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author:

Zhang, Pengyu (Zhang, Pengyu.) [1] | Wang, Yuankang (Wang, Yuankang.) [2] | Lin, Zhongchong (Lin, Zhongchong.) [3] | Sun, Xutao (Sun, Xutao.) [4] | Li, Kewei (Li, Kewei.) [5] | Qian, Huidong (Qian, Huidong.) [6] | Tang, Shuhan (Tang, Shuhan.) [7] | Liang, Zhongyu (Liang, Zhongyu.) [8] | Yun, Chao (Yun, Chao.) [9] | Li, Guobao (Li, Guobao.) [10] | Ma, Xiaobai (Ma, Xiaobai.) [11] | Yang, Wenyun (Yang, Wenyun.) [12] | Wang, Changsheng (Wang, Changsheng.) [13] | Yang, Jinbo (Yang, Jinbo.) [14]

Indexed by:

SCIE

Abstract:

Rare-earth transition-metal (R-T) intermetallic compounds with planar magnetocrystalline anisotropy exhibit enhanced high-frequency magnetic properties and superior microwave absorption performance compared to compounds with uniaxial magnetocrystalline anisotropy, due to their higher Snoek limit resulting from high saturation magnetization (Ms) and large anisotropy factor. In this work, we investigated the structure, magnetic, and microwave absorbing properties of Y2Fe17-xSix (0 <= x <= 2) with planer anisotropy and their paraffin composites. Neutron powder diffraction (NPD) indicates that Y2Fe17-xSix compounds all possess a disordered Th2Ni17-type hexagonal structure as the primary phase, and the preferential order for Si substituting Fe crystallographic sites is: 12k, 6g, 12j(1), 12j(2), 4f, and 4e. At room temperature (RT), the 57Fe M & ouml;ssbauer spectra reveal that the average hyperfine field increases with increasing Si content, which is proportional to the average atomic magnetic moment of Fe. Magnetic measurements show that Si substitution significantly raises the Curie temperature (T-c) of Y2Fe17-xSix compounds, while also increasing the M-s at RT. By studying the high-frequency electromagnetic properties of Y2Fe17-xSix/paraffin composites, it was found that the real part of permittivity (epsilon epsilon ') at 1 GHz decreases with increasing Si content, reducing by approximately 40% for x=2 compared to x=0. Meanwhile, the real part of permeability (mu ') at 1 GHz initially increases and then decreases with increasing Si content, reaching a maximum at x=1.5. Therefore, Si substitution is advantageous to enhance the impedance matching of the composites, leading to better microwave absorption performance. Among all the compositions, the Y2Fe15Si2/paraffin composite exhibits a minimum reflection loss (RL) of -53.3 dB with a thickness of 3.0 mm, and a maximum effective absorption bandwidth (EAB, RL<-10 dB) of 3.95 GHz with a thickness of 1.06 mm, making it a promising candidate for high-performance microwave absorbing materials (MAMs).

Keyword:

compound Magnetic properties Microwave absorption M & ouml;ssbauer spectroscopy Neutron diffraction Permeability Rare-earth transition-metal intermetallic

Community:

  • [ 1 ] [Zhang, Pengyu]Peking Univ, Sch Phys, State Key Lab Artificial Microstruct & Mesoscop Ph, Beijing 100871, Peoples R China
  • [ 2 ] [Wang, Yuankang]Peking Univ, Sch Phys, State Key Lab Artificial Microstruct & Mesoscop Ph, Beijing 100871, Peoples R China
  • [ 3 ] [Sun, Xutao]Peking Univ, Sch Phys, State Key Lab Artificial Microstruct & Mesoscop Ph, Beijing 100871, Peoples R China
  • [ 4 ] [Li, Kewei]Peking Univ, Sch Phys, State Key Lab Artificial Microstruct & Mesoscop Ph, Beijing 100871, Peoples R China
  • [ 5 ] [Qian, Huidong]Peking Univ, Sch Phys, State Key Lab Artificial Microstruct & Mesoscop Ph, Beijing 100871, Peoples R China
  • [ 6 ] [Tang, Shuhan]Peking Univ, Sch Phys, State Key Lab Artificial Microstruct & Mesoscop Ph, Beijing 100871, Peoples R China
  • [ 7 ] [Yang, Wenyun]Peking Univ, Sch Phys, State Key Lab Artificial Microstruct & Mesoscop Ph, Beijing 100871, Peoples R China
  • [ 8 ] [Wang, Changsheng]Peking Univ, Sch Phys, State Key Lab Artificial Microstruct & Mesoscop Ph, Beijing 100871, Peoples R China
  • [ 9 ] [Yang, Jinbo]Peking Univ, Sch Phys, State Key Lab Artificial Microstruct & Mesoscop Ph, Beijing 100871, Peoples R China
  • [ 10 ] [Zhang, Pengyu]Beijing Key Lab Magnetoelectr Mat & Devices, Beijing 100871, Peoples R China
  • [ 11 ] [Wang, Yuankang]Beijing Key Lab Magnetoelectr Mat & Devices, Beijing 100871, Peoples R China
  • [ 12 ] [Sun, Xutao]Beijing Key Lab Magnetoelectr Mat & Devices, Beijing 100871, Peoples R China
  • [ 13 ] [Qian, Huidong]Beijing Key Lab Magnetoelectr Mat & Devices, Beijing 100871, Peoples R China
  • [ 14 ] [Tang, Shuhan]Beijing Key Lab Magnetoelectr Mat & Devices, Beijing 100871, Peoples R China
  • [ 15 ] [Yang, Wenyun]Beijing Key Lab Magnetoelectr Mat & Devices, Beijing 100871, Peoples R China
  • [ 16 ] [Wang, Changsheng]Beijing Key Lab Magnetoelectr Mat & Devices, Beijing 100871, Peoples R China
  • [ 17 ] [Yang, Jinbo]Beijing Key Lab Magnetoelectr Mat & Devices, Beijing 100871, Peoples R China
  • [ 18 ] [Lin, Zhongchong]Fujian Normal Univ, Coll Phys & Energy, Fujian Prov Key Lab Quantum Manipulat & New Energy, Fuzhou 350117, Peoples R China
  • [ 19 ] [Liang, Zhongyu]Fuzhou Univ, Sch Adv Mfg, Jinjiang 362200, Peoples R China
  • [ 20 ] [Yun, Chao]Sun Yat Sen Univ, Sch Mat, Shenzhen 518107, Peoples R China
  • [ 21 ] [Li, Guobao]Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
  • [ 22 ] [Li, Guobao]Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
  • [ 23 ] [Ma, Xiaobai]China Inst Atom Energy, Dept Nucl Phys, Beijing 102413, Peoples R China

Reprint 's Address:

  • [Zhang, Pengyu]Peking Univ, Sch Phys, State Key Lab Artificial Microstruct & Mesoscop Ph, Beijing 100871, Peoples R China;;[Yang, Wenyun]Peking Univ, Sch Phys, State Key Lab Artificial Microstruct & Mesoscop Ph, Beijing 100871, Peoples R China;;[Wang, Changsheng]Peking Univ, Sch Phys, State Key Lab Artificial Microstruct & Mesoscop Ph, Beijing 100871, Peoples R China;;[Yang, Jinbo]Peking Univ, Sch Phys, State Key Lab Artificial Microstruct & Mesoscop Ph, Beijing 100871, Peoples R China

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Source :

JOURNAL OF ALLOYS AND COMPOUNDS

ISSN: 0925-8388

Year: 2025

Volume: 1031

5 . 8 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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