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author:

Lai, Fuqiang (Lai, Fuqiang.) [1] | Hu, Anqiong (Hu, Anqiong.) [2] | Hao, Xiangfei (Hao, Xiangfei.) [3] | Bai, Hongbai (Bai, Hongbai.) [4] | Ren, Zhiying (Ren, Zhiying.) [5] | Wu, Yiwan (Wu, Yiwan.) [6]

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Abstract:

Metal rubber (MR) is recognized for its exceptional qualities as a vibration and damping structural material, and it exhibits commendable creep resistance under regular work conditions. However, the extent of its creep resistance when subjected to environmental challenges, such as the wet marine environments found aboard ships or the oil-polluted settings that are characteristic of factory processing equipment, remains undetermined. Currently, the literature contains limited investigations into the static compressive creep behavior of MR within marine corrosive environments. This scarcity of research underscores the need for further exploration to ascertain the performance capabilities of MR under these harsh circumstances. Leveraging these insights, this study initiates the fabrication of MR specimens from 304 stainless steel wire via a series of processes including winding, drawing, blank winding, and stamping. Subsequently, the MR specimens undergo distinct surface modification treatments: silanization (S), chemical pickling (P), and a combination of chemical pickling followed by silanization (P-S). These treatments yield three categories of MR specimens that exhibit varied surface attributes. A 5wt.% NaCl solution is employed to emulate a marine environment, and an alternate immersion corrosion creep (AICC) test is conducted on the MR specimens with the aforementioned surface treatments. The post-test analysis involves the examination of the micro-morphology, elemental composition of corrosion products, corrosion resistance, and creep resistance of the three specimens. Characterization techniques, such as tungsten filament scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), and electrochemical comprehensive testing are utilized to facilitate these assessments. The results show that after the AICC test, the corrosion products of the three specimens are mainly O, Fe, and Cr. The corrosion products on the surface of the untreated and S-MR specimens are covered in bulk on the surface of the wire. The P-MR and P-S-MR specimens are adhered to the metal wire in the form of a cell. The electrochemical test results show that the S-MR has the lowest corrosion potential (Ecorr) and the highest corrosion current density (icorr) under the AICC conditions, indicating that it has the worst pitting resistance and is more prone to pitting reactions. However, compared with untreated specimens, the impedance Rp and diffusion coefficient n of S-MR specimens are higher, whereas the Q value is lower, indicating that the passivation film stability is better and the corrosion rate is lower. The Ecorr of P-S-MR specimens is-447.37 mV, which is relatively high, whereas their icorr is relatively low, at 0.91 μA·cm−2. In addition, the overall corrosion rates of S-MR, P-MR, and P-S-MR are 0.024 9, 0.019 2, and 0.013 4 mm / a, respectively, which are lower than those of the untreated specimens (0.044 1 mm / a). The results show that the silane film produced by silanization has a better protective effect on the S-MR specimens, and the comprehensive comparison shows that the P-S-MR specimens show the best corrosion resistance in the 5wt.% NaCl solution. According to the variation amplitude of the mechanical performance of each specimen during the AICC test, the creep phenomena of the four specimens occurs in different degrees in the intermediate immersion corrosion environment. The height variation amplitude h, average stiffness variation amplitude k, energy dissipation variation amplitude e, and loss factor variation amplitude l of the P-S-MR specimens are-2.23%, 19.21%,-15.14%, and-3.79%, respectively, whereas the k and e values of the untreated specimens are 29.45% and-29.31%, respectively, which are close to the failure threshold of ±30%. Moreover, the overall magnitude of the mechanical performance change amplitude maintains the same order: untreated > S-MR > P-MR > P-S-MR. These results show that the changes in mechanical performance of MR specimens are affected by the degree of corrosion. That is, the higher the degree of corrosion, the higher the degree of creep caused to the specimens. These results also indicate that the P-S treatment of MR specimens is an effective technical approach by which to improve their corrosion and creep resistance. Therefore, this research can serve as an important reference for the extension of the engineering applications of metal rubber. © 2025, Chinese Mechanical Engineering Society. All rights reserved.

Keyword:

Chemical modification Corrosion resistance Corrosive effects Creep Creep resistance Creep testing Electrochemical corrosion Heat treatment Metal drawing Pickling Seawater corrosion Surface testing Surface treatment Wire products

Community:

  • [ 1 ] [Lai, Fuqiang]School of Mechanical Engineering and Automation, Fuzhou University, Fuzhou; 350116, China
  • [ 2 ] [Hu, Anqiong]School of Mechanical Engineering and Automation, Fuzhou University, Fuzhou; 350116, China
  • [ 3 ] [Hao, Xiangfei]School of Mechanical Engineering and Automation, Fuzhou University, Fuzhou; 350116, China
  • [ 4 ] [Bai, Hongbai]School of Mechanical Engineering and Automation, Fuzhou University, Fuzhou; 350116, China
  • [ 5 ] [Ren, Zhiying]School of Mechanical Engineering and Automation, Fuzhou University, Fuzhou; 350116, China
  • [ 6 ] [Wu, Yiwan]School of Mechanical Engineering and Automation, Fuzhou University, Fuzhou; 350116, China

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Source :

China Surface Engineering

ISSN: 1007-9289

Year: 2025

Issue: 1

Volume: 38

Page: 141-151

0 . 8 0 0

JCR@2023

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ESI Highly Cited Papers on the List: 0 Unfold All

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30 Days PV: 3

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