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学者姓名:吕秋丰
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The rapid growth of industries and population has led to severe water pollution, especially from the oil and dyes pollution. Recently, MXene with hydrophilicity layer structure and excellent adsorption capacity has been regarded as a promising material for high efficiency dye adsorption and oil–water separation. In this study, aminated-SiO2 nanorods and monolayer Ti3C2Tx MXene were combined by a facile self-assembly method to prepare a new composite (NSx/MXene) for dye adsorption and oil–water separation. The results show that the adsorption capacity of the NSx/MXene composite was enhanced due to the introduction of aminated-SiO2 nanorods with more active sites. Especially, the NS2/MXene composite has a maximum adsorption capacity up to 4532.5 mg g−1 for AB74 dye, which is attributed to the electrostatic interaction between NS2/MXene and AB74 dye molecules. In addition, NS2/MXene modified polyurethane sponge (NS2/MXene@PU) was prepared by immersing dried polyurethane (PU) sponge in the NS2/MXene suspension. The NS2/MXene@PU sponge has a characteristic of superhydrophilicity in air and superoleophobicity in water, and shows a high separation flux of 27.44 × 104 L m−2 h−1 for a cyclohexane-water mixture. After 30 cycle experiments, the separation flux of NS2/MXene@PU for the cyclohexane-water mixture can still be 21.66 × 104 L m−2 h−1, indicating an excellent cycling stability of NS2/MXene@PU. Hence, this new NS2/MXene material has excellent application prospects in dye adsorption and oil–water separation. © 2024 Elsevier B.V.
Keyword :
Amination Amination Bioremediation Bioremediation Nanoribbons Nanoribbons Nanorods Nanorods Self assembly Self assembly Suspensions (fluids) Suspensions (fluids)
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GB/T 7714 | Chen, Xu-Han , Wang, Cheng-Zhen , Lü, Qiu-Feng . High efficiency dye adsorption and oil–water separation of aminated-SiO2 decorated monolayer Ti3C2Tx MXene [J]. | Journal of Molecular Liquids , 2025 , 418 . |
MLA | Chen, Xu-Han 等. "High efficiency dye adsorption and oil–water separation of aminated-SiO2 decorated monolayer Ti3C2Tx MXene" . | Journal of Molecular Liquids 418 (2025) . |
APA | Chen, Xu-Han , Wang, Cheng-Zhen , Lü, Qiu-Feng . High efficiency dye adsorption and oil–water separation of aminated-SiO2 decorated monolayer Ti3C2Tx MXene . | Journal of Molecular Liquids , 2025 , 418 . |
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Nickel-cobalt layered double hydroxide (NiCo-LDH) has received much attention in the field of supercapacitor electrodes due to its multiple oxidation states and good electrochemical activity. However, NiCo-LDH often suffers from structural instability and low conductivity in practical applications. In this study, sea urchin-like structural NiCo-LDH coated cobalt-nitrogen co-doped carbon (NiCo-LDH@Co-NC-x) electrode materials were prepared by in situ growth of NiCo-LDH on the surface of cobalt-nitrogen co-doped carbon nanosheets (Co-NC) using a one-step hydrothermal method. The results show that the NiCo-LDH@Co-NC-2 electrode material exhibits excellent electrochemical performance, its specific capacitance is up to 1909 F g- 1 at a current density of 1 A g- 1, and capacitance retention of 69.5 % (only 26.2 % for NiCo-LDH) can be achieved after 10,000 cycles at a current density of 10 A g- 1. This is because the abundant and uniformly distributed Co nanoparticles on Co-NC provide nucleation sites for the in-situ growth of NiCo-LDH, effectively improving the interface binding between Co-NC and NiCo-LDH, enhancing the structural stability of NiCo-LDH, and ensuring highly efficient electron transport throughout the NiCo-LDH@Co-NC-2 electrode. An asymmetric supercapacitor (NiCo-LDH@Co-NC-2// AC) was further assembled with NiCo-LDH@Co-NC-2 and activated carbon (AC) as positive and negative electrodes, respectively, achieving an energy density as high as 36.8 Wh kg- 1 at a power density of 750 W kg- 1. These findings suggest that the NiCo-LDH@Co-NC-2 composite can be a promising candidate for highperformance supercapacitor electrode.
