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学者姓名：汤育欣
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Abstract ：
Polyethylene oxide (PEO)-based electrolytes are essential to advance all-solid-state lithium batteries (ASSLBs) with high safety/energy density due to their inherent flexibility and scalability. However, the inefficient Li+ transport in PEO often leads to poor rate performance and diminished stability of the ASSLBs. The regulation of intermolecular H-bonds is regarded as one of the most effective approaches to enable efficient Li+ transport, while the practical performances are hindered by the electrochemical instability of free H-bond donors and the constrained mobility of highly ordered H-bonding structures. To overcome these challenges, we develop a surface-confined disordered H-bond system with stable donor-acceptor interactions to construct a loosened chain segments/ions arrangement in the bulk phase of PEO-based electrolytes, realizing the crystallization inhibition of PEO, weak coordination of Li+ and entrapment of anions, which are conducive to efficient Li+ transport and stable Li+ deposition. The rationally designed LiFePO4-based ASSLB demonstrates a long cycle-life of over 400 cycles at 1.0 C and 65 degrees C with a capacity retention rate of 87.5 %, surpassing most of the currently reported polymer-based ASSLBs. This work highlights the importance of confined disordered H-bonds on Li+ transport in an all-solid-state battery system, paving the way for the future design of polymer-based ASSLBs.
Keyword ：
all-solid-state Li batteries all-solid-state Li batteries H-bond H-bond Li+ transport Li+ transport polyethylene oxide polyethylene oxide polymer electrolytes polymer electrolytes
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| GB/T 7714 | Fan, You , Malyi, Oleksandr I. , Wang, Huicai et al. Surface-Confined Disordered Hydrogen Bonds Enable Efficient Lithium Transport in All-Solid-State PEO-Based Lithium Battery [J]. | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION , 2025 . |
| MLA | Fan, You et al. "Surface-Confined Disordered Hydrogen Bonds Enable Efficient Lithium Transport in All-Solid-State PEO-Based Lithium Battery" . | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2025) . |
| APA | Fan, You , Malyi, Oleksandr I. , Wang, Huicai , Cheng, Xiangxin , Fu, Xiaobin , Wang, Jingshu et al. Surface-Confined Disordered Hydrogen Bonds Enable Efficient Lithium Transport in All-Solid-State PEO-Based Lithium Battery . | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION , 2025 . |
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The development of solid-state electrolytes for Li-metal batteries demands high ionic conductivity, interfacial compatibility, and robust mechanical strength to address lithium dendrite formation and manufacturing challenges. Herein, We report a high-performance SSE, designed via in-situ polymerization of cross-linked poly(vinyl carbonate) (PVC) on a LATSP-coated polypropylene (PP) separator, resulting a LATSP@PP-PVC composite solid electrolyte. The PP separator ensures mechanical strength, while the LATSP coating improves wettability and lithium salt dissociation. Additionally, the cross-linked PVC network restricts TFSI-ion migration, enhancing Li+ conductivity. As a result, the composite exhibits excellent mechanical properties (70 MPa tensile strength, 54 % tensile strain), alongside a room-temperature ionic conductivity (3.19 x 10-4 S cm-1) and a Li+ transference number of 0.468. Li metal batteries employing this SSE paired with LiFePO4 cathodes show 81.56 % capacity retention after 800 cycles at 2 C, demonstrating its potential for commercial solid-state batteries. These findings hold promise for advancing the commercialization of composite electrolytes for solid state batteries.
