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author:

Chen, Bingshen (Chen, Bingshen.) [1] | Xia, Biao (Xia, Biao.) [2] | Liao, Shijie (Liao, Shijie.) [3] | Zeng, Daiwei (Zeng, Daiwei.) [4] | Lin, Tengfei (Lin, Tengfei.) [5] (Scholars:林腾飞) | Wen, Na (Wen, Na.) [6] (Scholars:温娜) | Gao, Min (Gao, Min.) [7] (Scholars:高旻) | Zhao, Chunlin (Zhao, Chunlin.) [8] (Scholars:赵纯林) | Wu, Xiao (Wu, Xiao.) [9] (Scholars:吴啸) | Lin, Cong (Lin, Cong.) [10] (Scholars:林枞) | Zheng, Xiaochun (Zheng, Xiaochun.) [11] | Gao, Fei (Gao, Fei.) [12]

Indexed by:

EI Scopus SCIE

Abstract:

Two-way shape memory polymers (2W-SMPs), which can transition between two distinct temporary shapes, have garnered significant attention from researchers. This study successfully developed thermadapt 2W-SMPs using syndiotactic 1,2-polybutadiene (SPB) by leveraging dynamic covalent crosslinking techniques. Initially, m-chloroperbenzoic acid (m-CPBA) was employed for the epoxidation of SPB. Cysteine (Cys) was subsequently introduced to form a dynamic covalent bond of beta-hydroxy ester via the reaction between the epoxy groups on SPB and the carboxyl groups of Cys. The sulfhydryl groups of Cys can undergo oxidative coupling to form disulfide bonds, thereby establishing two distinct types of dynamic covalent bonds within the material and lowering its topological rearrangement temperature. Through the exchange reactions of these dynamic covalent bonds at elevated temperatures, the resulting material exhibits enhanced mechanical properties and can be reshaped in the solid state. This work provides a viable method for preparing recyclable thermally adaptive 2W-SMPs under stress-free conditions, thereby enriching the research landscape in the field of shape memory materials.

Keyword:

Community:

  • [ 1 ] [Chen, Bingshen]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Xia, Biao]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Liao, Shijie]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Zeng, Daiwei]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 5 ] [Lin, Tengfei]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 6 ] [Wen, Na]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 7 ] [Gao, Min]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 8 ] [Zhao, Chunlin]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 9 ] [Wu, Xiao]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 10 ] [Lin, Cong]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 11 ] [Zheng, Xiaochun]Fuzhou Univ, Affiliated Prov Hosp, Dept Anesthesiol, Fuzhou 350001, Peoples R China
  • [ 12 ] [Gao, Fei]Fuzhou Univ, Affiliated Prov Hosp, Dept Anesthesiol, Fuzhou 350001, Peoples R China
  • [ 13 ] [Zheng, Xiaochun]Fujian Med Univ, Shengli Clin Med Coll, Fuzhou 350122, Peoples R China
  • [ 14 ] [Gao, Fei]Fujian Med Univ, Shengli Clin Med Coll, Fuzhou 350122, Peoples R China
  • [ 15 ] [Zheng, Xiaochun]Fujian Emergency Med Ctr, Fujian Prov Key Lab Emergency Med, Fujian Prov Key Lab Crit Care Med, Fujian Prov Coconstructed Lab Belt & Rd, Fuzhou 350001, Peoples R China
  • [ 16 ] [Gao, Fei]Fujian Emergency Med Ctr, Fujian Prov Key Lab Emergency Med, Fujian Prov Key Lab Crit Care Med, Fujian Prov Coconstructed Lab Belt & Rd, Fuzhou 350001, Peoples R China

Reprint 's Address:

  • 林腾飞 高飞

    [Lin, Tengfei]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China;;[Gao, Fei]Fuzhou Univ, Affiliated Prov Hosp, Dept Anesthesiol, Fuzhou 350001, Peoples R China;;[Gao, Fei]Fujian Med Univ, Shengli Clin Med Coll, Fuzhou 350122, Peoples R China;;[Gao, Fei]Fujian Emergency Med Ctr, Fujian Prov Key Lab Emergency Med, Fujian Prov Key Lab Crit Care Med, Fujian Prov Coconstructed Lab Belt & Rd, Fuzhou 350001, Peoples R China

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Source :

JOURNAL OF MATERIALS SCIENCE

ISSN: 0022-2461

Year: 2025

Issue: 28

Volume: 60

Page: 12172-12185

3 . 5 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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