Keyword :
Carbon nanosheets Carbon nanosheets Nickel-cobalt layered double hydroxide Nickel-cobalt layered double hydroxide Supercapacitor Supercapacitor
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GB/T 7714 | Fu, Yu-Gang , Li, Yi-Han , Lu, Qiu-Feng . In situ construction of sea urchin-like structural NiCo-LDH coated cobalt-nitrogen - nitrogen co-doped carbon as high-performance electrode for supercapacitor [J]. | JOURNAL OF ENERGY STORAGE , 2024 , 100 . |
MLA | Fu, Yu-Gang 等. "In situ construction of sea urchin-like structural NiCo-LDH coated cobalt-nitrogen - nitrogen co-doped carbon as high-performance electrode for supercapacitor" . | JOURNAL OF ENERGY STORAGE 100 (2024) . |
APA | Fu, Yu-Gang , Li, Yi-Han , Lu, Qiu-Feng . In situ construction of sea urchin-like structural NiCo-LDH coated cobalt-nitrogen - nitrogen co-doped carbon as high-performance electrode for supercapacitor . | JOURNAL OF ENERGY STORAGE , 2024 , 100 . |
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创新创业教育与专业教育融合是创新人才培养、专业内涵发展和创新创业教育发展的必然要求。针对目前两者融合不够深入的问题,福州大学高分子材料与工程专业从教育理念、师资队伍、课程设置和教学管理等方面进行改革探索,以期实现高质量人才培养目标,为科学研究和区域经济发展提供有力支撑。
Keyword :
专业教育 专业教育 创新创业教育 创新创业教育 教学改革 教学改革
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GB/T 7714 | 吕秋丰 , 黄艳 , 林起浪 et al. 创新创业教育与专业教育融合的探索——以福州大学高分子材料与工程专业为例 [J]. | 化工高等教育 , 2024 , 41 (04) : 51-57 . |
MLA | 吕秋丰 et al. "创新创业教育与专业教育融合的探索——以福州大学高分子材料与工程专业为例" . | 化工高等教育 41 . 04 (2024) : 51-57 . |
APA | 吕秋丰 , 黄艳 , 林起浪 , 林腾飞 . 创新创业教育与专业教育融合的探索——以福州大学高分子材料与工程专业为例 . | 化工高等教育 , 2024 , 41 (04) , 51-57 . |
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创新创业教育与专业教育融合是创新人才培养、专业内涵发展和创新创业教育发展的必然要求.针对目前两者融合不够深入的问题,福州大学高分子材料与工程专业从教育理念、师资队伍、课程设置和教学管理等方面进行改革探索,以期实现高质量人才培养目标,为科学研究和区域经济发展提供有力支撑.
Keyword :
专业教育 专业教育 创新创业教育 创新创业教育 教学改革 教学改革
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GB/T 7714 | 吕秋丰 , 黄艳 , 林起浪 et al. 创新创业教育与专业教育融合的探索 [J]. | 化工高等教育 , 2024 , 41 (4) : 51-57 . |
MLA | 吕秋丰 et al. "创新创业教育与专业教育融合的探索" . | 化工高等教育 41 . 4 (2024) : 51-57 . |
APA | 吕秋丰 , 黄艳 , 林起浪 , 林腾飞 . 创新创业教育与专业教育融合的探索 . | 化工高等教育 , 2024 , 41 (4) , 51-57 . |
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为培养适应社会发展需要的应用型创新人才,文章针对高分子化学实验课程传统教学存在的问题,提出了一种虚拟仿真实验教学与传统实验教学相结合的实验教学模式.该教学模式的实施,有助于弥补传统实验教学的不足,激发学生的学习兴趣,锻炼学生的实践能力和创新思维,提高教学质量和效率,促进应用型创新人才的培养.
