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author:

Bhosale, Sanjana (Bhosale, Sanjana.) [1] | Zhang, Jinlong (Zhang, Jinlong.) [2] | Meng, Xiaowei (Meng, Xiaowei.) [3] | Hong, Ruoyu Roy (Hong, Ruoyu Roy.) [4] (Scholars:洪若瑜)

Indexed by:

EI SCIE

Abstract:

Lithium-rich, manganese-based layered oxides are among the most promising cathode materials for next-generation lithium-ion batteries (LIBs), offering high reversible capacity, elevated operating voltage, and cost-effectiveness compared to conventional cathodes. However, their practical application is hindered by irreversible lattice oxygen loss and structural degradation during cycling. In this work, Li-1.2[Mn0.54Ni0.13Co0.13]O-2 was modified via in situ Mg2+ doping and uniform Li2MnO3 surface coating to address these challenges. The dual-modified material was systematically investigated through theoretical analysis and validated experimentally using structural, morphological, and electrochemical characterization techniques. Electrochemical evaluations revealed that the synergistic effect of Mg2+ doping and Li2MnO3 coating significantly improved the material's performance, delivering a high discharge capacity of 193.9 mAh/g at 1C and an impressive capacity retention of 86.4% after 200 cycles. Additionally, the 52.73% reduction in voltage fade achieved through Mg2+ doping and Li2MnO3 coating further confirms the enhanced interfacial stability and significantly improved long-term cycling durability of the modified electrode.

Keyword:

dual-modified cathode in situ Mg doping Li2MnO3 coating lithium-ion battery lithium-rich layered oxide cathode

Community:

  • [ 1 ] [Bhosale, Sanjana]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 2 ] [Zhang, Jinlong]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 3 ] [Hong, Ruoyu Roy]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 4 ] [Meng, Xiaowei]Jiangsu CFG Technol Co Ltd, Liyang 213321, Jiangsu, Peoples R China

Reprint 's Address:

  • 洪若瑜

    [Hong, Ruoyu Roy]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Fujian, Peoples R China

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Source :

ACS APPLIED ENERGY MATERIALS

ISSN: 2574-0962

Year: 2025

Issue: 16

Volume: 8

Page: 11948-11960

5 . 5 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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