light-mediated two-component beta-fluoro-fluorosulfonamidation reaction of styrenes is demonstrated. The bench-stable reagent, N-fluorosulfamoyl-pyridinium tetrafluoroborate can be used as a photoredox-active nitrogen-centered radical precursor and also as the fluoride source. This transformation can convert a series of styrenes to functional group-enriched products, including substrates with electron-donating or withdrawing groups, as well as di- and tri-substituents on the C-C double bond.

Keyword:

fluorination fluorosulfamidation photoredox catalysis radical reactions sulfamoyl fluorides

Community:

  • [ 1 ] [Huang, Yao]Fuzhou Univ, Fujian Prov Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Peoples R China
  • [ 2 ] [Huang, Junqi]Fuzhou Univ, Fujian Prov Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Peoples R China
  • [ 3 ] [Huang, Yao]Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
  • [ 4 ] [Huang, Junqi]Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
  • [ 5 ] [Liao, Saihu]Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
  • [ 6 ] [Wang, Peng]Huaibei Normal Univ, Coll Chem & Mat Sci, Key Lab Green & Precise Synthet Chem & Applicat, Minist Educ, Huaibei 235000, Anhui, Peoples R China

Reprint 's Address:

  • [Liao, Saihu]Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China

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Source :

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

ISSN: 1434-193X

Year: 2025

2 . 5 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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