Developing Thiols as a Versatile Organo-Photocatalyst for the Visible-Light-Mediated Polymerization - Details

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Thiols　are　well-established　hydrogen　atom　transfer　catalysts　for　organic　reaction　development　and　agents　for　polymer　modification　and　cross-linking.　Herein,　we　demonstrate　a　different　scenery　that　aryl　thiols　like　1-naphthalenethiol　and　1-pyrenethiol　(PySH)　can　also　act　as　a　photocatalyst　for　polymerization,　which　can　be　photoactivated　under　visible　light　to　function　as　a　photoacid　catalyst　to　promote　the　ring-opening　polymerization　of　lactones,　affording　well-defined　polymers　with　controlled　molecular　weights　and　narrowed　dispersities　(Đ　©　2025　American　Chemical　Society

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Atoms Atom transfer radical polymerization Cationic polymerization Crosslinking Photocatalysts

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[ 1 ] [Zhang, Xun]State Key Laboratory of Physical Chemistry of Solid Surfaces, Gulei Innovation Institute, Xiamen University, Xiamen; 361005, China
[ 2 ] [Zhang, Xun]School of Materials and Architectural Engineering (Guizhou School of Emergency Management), Guizhou Normal University, Huaxi University Town, Gui’an New District, Guizhou; 550025, China
[ 3 ] [Hu, Siping]Key Laboratory of Molecule Synthesis and Function Discovery, College of Chemistry, Fuzhou University, Fuzhou; 350116, China
[ 4 ] [Yang, Xue]State Key Laboratory of Physical Chemistry of Solid Surfaces, Gulei Innovation Institute, Xiamen University, Xiamen; 361005, China
[ 5 ] [Chusov, Denis A.]A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilova str., Moscow; 119334, Russia
[ 6 ] [Song, Jinshuai]College of Chemistry, Pingyuan Laboratory, Zhengzhou University, 100 Science Avenue, Zhengzhou; 450001, China
[ 7 ] [Liao, Saihu]State Key Laboratory of Physical Chemistry of Solid Surfaces, Gulei Innovation Institute, Xiamen University, Xiamen; 361005, China

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Source ：

ACS Catalysis

Year： 2025

Issue： 18

Volume： 15

Page： 16292-16299

1 1 . 7 0 0

JCR@2023

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