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author:

Wu, Shuang (Wu, Shuang.) [1] | Feng, Wuliang (Feng, Wuliang.) [2] | Wang, Peiyao (Wang, Peiyao.) [3] | Ma, Chenyao (Ma, Chenyao.) [4] | Shen, Li (Shen, Li.) [5] | Shi, Qinhao (Shi, Qinhao.) [6] | Liu, Yiran (Liu, Yiran.) [7] | Zhang, Ying (Zhang, Ying.) [8] | Zhu, Xingbao (Zhu, Xingbao.) [9] | Zhang, Jiujun (Zhang, Jiujun.) [10] | Jiao, Zheng (Jiao, Zheng.) [11] | Zhao, Yufeng (Zhao, Yufeng.) [12]

Indexed by:

SCIE

Abstract:

All-solid-state lithium batteries (ASSLBs) hold great promise to develop high-energy-density and safety secondary batteries, but suffer from the fundamental obstacles of interfacial mechano-electrochemical instabilities and lithium (Li) dendrite growth. Herein, a kinetics-reinforced mechano-electrochemical stable lithium-silicon-nitrogen composites (LSN), is developed, which can effectively promote the interfacial stabilities and suppress Li dendrite propagation. With the integration of silicon, interfacial electrochemical stability is significantly improved by cutting down the potential difference between the Li6PS5Cl solid electrolyte and LSN. The participation of nitrogen accelerates the kinetic process of Li diffusion, which mitigates concentration polarization and reduces the interfacial overpotential. Simultaneously, interfacial contact loss has been successfully restricted due to the upholding of the Li4.4Si & Li3N framework. The mechanical, electrochemical, and kinetical reinforced Li6PS5Cl/LSN interface enables a high critical current density of 15.2 mA cm-2 (50 degrees C), and a stable cycling of ASSLBs (70.11% capacity retention after 500 cycles), thus overcoming the instinct drawbacks of lithium metal anode and establishing a scalable design principle for dendrite-free ASSLBs.

Keyword:

all solid-state batteries dendrites interface lithium anode

Community:

  • [ 1 ] [Wu, Shuang]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 2 ] [Jiao, Zheng]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 3 ] [Wu, Shuang]Shanghai Univ, Inst Sustainable Energy, Coll Sci, Shanghai 200444, Peoples R China
  • [ 4 ] [Feng, Wuliang]Shanghai Univ, Inst Sustainable Energy, Coll Sci, Shanghai 200444, Peoples R China
  • [ 5 ] [Wang, Peiyao]Shanghai Univ, Inst Sustainable Energy, Coll Sci, Shanghai 200444, Peoples R China
  • [ 6 ] [Ma, Chenyao]Shanghai Univ, Inst Sustainable Energy, Coll Sci, Shanghai 200444, Peoples R China
  • [ 7 ] [Shen, Li]Shanghai Univ, Inst Sustainable Energy, Coll Sci, Shanghai 200444, Peoples R China
  • [ 8 ] [Shi, Qinhao]Shanghai Univ, Inst Sustainable Energy, Coll Sci, Shanghai 200444, Peoples R China
  • [ 9 ] [Liu, Yiran]Shanghai Univ, Inst Sustainable Energy, Coll Sci, Shanghai 200444, Peoples R China
  • [ 10 ] [Zhang, Ying]Shanghai Univ, Inst Sustainable Energy, Coll Sci, Shanghai 200444, Peoples R China
  • [ 11 ] [Zhang, Jiujun]Shanghai Univ, Inst Sustainable Energy, Coll Sci, Shanghai 200444, Peoples R China
  • [ 12 ] [Zhao, Yufeng]Shanghai Univ, Inst Sustainable Energy, Coll Sci, Shanghai 200444, Peoples R China
  • [ 13 ] [Zhu, Xingbao]Got High Tech Co Ltd, Hefei 230012, Peoples R China
  • [ 14 ] [Zhang, Jiujun]Fuzhou Univ, Inst New Energy Mat & Engn, Sch Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China

Reprint 's Address:

  • [Jiao, Zheng]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China;;[Feng, Wuliang]Shanghai Univ, Inst Sustainable Energy, Coll Sci, Shanghai 200444, Peoples R China;;[Zhao, Yufeng]Shanghai Univ, Inst Sustainable Energy, Coll Sci, Shanghai 200444, Peoples R China

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Source :

ADVANCED ENERGY MATERIALS

ISSN: 1614-6832

Year: 2025

2 4 . 4 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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