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author:

Li, Shiqing (Li, Shiqing.) [1] | Tuo, Jie (Tuo, Jie.) [2] | Wan, Zheng (Wan, Zheng.) [3] | Zhang, Shuo (Zhang, Shuo.) [4] | Yu, Muyang (Yu, Muyang.) [5] | Ma, Ying (Ma, Ying.) [6] | Peng, Rusi (Peng, Rusi.) [7] | Xu, Hao (Xu, Hao.) [8] | Jiang, Jingang (Jiang, Jingang.) [9] | Chen, Shifu (Chen, Shifu.) [10] | He, Xiao (He, Xiao.) [11] | Wu, Peng (Wu, Peng.) [12]

Indexed by:

SCIE

Abstract:

The molecular traffic control (MTC) effect, a critical concept in porous materials catalysis, describes the diffusion behavior of reactant and product molecules through pore channels within zeolites, thereby establishing a relationship between the pore system and the catalytic performance. Herein, a series of a-oriented MFI-type ZSM-5 catalysts with modulated orientation length while maintaining comparable physicochemical properties are synthesized, and their performance in butene cracking reactions are evaluated. By precisely modulating the pore structure and crystal morphology of ZSM-5, it is demonstrated that minimizing the sinusoidal channel length along a-axis effectively optimizes the MTC effect, resulting in a superior propene selectivity (approximate to 60%) and an enhanced propene-to-ethene ratio (approximate to 12). Computational simulations coupled with experimental measurements reveal that reducing the length along a-axis facilitates preferential outward diffusion of propene molecules as terminal products. This work not only provides solid proof of molecular traffic control but also offers theoretical guidance for the rational design of other useful porous catalysts.

Keyword:

butene cracking molecular traffic control oriented morphology propene ZSM-5 zeolite

Community:

  • [ 1 ] [Li, Shiqing]Huaibei Normal Univ, Key Lab Green & Precise Synthet Chem & Applicat, Minist Chem & Mat Sci, Hueibei 235000, Anhui, Peoples R China
  • [ 2 ] [Zhang, Shuo]Huaibei Normal Univ, Key Lab Green & Precise Synthet Chem & Applicat, Minist Chem & Mat Sci, Hueibei 235000, Anhui, Peoples R China
  • [ 3 ] [Yu, Muyang]Huaibei Normal Univ, Key Lab Green & Precise Synthet Chem & Applicat, Minist Chem & Mat Sci, Hueibei 235000, Anhui, Peoples R China
  • [ 4 ] [Ma, Ying]Huaibei Normal Univ, Key Lab Green & Precise Synthet Chem & Applicat, Minist Chem & Mat Sci, Hueibei 235000, Anhui, Peoples R China
  • [ 5 ] [Peng, Rusi]Huaibei Normal Univ, Key Lab Green & Precise Synthet Chem & Applicat, Minist Chem & Mat Sci, Hueibei 235000, Anhui, Peoples R China
  • [ 6 ] [Chen, Shifu]Huaibei Normal Univ, Key Lab Green & Precise Synthet Chem & Applicat, Minist Chem & Mat Sci, Hueibei 235000, Anhui, Peoples R China
  • [ 7 ] [Li, Shiqing]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China
  • [ 8 ] [Tuo, Jie]East China Normal Univ, Sch Chem & Mol Engn, State Key Lab Petr Mol & Proc Engn, Shanghai Key Lab Green Chem & Chem Proc, 3663 North Zhongshan Rd, Shanghai 200062, Peoples R China
  • [ 9 ] [Xu, Hao]East China Normal Univ, Sch Chem & Mol Engn, State Key Lab Petr Mol & Proc Engn, Shanghai Key Lab Green Chem & Chem Proc, 3663 North Zhongshan Rd, Shanghai 200062, Peoples R China
  • [ 10 ] [Jiang, Jingang]East China Normal Univ, Sch Chem & Mol Engn, State Key Lab Petr Mol & Proc Engn, Shanghai Key Lab Green Chem & Chem Proc, 3663 North Zhongshan Rd, Shanghai 200062, Peoples R China
  • [ 11 ] [Wu, Peng]East China Normal Univ, Sch Chem & Mol Engn, State Key Lab Petr Mol & Proc Engn, Shanghai Key Lab Green Chem & Chem Proc, 3663 North Zhongshan Rd, Shanghai 200062, Peoples R China
  • [ 12 ] [Wan, Zheng]East China Normal Univ, Shanghai Engn Res Ctr Mol Therapeut & New Drug Dev, Shanghai Frontiers Sci Ctr Mol Intelligent Synth, Sch Chem & Mol Engn, Shanghai 200062, Peoples R China
  • [ 13 ] [He, Xiao]East China Normal Univ, Shanghai Engn Res Ctr Mol Therapeut & New Drug Dev, Shanghai Frontiers Sci Ctr Mol Intelligent Synth, Sch Chem & Mol Engn, Shanghai 200062, Peoples R China

Reprint 's Address:

  • [Peng, Rusi]Huaibei Normal Univ, Key Lab Green & Precise Synthet Chem & Applicat, Minist Chem & Mat Sci, Hueibei 235000, Anhui, Peoples R China;;[Wu, Peng]East China Normal Univ, Sch Chem & Mol Engn, State Key Lab Petr Mol & Proc Engn, Shanghai Key Lab Green Chem & Chem Proc, 3663 North Zhongshan Rd, Shanghai 200062, Peoples R China;;[He, Xiao]East China Normal Univ, Shanghai Engn Res Ctr Mol Therapeut & New Drug Dev, Shanghai Frontiers Sci Ctr Mol Intelligent Synth, Sch Chem & Mol Engn, Shanghai 200062, Peoples R China

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SMALL

ISSN: 1613-6810

Year: 2025

1 3 . 0 0 0

JCR@2023

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WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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