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author:

Xu, Xiahong (Xu, Xiahong.) [1] | Sui, Yan (Sui, Yan.) [2] | Chen, Wentong (Chen, Wentong.) [3] | Li, Xiaodan (Li, Xiaodan.) [4] | Li, Yuntong (Li, Yuntong.) [5] | Zhong, Hong (Zhong, Hong.) [6] | Huang, Wei (Huang, Wei.) [7]

Indexed by:

EI SCIE

Abstract:

The catalytic conversion of CO2 into valuable cyclic carbonates has emerged as a sustainable and effective strategy to mitigate global warming. However, the activation of CO2 remains challenging due to its high intrinsic thermodynamic stability and kinetic inertness. To address this, an imidazolium-and triazine-based ionic polymer [(HO)3-ImtTbIP] was synthesized via the quaternization reaction of 1,2,4,5-tetrakis (bromomethyl)benzene (Tb) with 2,4,6-tris(4-(1H-imidazole-1-yl)phenyl)-1,3,5-triazine (Imt) and 2-(hydroxymethyl)-2-(1H-imidazole-1-yl) propane-1,3-diol [(HO)3]. The 2-(hydroxymethyl)-2-(1H-imidazole-1-yl)propane-1,3-diol moieties in the polymer backbone act as strong hydrogen bond donors, facilitating the weakening of the C-O bond in epoxides, while the charge-balanced bromide anions function as nucleophiles, attacking the activated epoxides and enabling ring-opening. Simultaneously, CO2 activated through the triazinyl and imidazolium groups interact with oxyanion intermediates to form alkyl carbonate species. The (HO)3-ImtTbIP, featuring well-defined task-specific active functional groups show efficient conversion of CO2 and epoxides to cyclic carbonates under mild conditions (100 degrees C, 1 bar CO2). This pre-functionalized polymer exhibits significant potential for sustainable CO2 utilization.

Keyword:

CO 2 conversion Cyclic carbonates Electrostatic hydrogen bond Heterogeneous catalysis Ionic polymer

Community:

  • [ 1 ] [Xu, Xiahong]Jinggangshan Univ, Sch Chem & Chem Engn, Key Lab Coordinat Chem Jiangxi Prov, Jian 343009, Jiangxi, Peoples R China
  • [ 2 ] [Sui, Yan]Jinggangshan Univ, Sch Chem & Chem Engn, Key Lab Coordinat Chem Jiangxi Prov, Jian 343009, Jiangxi, Peoples R China
  • [ 3 ] [Chen, Wentong]Jinggangshan Univ, Sch Chem & Chem Engn, Key Lab Coordinat Chem Jiangxi Prov, Jian 343009, Jiangxi, Peoples R China
  • [ 4 ] [Li, Xiaodan]Jinggangshan Univ, Sch Chem & Chem Engn, Key Lab Coordinat Chem Jiangxi Prov, Jian 343009, Jiangxi, Peoples R China
  • [ 5 ] [Li, Yuntong]Jinggangshan Univ, Sch Chem & Chem Engn, Key Lab Coordinat Chem Jiangxi Prov, Jian 343009, Jiangxi, Peoples R China
  • [ 6 ] [Zhong, Hong]Jinggangshan Univ, Sch Chem & Chem Engn, Key Lab Coordinat Chem Jiangxi Prov, Jian 343009, Jiangxi, Peoples R China
  • [ 7 ] [Huang, Wei]Jinggangshan Univ, Sch Chem & Chem Engn, Key Lab Coordinat Chem Jiangxi Prov, Jian 343009, Jiangxi, Peoples R China
  • [ 8 ] [Zhong, Hong]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China
  • [ 9 ] [Xu, Xiahong]Jiangxi Univ Sci & Technol, Sch Chem & Chem Engn, Ganzhou 341000, Jiangxi, Peoples R China

Reprint 's Address:

  • 待查

    [Zhong, Hong]Jinggangshan Univ, Sch Chem & Chem Engn, Key Lab Coordinat Chem Jiangxi Prov, Jian 343009, Jiangxi, Peoples R China;;[Huang, Wei]Jinggangshan Univ, Sch Chem & Chem Engn, Key Lab Coordinat Chem Jiangxi Prov, Jian 343009, Jiangxi, Peoples R China

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Source :

POLYMER

ISSN: 0032-3861

Year: 2025

Volume: 337

4 . 1 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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