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Abstract:
Safety issues significantly influence the iterative application of lithium-ion batteries (LIBs), and they have become a critical challenge that requires immediate resolution. Herein, a new type of self-quenched battery with an anode failure hunter was developed in which a high flame retardant was utilized to react with the Li x C6 of the anode, making it ineffective at a temperature range of 90-120 degrees C, avoiding its reaction with the oxygen produced by the cathode and blocking the occurrence of a large scale chain exothermic reaction (O2 + Li x C6). After the anode failure hunter was assembled as a self-quenched battery, the onset temperature of the self-quenched battery was increased by 15.5 degrees C, improving battery safety from the intrinsic level. More importantly, the energy release of the thermal runaway for the self-quenched battery has been reduced by 123.7 degrees C, significantly improving the safety of the battery. Therefore, such work could provide a new strategy to design devices for solving the safety issue in LIBs.
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ACS ENERGY LETTERS
ISSN: 2380-8195
Year: 2025
1 9 . 5 0 0
JCR@2023
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 1