Keyword ：
Cross-linked network Cross-linked network In-situ polymerization In-situ polymerization Interfaces Interfaces LATSP@PP separator LATSP@PP separator Solid-state lithium metal batteries Solid-state lithium metal batteries
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| GB/T 7714 | Zhao, Wenlong , Wang, Huihui , Dong, Qingyu et al. Mechanical stable composite electrolyte for solid-state lithium metal batteries [J]. | CHEMICAL ENGINEERING JOURNAL , 2025 , 505 . |
| MLA | Zhao, Wenlong et al. "Mechanical stable composite electrolyte for solid-state lithium metal batteries" . | CHEMICAL ENGINEERING JOURNAL 505 (2025) . |
| APA | Zhao, Wenlong , Wang, Huihui , Dong, Qingyu , Shao, Hui , Zhang, Yanyan , Tang, Yuxin et al. Mechanical stable composite electrolyte for solid-state lithium metal batteries . | CHEMICAL ENGINEERING JOURNAL , 2025 , 505 . |
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Layered oxide cathodes show great promise for commercial applications due to their low cost, high specific capacity, and energy density. However, their rapid capacity decay and slow kinetics primarily caused by harmful phase transitions and a high energy barrier for Na+ diffusion result in inferior battery performance. Herein, we modulate the crystal structure of layered oxide cathodes by replacing the Fe3+ site with Al3+, which strengthens the transition metal layers and enlarges the Na translation layer owing to the smaller ion radius of Al3+ and the stronger bonding energy of Al-O. This restrains the Jahn-Teller effect owing to transition metal dissolution and improves the electrochemical kinetics. Consequently, the modified cathodes exhibited an excellent high-rate performance of 111 mA h g-1 at a high rate of 5.0C and an unexpectedly long cycling life with a 73.88% capacity retention rate after 500 cycles at 5.0C, whereas the bare cathode exhibited a rate performance of 97.3 mA h g-1 with a low capacity retention rate of 48.42% after 500 cycles at 5.0C. This study provides valuable insights into tuning the crystal structure for designing fast charging and highly stable O3-type cathodes.
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| GB/T 7714 | Lin, Jingping , Chen, Daoyuan , Lin, Zhimin et al. Crystal structure modulation enabling fast charging and stable layered sodium oxide cathodes [J]. | NANOSCALE , 2025 , 17 (16) : 10095-10104 . |
| MLA | Lin, Jingping et al. "Crystal structure modulation enabling fast charging and stable layered sodium oxide cathodes" . | NANOSCALE 17 . 16 (2025) : 10095-10104 . |
| APA | Lin, Jingping , Chen, Daoyuan , Lin, Zhimin , Hong, Zige , Chen, Qiuyan , Wang, Yating et al. Crystal structure modulation enabling fast charging and stable layered sodium oxide cathodes . | NANOSCALE , 2025 , 17 (16) , 10095-10104 . |
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Sodium-ion batteries (SIBs) with low cost and high safety are considered as an electrochemical energy storage technology suitable for large-scale energy storage. Hard carbon, which is inexpensive and has both high capacity and low sodium storage potential, is regarded as the most promising anode for commercial SIBs. However, the commercialization of hard carbon still faces technical issues of low initial Coulombic efficiency, poor rate performance, and insufficient cycling stability, due to the intrinsically irregular microstructure of hard carbon. To address these challenges, the rational design of the hard carbon microstructure is crucial for achieving high-performance SIBs, via gaining an in-depth understanding of its structure–performance correlations. In this context, our review firstly describes the sodium storage mechanism from the perspective of the hard carbon microstructure's formation. We then summarize the state-of-art development of hard carbon, providing a critical overview of emergence of hard carbon in terms of precursor selection, microstructure design, and electrolyte regulation to optimize strategies for addressing practical problems. Finally, we highlight directions for the future development of hard carbon to achieve the commercialization of high-performance SIBs. We believe this review will serve as basic guidance for the rational design of hard carbon and stimulate more exciting research into other types of energy storage devices. © 2023 The Authors
Keyword ：
Controllable microstructure Controllable microstructure Coulombic efficiency Coulombic efficiency Electrolyte regulation Electrolyte regulation Hard carbon Hard carbon Sodium-ion batteries Sodium-ion batteries Sodium storage mechanism Sodium storage mechanism
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| GB/T 7714 | Wang, F. , Jiang, Z. , Zhang, Y. et al. Revitalizing sodium-ion batteries via controllable microstructures and advanced electrolytes for hard carbon [J]. | eScience , 2024 , 4 (3) . |
| MLA | Wang, F. et al. "Revitalizing sodium-ion batteries via controllable microstructures and advanced electrolytes for hard carbon" . | eScience 4 . 3 (2024) . |
| APA | Wang, F. , Jiang, Z. , Zhang, Y. , Li, J. , Wang, H. , Jiang, Y. et al. Revitalizing sodium-ion batteries via controllable microstructures and advanced electrolytes for hard carbon . | eScience , 2024 , 4 (3) . |
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Abstract ：
Sodium-ion batteries (SIBs) with low cost and high safety are considered as an electrochemical energy storage technology suitable for large-scale energy storage. Hard carbon, which is inexpensive and has both high capacity and low sodium storage potential, is regarded as the most promising anode for commercial SIBs. However, the commercialization of hard carbon still faces technical issues of low initial Coulombic efficiency, poor rate performance, and insufficient cycling stability, due to the intrinsically irregular microstructure of hard carbon. To address these challenges, the rational design of the hard carbon microstructure is crucial for achieving highperformance SIBs, via gaining an in-depth understanding of its structure-performance correlations. In this context, our review firstly describes the sodium storage mechanism from the perspective of the hard carbon microstructure's formation. We then summarize the state-of-art development of hard carbon, providing a critical overview of emergence of hard carbon in terms of precursor selection, microstructure design, and electrolyte regulation to optimize strategies for addressing practical problems. Finally, we highlight directions for the future development of hard carbon to achieve the commercialization of high-performance SIBs. We believe this review will serve as basic guidance for the rational design of hard carbon and stimulate more exciting research into other types of energy storage devices.
