Atmospheric　water　harvesting　(AWH)　is　a　promising　method　to　combat　the　challenge　of　water　shortage.　Despite　the　great　progress　of　AWH,　the　imperfect　structural　design,　complex　fabrication　procedures,　and　sluggish　sorption/desorption　kinetics　hinder　its　AHW　performance.　Herein,　a　honeycomb　organogel　fabric　(CHOF)　with　an　interior　osmotic　pressure　of　184.7　atm　is　reported.　The　calcium　alginate　skeleton　was　designed　to　accommodate　hygroscopic　glycerin　solution,　enabling　the　enhancement　of　water　sorption　of　the　CHOF.　The　interior　osmotic　pressure　could　refresh　the　sorption/desorption　sites　of　the　CHOF　by　continuously　transporting　the　sorbed　water　from　the　surface　to　interior　and　the　reverse,　thus　strengthening　sorption/desorption　kinetics.　The　honeycomb　structure　and　loaded　carbon　black　of　CHOF　could　endow　it　with　an　effective　solar-to-thermal　performance　for　water　desorption.　Furthermore,　based　on　the　mature　textile　weaving　technology,　the　CHOF　was　easy　to　be　scaled　up　and　did　not　show　a　decline　of　performance.　The　rapid　sorption–desorption　kinetics　of　CHOF　was　beneficial　for　daily　multiple　capture-release　cycles.　Ultimately,　the　daily　water　production　of　CHOF　could　achieve　6.70　kg　m–2day–1,　which　proves　that　the　CHOF　could　be　regarded　as　a　sustainable　material　for　large-scale　water　production.　©　2025　American　Chemical　Society