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Abstract:
All inorganic CsPbBr3 perovskite is a promising emissio n material for high-performance lighting and display appl ications, but its poor stability and sensitivity to moisture and oxygen hinder commercialization. Packaging perovsk ite quantum dots (PQDs) in organosilicon matrices offers an effective way to enhance stability. In this work, we replaced traditional oleic acid ligands with bromopropion ic acid. The Pb-Br formed can fill bromine vacancies, i mproving luminescence. The carboxyl group (-COOH) in bromopropionic acid releases protons (H+) and catalyze s the polymerization of octamethylcyclotetrasiloxane (D 4), forming a silicone coating on the PQDs. Additionally, oxygen in silicones bonds with Pb, passivating defects. The resulting CsPbBr3/silicon composite shows a 1.8 tim es increase in photoluminescence quantum yield (PLQY) and significantly improved stability. This optimized com posite material demonstrates strong potential for use as c olor converters in lighting and display applications, enha ncing the performance and stability of optoelectronic dev ices. © 2025, John Wiley and Sons Inc. All rights reserved.
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ISSN: 0097-966X
Year: 2025
Issue: S1
Volume: 56
Page: 1807-1809
Language: English
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SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 4
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