Keyword ：
Controllable microstructure Controllable microstructure Coulombicefficiency Coulombicefficiency Electrolyte regulation Electrolyte regulation Hard carbon Hard carbon Sodium-ion batteries Sodium-ion batteries Sodium storage mechanism Sodium storage mechanism
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| GB/T 7714 | Wang, Feng , Jiang, Zhenming , Zhang, Yanyan et al. Revitalizing sodium-ion batteries via controllable microstructures and advanced electrolytes for hard carbon [J]. | ESCIENCE , 2024 , 4 (3) . |
| MLA | Wang, Feng et al. "Revitalizing sodium-ion batteries via controllable microstructures and advanced electrolytes for hard carbon" . | ESCIENCE 4 . 3 (2024) . |
| APA | Wang, Feng , Jiang, Zhenming , Zhang, Yanyan , Zhang, Yanlei , Li, Jidao , Wang, Huibo et al. Revitalizing sodium-ion batteries via controllable microstructures and advanced electrolytes for hard carbon . | ESCIENCE , 2024 , 4 (3) . |
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The plateau-type sodium titanate with suitable sodiation potential is a promising anode candidate for high safe and high energy density of sodium-ion batteries (SIBs). However, the poor initial Coulombic efficiency (ICE) and cyclic instability of sodium titanate are attributed to the unstable interfacial structure along with the decomposition of electrolytes, resulting in the continuous formation of solid electrolyte interface (SEI) film. To address this issue, a chemical grafting method is developed to fabricate a highly stable interface layer of inert Al2O3 on the sodium titanate anode, rendering the high ICE and excellent cycling stability. Based on theoretical calculations, NaPF6 are more likely adsorption on the Al2O3 surface and produce sodium fluoride. The formation of a thin and dense SEI film with rich sodium fluoride achieves the low interfacial resistances and charge-transfer resistances. Benefitting from our design, the obtained sodium titanate exhibits a high ICE from 67.7 % to 79.4 % and an enhanced reversible capacity from 151 mAh g-1 to 181 mAh g-1 at 20 mA g-1, along with an increase in capacity retention from 56.5 % to 80.6 % after 500 cycles. This work heralds a promising paradigm for rational regulation of interfacial stability to achieve high-performance anodes for SIBs. A chemical grafting method is developed to fabricate a highly stable interface layer of inert Al2O3 on the sodium titanate anode, rendering the high initial Coulombic efficiency (ICE) and excellent cycling stability. This is due to the formation of a thin and dense solid-electrolyte interface (SEI) film with rich sodium fluoride, leading to the lower interfacial resistances and charge-transfer resistances.+ image
Keyword ：
heterostructure-layer heterostructure-layer initial Coulombic efficiency initial Coulombic efficiency Plateau-type sodium titanate Plateau-type sodium titanate sodium-ion batteries sodium-ion batteries
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| GB/T 7714 | Zhang, Yanlei , Li, Linwei , Wang, Feng et al. Achieving High Initial Coulombic Efficiency and Capacity in a Surface Chemical Grafting Layer of Plateau-type Sodium Titanate [J]. | CHEMSUSCHEM , 2024 , 17 (11) . |
| MLA | Zhang, Yanlei et al. "Achieving High Initial Coulombic Efficiency and Capacity in a Surface Chemical Grafting Layer of Plateau-type Sodium Titanate" . | CHEMSUSCHEM 17 . 11 (2024) . |
| APA | Zhang, Yanlei , Li, Linwei , Wang, Feng , Wang, Huicai , Jiang, Zhenming , Lin, Zhimin et al. Achieving High Initial Coulombic Efficiency and Capacity in a Surface Chemical Grafting Layer of Plateau-type Sodium Titanate . | CHEMSUSCHEM , 2024 , 17 (11) . |
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Since limited energy density and intrinsic safety issues of commercial lithium-ion batteries (LIBs), solid-state batteries (SSBs) are promising candidates for next-generation energy storage systems. However, their practical applications are restricted by interfacial issues and kinetic problems, which result in energy density decay and safety failure. This review discusses the formation mechanisms of these issues from the perspective of typical solid-state electrolytes (SSEs) and provides an overview of recent advanced anode engineering for SSBs based on representative anodes including Li metal, graphite-based, and Si-based anodes, summarizing the advantages and problems of each strategy. The development of the anode-free batteries concept is demonstrated as well. Finally, recommendations are proposed for the potential directions in future research in anode engineering for SSBs. © The Author(s) 2024.
