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author:

Ji, Shiyang (Ji, Shiyang.) [1] | Zhou, Yifan (Zhou, Yifan.) [2] | Xiong, Lin (Xiong, Lin.) [3] | Liu, Xinyu (Liu, Xinyu.) [4] | Zhu, Tong (Zhu, Tong.) [5] | Zhan, Xiuqin (Zhan, Xiuqin.) [6] | Yan, Yongli (Yan, Yongli.) [7] | Yao, Jiannian (Yao, Jiannian.) [8] | Wang, Kang (Wang, Kang.) [9] | Zhao, Yong Sheng (Zhao, Yong Sheng.) [10]

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Scopus SCIE

Abstract:

Organic materials are particularly appealing for circularly polarized (CP) lasers due to their remarkable chiroptical activities and exceptional optical gain properties. However, conventional organic CP lasers based on chiral molecules or microstructures typically exhibit reciprocal behavior, which complicates material synthesis and device fabrication for practical applications. In this study, we present nonreciprocal CP lasing from achiral organic microcrystals through the coupling between fluorescence linear anisotropy (f) and linear birefringence (LB), known as f-LB effect. By carefully controlling the crystallization process, we prepared triclinic and orthorhombic polymorphs with distinct molecular packing arrangements, which unlock the precise manipulation of f-LB coupling for efficient polarization state conversion of photons. The triclinic crystals exhibited stronger f-LB effect owing to the suitable angle between the emission plane and birefringence axis, resulting in robust nonreciprocal CP luminescence. More importantly, this coupling was further amplified during lasing oscillation, ultimately enabling nonreciprocal CP lasing with a dissymmetry factor of similar to 1.0. These findings provide a novel approach to exploring high-performance nonreciprocal CP lasers and offer new insights into chiral photonics and optoelectronics.

Keyword:

Community:

  • [ 1 ] [Ji, Shiyang]Chinese Acad Sci, Key Lab Photochem, Inst Chem, Beijing 100190, Peoples R China
  • [ 2 ] [Zhou, Yifan]Chinese Acad Sci, Key Lab Photochem, Inst Chem, Beijing 100190, Peoples R China
  • [ 3 ] [Xiong, Lin]Chinese Acad Sci, Key Lab Photochem, Inst Chem, Beijing 100190, Peoples R China
  • [ 4 ] [Yan, Yongli]Chinese Acad Sci, Key Lab Photochem, Inst Chem, Beijing 100190, Peoples R China
  • [ 5 ] [Yao, Jiannian]Chinese Acad Sci, Key Lab Photochem, Inst Chem, Beijing 100190, Peoples R China
  • [ 6 ] [Wang, Kang]Chinese Acad Sci, Key Lab Photochem, Inst Chem, Beijing 100190, Peoples R China
  • [ 7 ] [Zhao, Yong Sheng]Chinese Acad Sci, Key Lab Photochem, Inst Chem, Beijing 100190, Peoples R China
  • [ 8 ] [Ji, Shiyang]Univ Chinese Acad Sci, Sch Chem Sci, Beijing 100049, Peoples R China
  • [ 9 ] [Zhou, Yifan]Univ Chinese Acad Sci, Sch Chem Sci, Beijing 100049, Peoples R China
  • [ 10 ] [Xiong, Lin]Univ Chinese Acad Sci, Sch Chem Sci, Beijing 100049, Peoples R China
  • [ 11 ] [Yao, Jiannian]Univ Chinese Acad Sci, Sch Chem Sci, Beijing 100049, Peoples R China
  • [ 12 ] [Wang, Kang]Univ Chinese Acad Sci, Sch Chem Sci, Beijing 100049, Peoples R China
  • [ 13 ] [Zhao, Yong Sheng]Univ Chinese Acad Sci, Sch Chem Sci, Beijing 100049, Peoples R China
  • [ 14 ] [Liu, Xinyu]Beijing Inst Technol, Sch Mech Engn, Laser Micro Nano Fabricat Lab, Beijing 100081, Peoples R China
  • [ 15 ] [Zhu, Tong]Beijing Inst Technol, Sch Mech Engn, Laser Micro Nano Fabricat Lab, Beijing 100081, Peoples R China
  • [ 16 ] [Zhan, Xiuqin]Yangzhou Univ, Sch Chem & Chem Engn, Yangzhou 225002, Peoples R China
  • [ 17 ] [Yao, Jiannian]Fuzhou Univ, Inst Mol Engn Plus, Coll Chem, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • [Wang, Kang]Chinese Acad Sci, Key Lab Photochem, Inst Chem, Beijing 100190, Peoples R China;;[Zhao, Yong Sheng]Chinese Acad Sci, Key Lab Photochem, Inst Chem, Beijing 100190, Peoples R China;;[Wang, Kang]Univ Chinese Acad Sci, Sch Chem Sci, Beijing 100049, Peoples R China;;[Zhao, Yong Sheng]Univ Chinese Acad Sci, Sch Chem Sci, Beijing 100049, Peoples R China

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Source :

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

ISSN: 0002-7863

Year: 2025

Issue: 19

Volume: 147

Page: 16674-16680

1 4 . 5 0 0

JCR@2023

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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