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Abstract:
This work reports the synthesis of a 1,3-linked tetracyclopentadienylcobalt-cyclobutadiene macrocycle ([CpCoCb] 4 ) via Pt-templated cyclization. Structural characterization by SCXRD confirms a C i -symmetric nanohoop (1.5 nm diameter). Unique CH-pi interactions drive the 1D channel packing. Electrochemical studies reveal multiredox activity. This work establishes a new paradigm for strained organometallic architectures with potential applications in multistate molecular electronics and host-guest systems.
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ORGANIC LETTERS
ISSN: 1523-7060
Year: 2025
4 . 9 0 0
JCR@2023
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 0
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