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author:

Peng, Jianzhao (Peng, Jianzhao.) [1] | Sun, Lidan (Sun, Lidan.) [2] | Li, Yongliang (Li, Yongliang.) [3] | Zhang, Qianling (Zhang, Qianling.) [4] | Ren, Xiangzhong (Ren, Xiangzhong.) [5] | Li, Xifei (Li, Xifei.) [6] | Zhang, Jiujun (Zhang, Jiujun.) [7] | Sun, Xueliang (Sun, Xueliang.) [8] | Song, Zhongxin (Song, Zhongxin.) [9] | Zhang, Lei (Zhang, Lei.) [10]

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Abstract:

In the context of the global greenhouse effect and energy scarcity, it is of great significance to convert carbon dioxide (CO2) into value-added fuels and chemicals through renewable electricity. Cu-based catalysts have been challenging for producing C1 and C2+ high-value chemicals in electrochemical CO2 reduction reaction (CO2RR). Plenty of research groups have engaged in the development of Cu-based catalysts with high activity, selectivity, and stability. This review comprehensively summarizes the recent progress in engineering Cu-based catalysts for CO2RR, with a detailed understanding of the reaction mechanism, catalyst design, and product selectivity. Besides, the strategies aiming at improving the stability of Cu-based catalysts and advancements in CO2RR electrolyzers are addressed. Finally, the future important research directions of Cu-based catalysts in practical CO2RR are prospected. © Shanghai University and Periodicals Agency of Shanghai University 2025.

Keyword:

Carbon dioxide Catalyst activity Catalyst selectivity Copper compounds Electrolytic reduction Product design

Community:

  • [ 1 ] [Peng, Jianzhao]College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, China
  • [ 2 ] [Sun, Lidan]College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, China
  • [ 3 ] [Li, Yongliang]College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, China
  • [ 4 ] [Zhang, Qianling]College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, China
  • [ 5 ] [Ren, Xiangzhong]College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, China
  • [ 6 ] [Li, Xifei]Shaanxi Engineering Research Center of Key Materials for Lithium/Sodium-Ion Batteries, Institute of Advanced Electrochemical Energy, School of Materials Science and Engineering, Xi’an University of Technology, Shaanxi, China
  • [ 7 ] [Zhang, Jiujun]Institute for New Energy Materials and Engineering, College of Materials Science and Engineering, Fuzhou University, Fujian, China
  • [ 8 ] [Sun, Xueliang]Shaanxi Engineering Research Center of Key Materials for Lithium/Sodium-Ion Batteries, Institute of Advanced Electrochemical Energy, School of Materials Science and Engineering, Xi’an University of Technology, Shaanxi, China
  • [ 9 ] [Sun, Xueliang]Department of Mechanical and Materials Engineering, The University of Western Ontario, London; ON; N6A 5B9, Canada
  • [ 10 ] [Sun, Xueliang]Eastern Institute for Advanced Study, Eastern Institute of Technology, Zhejiang, China
  • [ 11 ] [Song, Zhongxin]College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, China
  • [ 12 ] [Zhang, Lei]College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, China

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Source :

Electrochemical Energy Reviews

Year: 2025

Issue: 1

Volume: 8

2 8 . 5 0 0

JCR@2023

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ESI Highly Cited Papers on the List: 0 Unfold All

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30 Days PV: 0

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