Keyword ：
anode materials anode materials interfacial contact interfacial contact Li dendrite growth Li dendrite growth solid-state batteries solid-state batteries
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| GB/T 7714 | Zheng, Y. , Shen, Y. , Guo, J. et al. Recent advances in solid-state lithium batteries based on anode engineering [J]. | Nano Research Energy , 2024 , 3 (3) . |
| MLA | Zheng, Y. et al. "Recent advances in solid-state lithium batteries based on anode engineering" . | Nano Research Energy 3 . 3 (2024) . |
| APA | Zheng, Y. , Shen, Y. , Guo, J. , Li, J. , Wang, J. , Ning, D. et al. Recent advances in solid-state lithium batteries based on anode engineering . | Nano Research Energy , 2024 , 3 (3) . |
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Solid-state lithium batteries(SSLBs)with high safety have emerged to meet the increasing energy density demands of electric vehicles,hybrid electric vehicles,and portable electronic devices.However,the dendrite formation,high interfacial resistance,and deleterious interfacial reactions caused by solid-solid contact between electrode and electrolyte have hindered the commercialization of SSLBs.Thus,in this review,the state-of-the-art developments in the rational design of solid-state electrolyte and their progression toward practical applications are reviewed.First,the origin of interface instability and the sluggish charge carrier transportation in solid-solid interface are presented.Second,various strategies toward stabilizing interfacial stability(reducing interfacial resistance,suppressing lithium dendrites,and side reactions)are summarized from the physical and chemical perspective,including building protective layer,constructing 3D and gradient structures,etc.Finally,the remaining challenges and future development trends of solid-state electrolyte are prospected.This review provides a deep insight into solving the interfacial instability issues and promising solutions to enable practical high-energy-density lithium metal batteries.
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| GB/T 7714 | Honggang He , Litong Wang , Malek Al-Abbasi et al. Interface Engineering on Constructing Physical and Chemical Stable Solid-State Electrolyte Toward Practical Lithium Batteries [J]. | 能源与环境材料（英文） , 2024 , 7 (4) : 24-43 . |
| MLA | Honggang He et al. "Interface Engineering on Constructing Physical and Chemical Stable Solid-State Electrolyte Toward Practical Lithium Batteries" . | 能源与环境材料（英文） 7 . 4 (2024) : 24-43 . |
| APA | Honggang He , Litong Wang , Malek Al-Abbasi , Chunyan Cao , Heng Li , Zhu Xu et al. Interface Engineering on Constructing Physical and Chemical Stable Solid-State Electrolyte Toward Practical Lithium Batteries . | 能源与环境材料（英文） , 2024 , 7 (4) , 24-43 . |
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Aqueous zinc-iodine (Zn-I2) batteries have attracted considerable research interest as an alternative energy storage system due to their high specific capacity, intrinsic safety, and low cost. However, the notorious shuttle effect of soluble polyiodides causes severe capacity loss and poor electrochemical reversibility, restricting their practical usage. Herein, this study reports a bifunctional binder (polyacrylonitrile copolymer, as known as LA133) with strong iodine-chemisorption capability for aqueous Zn-I2 batteries to suppress polyiodide shuttling. From both calculation and experimental data, this study reveals that the amide and carboxyl groups in LA133 binder can strongly bond to polyiodides, significantly immobilizing them at cathode side. As a result, fewer byproducts, slower hydrogen evolution, and