Cobalt-Catalyzed anti-Markovnikov-Selective Hydroborylation of Perfluoroalkylethylenes - Details

author：

Dong, Renning (Dong, Renning.) ^[1] | Huang, Yangjie (Huang, Yangjie.) ^[2] | Wei, Liqin (Wei, Liqin.) ^[3] | Xie, Lili (Xie, Lili.) ^[4] | Weng, Zhiqiang (Weng, Zhiqiang.) ^[5]

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Abstract：

A　facile　protocol　for　anti-Markovnikov-selective　hydroborylation　of　perfluoroalkylethylenes　with　pinacolborane　has　been　developed　in　the　presence　of　Co(acac)2　and　dppf　in　DMAC　to　furnish　diverse　perfluoroalkylethylboronate　esters.　Subsequently,　perfluoroalkylethylboronate　ester　derivatives　were　further　transformed　into　2-perfluoroalkyl　ethanol,　amide,　and　cross-coupling　products.　©　2025　American　Chemical　Society.

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Catalysis

Community：

[ 1 ] [Dong, Renning]Key Laboratory of Molecule Synthesis and Function Discovery, College of Chemistry, Fuzhou University, Fuzhou; 350108, China
[ 2 ] [Huang, Yangjie]Fujian Provincial University Engineering Research Center of Green Materials and Chemical Engineering, Fujian Engineering Research Center of New Chinese Lacquer Material, College of Materials and Chemical Engineering, Minjiang University, Fuzhou; 350108, China
[ 3 ] [Wei, Liqin]Fujian Provincial University Engineering Research Center of Green Materials and Chemical Engineering, Fujian Engineering Research Center of New Chinese Lacquer Material, College of Materials and Chemical Engineering, Minjiang University, Fuzhou; 350108, China
[ 4 ] [Xie, Lili]Key Laboratory of Molecule Synthesis and Function Discovery, College of Chemistry, Fuzhou University, Fuzhou; 350108, China
[ 5 ] [Weng, Zhiqiang]Key Laboratory of Molecule Synthesis and Function Discovery, College of Chemistry, Fuzhou University, Fuzhou; 350108, China
[ 6 ] [Weng, Zhiqiang]Fujian Provincial University Engineering Research Center of Green Materials and Chemical Engineering, Fujian Engineering Research Center of New Chinese Lacquer Material, College of Materials and Chemical Engineering, Minjiang University, Fuzhou; 350108, China

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Source ：

Journal of Organic Chemistry

ISSN： 0022-3263

Year： 2025

Issue： 23

Volume： 90

Page： 7567-7573

3 . 4 0 0

JCR@2023

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