Keyword :
实验教学 实验教学 虚实结合 虚实结合 虚拟仿真 虚拟仿真 高分子化学实验 高分子化学实验
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GB/T 7714 | 张夏兰 , 吕秋丰 , 靳艳巧 et al. 虚实结合的高分子化学实验课程教学改革探索 [J]. | 化工高等教育 , 2024 , 41 (4) : 142-149 . |
MLA | 张夏兰 et al. "虚实结合的高分子化学实验课程教学改革探索" . | 化工高等教育 41 . 4 (2024) : 142-149 . |
APA | 张夏兰 , 吕秋丰 , 靳艳巧 , 林起浪 . 虚实结合的高分子化学实验课程教学改革探索 . | 化工高等教育 , 2024 , 41 (4) , 142-149 . |
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Water-based biocarbon as an electrode material of supercapacitor for energy storage equipment has been widely studied because of its simple preparation, low cost, environmental friendliness and good cycle stability, but its low specific capacitance and energy density are the keys to hinder its development. In this study, 2D biocarbon nanosheets from kapok fibers were prepared via KOH activation. ACKF-2, an as-prepared activated biocarbon with an alkali-carbon mass ratio of 5:1, had a very high specific surface area of 3359.2 m2/g and a high pore volume of 2.1415 m3/g. Thus, ACKF-2 exhibits a high specific capacitance of 405 F/g at a current density of 1 A/g in a 6 mol/L KOH electrolyte. To further improve the electrochemical performance of ACKF-2, two redox additives, K3Fe(CN)6 and K4Fe(CN)6, were chosen as novel redox electrolytes. At a current density of 10 A/g, ACKF-2 showed a superhigh specific capacitance of 3380 F/g in the 1 mol/L H2SO4 electrolyte with adding K3Fe(CN)6 and K4Fe(CN)6. A symmetrical-supercapacitor device consisting of ACKF-2 and the new-type redox electrolyte can achieve an extremely high energy density of 264.1 Wh/kg at a high power density of 4593 W/kg. Therefore, this study provides a new energy storage scheme that can greatly improve the water-based carbon supercapacitor.
Keyword :
Activation Activation Biocarbon nanosheets Biocarbon nanosheets Kapok fiber Kapok fiber Redox additive Redox additive Supercapacitor Supercapacitor
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GB/T 7714 | Zheng, Xi , Lei, Ze-Le , Wang, Jun-Rui et al. Activated 2D biocarbon nanosheets from kapok fiber as an electrode material for supercapacitor with high energy density in redox electrolyte [J]. | BIOMASS & BIOENERGY , 2024 , 181 . |
MLA | Zheng, Xi et al. "Activated 2D biocarbon nanosheets from kapok fiber as an electrode material for supercapacitor with high energy density in redox electrolyte" . | BIOMASS & BIOENERGY 181 (2024) . |
APA | Zheng, Xi , Lei, Ze-Le , Wang, Jun-Rui , Lue, Qiu-Feng . Activated 2D biocarbon nanosheets from kapok fiber as an electrode material for supercapacitor with high energy density in redox electrolyte . | BIOMASS & BIOENERGY , 2024 , 181 . |
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The intensification of industrial production has led to a sharp increase in the discharge of toxic organic chemicals and wastewater from printing and dyeing industry. In this study, flower-like ZnO modified TiO 2 @Ti 3 C 2 T x composites (ZnO/TiO 2 @Ti 3 C 2 T x ) were prepared by in -situ oxidation solvothermal method from zinc nitrate hexahydrate and tetramethylammonium hydroxide intercalated Ti 3 C 2 T x . During the solvothermal processes, sodium hydroxide acted as an etchant to further exfoliated the accordion -like Ti 3 C 2 T x into single or few -layer; and at the same time, TiO 2 was formed in -situ on the surface of Ti 3 C 2 T x with simultaneous deposition of flower-like ZnO. The layer structural Ti 3 C 2 T x facilitates the loading and dispersion of ZnO and TiO 2 on its surface. After the in -situ oxidation by solvothermal method, TiO 2 was evenly distributed on the surface of Ti 3 C 2 T x , adjusting the functional groups on the surface of the ZnO/TiO 2 @Ti 3 C 2 T x composite, and improving its adsorption performance. ZnO/TiO 2 @Ti 3 C 2 T x can be used as an efficient adsorbent for malachite green with a high maximum adsorption capacity of 1232.7 mg g -1 , which is higher than that of TiO 2 @Ti 3 C 2 T x (628.57 mg g -1 ). Moreover, a superhydrophilic and underwater superoleophobic ZnO/TiO 2 @Ti 3 C 2 T x @PU sponge was prepared by loading ZnO/TiO 2 @Ti 3 C 2 T x onto polyurethane (PU) sponge. The introduction of ZnO enhances the surface roughness of the ZnO/TiO 2 @Ti 3 C 2 T x @PU sponge, which can effectively separate six oil -water mixtures, and has a high separation flux of 171784 L m - 2 h -1 and separation efficiency of 99.6% for cyclohexane-water mixture.
