Login | Cas Login
English| 简体中文| 繁体中文

  • Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

Advanced Search

author：

Zhang, T. (Zhang, T..) [1] | Zhang, Y. (Zhang, Y..) [2] | Chen, Z.-C. (Chen, Z.-C..) [3] | Qiu, Y. (Qiu, Y..) [4] | Zhang, M. (Zhang, M..) [5] | Zhang, S. (Zhang, S..) [6] | Peng, X. (Peng, X..) [7] | Zhang, L. (Zhang, L..) [8] | Zhou, Y. (Zhou, Y..) [9] | Zheng, L. (Zheng, L..) [10] | Xu, B.-Q. (Xu, B.-Q..) [11] | Wang, X. (Wang, X..) [12] | Jiang, L. (Jiang, L..) [13]

Indexed by：

Scopus

Abstract：

Strong　metal-support　interaction　(SMSI)　is　a　crucial　strategy　for　modulating　the　activity.　Finely　tailoring　the　size　of　the　support　to　the　nanoscale　still　faces　significant　challenges.　Herein,　for　the　first　time,　C60　carbon　cluster　is　utilized　as　a　nano-support　to　anchor　ultrafine　Ru　nanoclusters　to　create　a　Ru-C60　cluster–cluster　co-catalyst.　The　unique　geometric　structure　of　the　nano-support　C60　enables　the　construction　of　a　strong　cluster–cluster　interaction　(SCCI),　quite　different　from　traditional　SMSI.　La-modified　Ru-C60　presents　a　surprising　discovery　that　NH3　can　even　be　synthesized　at　150　°C,　and　exhibits　an　unprecedentedly　high　NH3　synthesis　rate　at　400　°C.　C60　not　only　acts　as　an　electron　buffer　to　balance　the　charge　density　of　Ru　sites,　but　also　stabilizes　more　metallic　Ru　active　sites　with　a　smaller　size　due　to　its　spatial　and　SCCI　effect,　thereby　achieving　superior　catalytic　performance　over　a　wide　range　of　temperatures　and　pressures.　©　2025　Elsevier　Ltd

Keyword：

Ammonia synthesis Cluster–cluster interaction Electronic structure Heterogeneous catalysis Nano-support

Community：

  • [ 1 ] [Zhang T.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fujian, 350002, China
  • [ 2 ] [Zhang Y.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fujian, 350002, China
  • [ 3 ] [Chen Z.-C.]State Key Laboratory of Physical Chemistry of Solid Surfaces, National Engineering Laboratory for Green Chemical Production of Alcohols-Ethers-Esters, iChEM, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, China
  • [ 4 ] [Qiu Y.]State Key Laboratory of Physical Chemistry of Solid Surfaces, National Engineering Laboratory for Green Chemical Production of Alcohols-Ethers-Esters, iChEM, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, China
  • [ 5 ] [Zhang M.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fujian, 350002, China
  • [ 6 ] [Zhang S.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fujian, 350002, China
  • [ 7 ] [Peng X.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fujian, 350002, China
  • [ 8 ] [Zhang L.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fujian, 350002, China
  • [ 9 ] [Zhou Y.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fujian, 350002, China
  • [ 10 ] [Zheng L.]Institute of High Energy Physics, Chinese Academy of Sciences, Beijing, 100049, China
  • [ 11 ] [Xu B.-Q.]Innovative Catalysis Program, Key Lab of Organic Optoelectronics & Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing, 100084, China
  • [ 12 ] [Wang X.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fujian, 350002, China
  • [ 13 ] [Wang X.]Qingyuan Innovation Laboratory, Fujian, Quanzhou, 362801, China
  • [ 14 ] [Jiang L.]National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fujian, 350002, China
  • [ 15 ] [Jiang L.]Qingyuan Innovation Laboratory, Fujian, Quanzhou, 362801, China

Reprint 's Address：

Email：

Show more details

Related Keywords：

Related Article：

Source ：

Chemical Engineering Science

ISSN： 0009-2509

Year： 2025

Volume： 312

4 . 1 0 0

JCR@2023

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 0

Affiliated Colleges：

Get Fulltext

DOI Library Discovery Baidu Scholar Search SCOPUS
Online/Total：883/13848709
Address：FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code：350116) Contact Us：0591-22865326
Copyright：FZU Library Technical Support：Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1