lesser Zn dendrite in the Zn-I2 battery are observed. Consequently, the battery shows high specific capacity (202.8 mAh g-1) with high iodine utilization efficiency (96.1%), and long cycling lifespan (2700 cycles). At the high mass loading of 7.82 mg cm-2, the battery can still retain 83.3% of its initial capacity after 1000 cycles. The specific capacity based on total cathode slurry mass reaches 71.2 mAh g-1, higher than most of the recent works. The strategy opens a new avenue to address the shuttling challenge of Zn-I2 batteries through bifunctional binder. A new bifunctional LA133 binder with strong iodine-chemisorption capability is reported for high-loading and shuttle-free Zn-I2 batteries. The oxygen-containing groups in LA133 binder can generate strong interactions with I2 and polyiodides, thus significantly enhancing the iodine immobilization performance. This work provides a new strategy to address the shuttling challenge of Zn-I2 batteries from functional binder design. image
Keyword ：
bifunctional binder bifunctional binder chemical confinement chemical confinement shuttle effect shuttle effect zinc-iodine batteries zinc-iodine batteries Zn corrosion Zn corrosion
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| GB/T 7714 | Wang, Kexuan , Li, Heng , Xu, Zhu et al. An Iodine-Chemisorption Binder for High-Loading and Shuttle-Free Zn-Iodine Batteries [J]. | ADVANCED ENERGY MATERIALS , 2024 , 14 (17) . |
| MLA | Wang, Kexuan et al. "An Iodine-Chemisorption Binder for High-Loading and Shuttle-Free Zn-Iodine Batteries" . | ADVANCED ENERGY MATERIALS 14 . 17 (2024) . |
| APA | Wang, Kexuan , Li, Heng , Xu, Zhu , Liu, Yupeng , Ge, Mingzheng , Wang, Huibo et al. An Iodine-Chemisorption Binder for High-Loading and Shuttle-Free Zn-Iodine Batteries . | ADVANCED ENERGY MATERIALS , 2024 , 14 (17) . |
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Layered structure Na2Ti3O7 with a suitable sodiation plateau potential (similar to 0.3 V vs Na+/Na) is a promising anode for highly safe sodium-ion batteries (SIBs). However, the practical use of Na2Ti3O7 is hindered by the unstable interface that forms between the anode and electrolyte leading to issues such as low initial coulombic efficiency (ICE) and cycling instability. Herein, we introduce tetraethyl orthosilicate (TEOS) as an electrolyte additive that can spontaneously and effectively react with the main component of the detrimental surface corrosion layer (sodium hydroxide, etc.) to form a protective film on the Na2Ti3O7 anode. The Na2Ti3O7 anode exhibits an enhanced capacity from 134.8 to 167.1 mAh g(-1) at 0.1 A g(-1), along with an increase in capacity retention from 56.1 to 83.9% after 250 cycles at 0.2 A g(-1). This work provides a straightforward protection strategy to address the unstable interface issues, rendering sodium titanate as a promising anode material to achieve practical application in the future.
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| GB/T 7714 | Jiang, Zhenming , Ke, Haifeng , Zhang, Yanlei et al. Building a Stable Plateau-Type Na2Ti3O7 Anode Interface toward Advanced Sodium-Ion Batteries [J]. | ENERGY & FUELS , 2024 , 38 (3) : 2472-2479 . |
| MLA | Jiang, Zhenming et al. "Building a Stable Plateau-Type Na2Ti3O7 Anode Interface toward Advanced Sodium-Ion Batteries" . | ENERGY & FUELS 38 . 3 (2024) : 2472-2479 . |
| APA | Jiang, Zhenming , Ke, Haifeng , Zhang, Yanlei , Li, Linwei , Wang, Feng , Li, Jidao et al. Building a Stable Plateau-Type Na2Ti3O7 Anode Interface toward Advanced Sodium-Ion Batteries . | ENERGY & FUELS , 2024 , 38 (3) , 2472-2479 . |
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