Keyword :
Adsorption Adsorption Malachite green Malachite green MXene MXene Oil-water separation Oil-water separation TiO2 TiO2 ZnO ZnO
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GB/T 7714 | Zhang, Kai-Ning , Lei, Ze-Le , Lu, Qiu-Feng . Flower-like ZnO modified TiO2@Ti3C2Tx composite for efficient adsorption of malachite green and oil-water separation [J]. | JOURNAL OF CLEANER PRODUCTION , 2024 , 447 . |
MLA | Zhang, Kai-Ning et al. "Flower-like ZnO modified TiO2@Ti3C2Tx composite for efficient adsorption of malachite green and oil-water separation" . | JOURNAL OF CLEANER PRODUCTION 447 (2024) . |
APA | Zhang, Kai-Ning , Lei, Ze-Le , Lu, Qiu-Feng . Flower-like ZnO modified TiO2@Ti3C2Tx composite for efficient adsorption of malachite green and oil-water separation . | JOURNAL OF CLEANER PRODUCTION , 2024 , 447 . |
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Poly (3,4-ethylenedioxythiophene) (PEDOT) is an electrically conductive polymer that is highly conductive and oxidatively stable. However, its poor cycling stability and small specific capacitance limit its application as an electrode material for supercapacitors. In this work, carbon nanotubes (CNTs) modified V-Ti3C2Tx/poly(3,4ethylenedioxythiophene) composite (CVT/PEDOT) was prepared by obtaining vanadium-doped Ti3C2Tx (VTi3C2Tx) using a simple hydrothermal method, and then polymerizing 3,4-ethylene-dioxythiophene monomers (EDOT) on the surface of carbon nanotubes modified V-Ti3C2Tx. The incorporation of CNTs with V-Ti3C2Tx results in better stability of CVT/PEDOT. The synergistic effect of the three components make the CVT/PEDOT composite have good electrochemical performance and excellent cycling stability as an electrode material for supercapacitor. The specific capacitance of CVT/PEDOT at a current density of 1 A g- 1 is up to 263 F g- 1, and the capacitance retention is 86 % after 5000 cycles at a current density of 10 A g- 1, which is superior to that of the VTi3C2Tx/PEDOT composite. The energy density of CVT/PEDOT is 15.26 Wh kg- 1 at a power density of 600 W kg- 1, which is higher than those of previously reported PEDOTs and other PEDOT-based composites. So, the CVT/PEDOT composite can be a potential candidate for electrode materials of supercapacitor.
Keyword :
CNTs CNTs Poly(3, 4-ethylenedioxythiophene) Poly(3, 4-ethylenedioxythiophene) Supercapacitor Supercapacitor Vanadium doping Vanadium doping
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GB/T 7714 | Lei, Ze-Le , Wan, Li , Lu, Qiu-Feng . Carbon nanotubes modified V-Ti3C2Tx/poly(3,4-ethylenedioxythiophene) composite as a high-performance electrode for supercapacitor [J]. | DIAMOND AND RELATED MATERIALS , 2024 , 150 . |
MLA | Lei, Ze-Le et al. "Carbon nanotubes modified V-Ti3C2Tx/poly(3,4-ethylenedioxythiophene) composite as a high-performance electrode for supercapacitor" . | DIAMOND AND RELATED MATERIALS 150 (2024) . |
APA | Lei, Ze-Le , Wan, Li , Lu, Qiu-Feng . Carbon nanotubes modified V-Ti3C2Tx/poly(3,4-ethylenedioxythiophene) composite as a high-performance electrode for supercapacitor . | DIAMOND AND RELATED MATERIALS , 2024 , 150 . |
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Traditional separation materials based on Ti3C2Tx modification are susceptible to contamination by oily sub-stances and have single performance, which limits their applications in treatment of actual oily wastewater. Here, to improve the hydrophilicity and stability of Ti3C2Tx, EHL-functionalized Ti3C2Tx (EHL-Ti3C2Tx) was prepared by enzymatic hydrolysis lignin (EHL) forming secondary bonds with the terminal oxygen-containing groups on the surface of Ti3C2Tx. EHL-Ti3C2Tx was further coated on polyurethane (PU) sponge to construct rough structures, enabling the modified EHL-Ti3C2Tx @PU sponge superhydrophilic/underwater super-oleophobic wettability to achieve separation efficiency above 99.5% for different oil/water mixtures. Especially, the maximum permeation flux of EHL-Ti3C2Tx @PU for cyclohexane/water mixture separation is up to 231,321 L m- 2 h-1. In addition, the functionalized interface constructed by EHL-Ti3C2Tx on mixed cellulose ester (MCE) membrane exhibits high permeability to malachite green and methylene blue cationic dyes with rejection rates of 99.1% and 98.1%, respectively. Therefore, two separation materials obtained by decorating EHL-Ti3C2Tx on PU and MCE substrates have extremely potential in treating complex wastewater.
