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author:

Li, Yingying (Li, Yingying.) [1] | Hao, Tong (Hao, Tong.) [2] | Han, Yu-Peng (Han, Yu-Peng.) [3] | Li, Hui-Zi (Li, Hui-Zi.) [4] | Yan, Yayu (Yan, Yayu.) [5] | Li, Qiao-Hong (Li, Qiao-Hong.) [6] | Chen, Shumei (Chen, Shumei.) [7] (Scholars:陈淑妹) | Wang, Fei (Wang, Fei.) [8] | Zhang, Jian (Zhang, Jian.) [9]

Indexed by:

Scopus SCIE

Abstract:

Cerium metal-organic frameworks (Ce-MOFs) have attracted extensive attention due to their potential in photocatalytic applications. However, Ce-MOFs constructed with organic carboxylic acids as ligands typically exhibit wide band gaps, which limit their utilization in the visible-light region. This work proposes a strategy to design visible-light-active Ce-MOFs by employing quinoline sulfonic acid as a ligand. The synthesized compound (1-Ce) features a high surface area, open Ce metal sites, and large-sized 1D channels. Benefiting from ligand-to-metal charge transfer, 1-Ce demonstrates good visible light absorption. Additionally, the chelating coordination of nitrogen and oxygen atoms endows 1-Ce with excellent chemical stability. Owing to its abundant metal sites, high porosity, and visible light responsiveness, 1-Ce exhibits outstanding photocatalytic activity for CO2 reduction under visible light, achieving a CO production rate of 138 mu mol.g(-1).h(-1)-surpassing previously reported Ce-MOF photocatalysts.

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Community:

  • [ 1 ] [Li, Yingying]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Hao, Tong]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Yan, Yayu]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Chen, Shumei]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 5 ] [Li, Yingying]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Hao, Tong]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [Han, Yu-Peng]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 8 ] [Li, Hui-Zi]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 9 ] [Yan, Yayu]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 10 ] [Li, Qiao-Hong]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 11 ] [Wang, Fei]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 12 ] [Zhang, Jian]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 13 ] [Li, Yingying]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China
  • [ 14 ] [Hao, Tong]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China
  • [ 15 ] [Yan, Yayu]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • 陈淑妹

    [Chen, Shumei]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China;;[Wang, Fei]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China;;[Zhang, Jian]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

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Source :

ACS MATERIALS LETTERS

Year: 2025

Issue: 6

Volume: 7

Page: 2337-2342

9 . 9 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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