Keyword :
Dye separation Dye separation Enzymatic hydrolysis lignin Enzymatic hydrolysis lignin High permeability High permeability Oil Oil water separation water separation
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GB/T 7714 | Wang, Qing-Ming , Liu, Zhen-Hui , Lu, Qiu-Feng . Lignin modified Ti3C2Tx assisted construction of functionalized interface for separation of oil/water mixture and dye wastewater [J]. | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS , 2023 , 656 . |
MLA | Wang, Qing-Ming et al. "Lignin modified Ti3C2Tx assisted construction of functionalized interface for separation of oil/water mixture and dye wastewater" . | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 656 (2023) . |
APA | Wang, Qing-Ming , Liu, Zhen-Hui , Lu, Qiu-Feng . Lignin modified Ti3C2Tx assisted construction of functionalized interface for separation of oil/water mixture and dye wastewater . | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS , 2023 , 656 . |
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The problems of easy oil contamination, easy oxidation, and low dye removal ability of 2D MXene hinder its practical application in high-efficiency oil/water separation and dye removal. In this study, Ti3C2Tx was first modified using NH3.H2O to obtain intercalated Ti3C2Tx (TN), and then, N-[3-(trimethoxysilyl) propyl] ethylenediamine (AEAPTMS) was used to conduct the surface aminated-modification of TN to achieve functional Ti3C2Tx (TN-AEAPTMS), which was then loaded onto polyurethane (PU) sponge to get TN-AEAPTMS@PU sponge. The low oil adhesion and super hydrophilicity/underwater super oleophobicity of TN-AEAPTMS@PU sponge enable excellent separation performance for oil/water mixtures of different densities. After being soaked in water for 45 days, TN-AEAPTMS can still maintain its original accordion-like morphology and hold good oil/water separation performance, overcoming the performance degradation caused by easy oxidation of Ti3C2Tx under water. More importantly, TN-AEAPTMS@MCE, which is acquired through vacuum suction filtration with TN-AEAPTMS loaded onto mixed cellulose ester microporous membrane, can remove various anionic and cationic organic dyes with high flux and removal rate, innovatively overcoming the poor adsorption performance of Ti3C2Tx for anionic dyes. Therefore, the TN-AEAPTMS composite exhibits excellent potential for practical applications in oil/water separation and dye removal.
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GB/T 7714 | Liu, Zhen-Hui , Cai, Wei-Qiu , Wang, Qing-Ming et al. Multifunctional applications of amino functionalized Ti3C2Tx: high flux oil/water separation and dye removal [J]. | NEW JOURNAL OF CHEMISTRY , 2023 , 47 (46) : 21381-21395 . |
MLA | Liu, Zhen-Hui et al. "Multifunctional applications of amino functionalized Ti3C2Tx: high flux oil/water separation and dye removal" . | NEW JOURNAL OF CHEMISTRY 47 . 46 (2023) : 21381-21395 . |
APA | Liu, Zhen-Hui , Cai, Wei-Qiu , Wang, Qing-Ming , Lu, Qiu-Feng . Multifunctional applications of amino functionalized Ti3C2Tx: high flux oil/water separation and dye removal . | NEW JOURNAL OF CHEMISTRY , 2023 , 47 (46) , 21381-21395 . |
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