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学者姓名：章培昆
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UV curable coatings have been widely used for their advantages of environmental protection and high curing efficiency. However, there are also some problems in the use of UV curable coatings, such as poor light transmission of colored coatings, shadow parts are difficult to accept light and can not be cured. In order to solve the problems existing in the curing process of UV curable coatings, the establishment of UV/ moisture dual curing system can effectively solve these problems. Using castor oil (CO), polytetramethylene ether glycol (PTMEG), isophorone diisocyanate (IPDI), hydroxyethyl methacrylate (HEMA) and tetrahydrofuran acrylate (THFA) as raw materials, a series of polyurethane prepolymers were synthesized by structural design and a series of UV/ moisture dual-curable coatings were prepared. The experimental verification, UV/ moisture dual curing system coating, not only solves the problem of traditional UV coating curing, and has better performance than UV coating, coating curing dual curing coating has excellent heat resistance and mechanical strength, tensile strength up to 8.4 MPa, small volume shrinkage, excellent weather resistance. This is a curing strategy for UV coatings that cannot fully accept UV light, and provides a new idea for the preparation of new environmentally friendly coatings by bio-based materials.
Keyword ：
Acrylate Acrylate Castor oil Castor oil Polyurethane Polyurethane UV/moisture dual-curing UV/moisture dual-curing
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| GB/T 7714 | Ding, Ao , Zhang, Pengfei , Zhou, Bing et al. Structural design and performance study of a biobased UV/moisture dual-curing coating for UV inadequate curing conditions [J]. | MATERIALS TODAY COMMUNICATIONS , 2025 , 44 . |
| MLA | Ding, Ao et al. "Structural design and performance study of a biobased UV/moisture dual-curing coating for UV inadequate curing conditions" . | MATERIALS TODAY COMMUNICATIONS 44 (2025) . |
| APA | Ding, Ao , Zhang, Pengfei , Zhou, Bing , Liu, Guang , Xu, Pingfan , Luo, Yaofa et al. Structural design and performance study of a biobased UV/moisture dual-curing coating for UV inadequate curing conditions . | MATERIALS TODAY COMMUNICATIONS , 2025 , 44 . |
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LED curing technology makes up for some drawbacks of UV mercury lamps with its merits of no ozone emission and low energy consumption, and gradually replaces traditional UV mercury lamps in numerous fields. Nevertheless, a solitary LED curing coating struggles to fulfill the requirements in terms of curing depth, curing chroma, and comprehensive performance. Based on these, four types of polyurethane acrylate (PUA) coatings were fabricated through two-step synthesis and LED/moisture dual curing technology using cycloaliphatic isocyanate (IPDI), aliphatic isocyanate (HDI), monofunctional acrylate (HEMA), and trifunctional acrylate (PETA) as the primary raw materials. The dual curing system integrates the advantages of LED curing and moisture curing, and mitigates the shortcomings of incomplete curing and poor comprehensive performance of single LED. The experimental results show that these four dual-curing coatings show a certain degree of optimization in comprehensive properties such as curing properties, thermal properties, mechanical properties, and coating properties. In particular, the dual-curing coating prepared with HDI as the hard segment and PETA as the endcapping agent has a surface drying time of only 5 s. After dual curing, the gel content, water contact angle, tensile strength, shear strength, hardness, and adhesive force of the sample can respectively reach 97.8 %, 112.4 degrees, 17.26 MPa, 3.7 MPa, 58.5 Shore D, and 5 B. Additionally, the coating also exhibited outstanding solvent resistance, with the absorption rates of 0.35 %, 8.42 %, 1.35 %, and 1.16 % respectively after 48 h immersion in water, ethanol, 10 wt% NaOH, and 10 wt% HCl solutions. It is also notable that the curing depth of the dual-cured coating can reach 8.96 mm, which is significantly higher than the 3.76 mm of the single light curing, and the colored curing is complete. Four kinds of coatings can be selected and customized in accordance with diverse application requirements, which is of great significance for the further development of environmental protection coatings and holds substantial practical value in industrial production.
Keyword ：
Comprehensive properties Comprehensive properties Isocyanate group Isocyanate group LED/moisture dual-curing system LED/moisture dual-curing system Polyurethane acrylate Polyurethane acrylate
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| GB/T 7714 | Luo, Yaofa , Liu, Guang , Xu, Pingfan et al. Structural design and preparation of LED/moisture dual-cured polyurethane acrylate coatings with comprehensive properties [J]. | PROGRESS IN ORGANIC COATINGS , 2025 , 200 . |
| MLA | Luo, Yaofa et al. "Structural design and preparation of LED/moisture dual-cured polyurethane acrylate coatings with comprehensive properties" . | PROGRESS IN ORGANIC COATINGS 200 (2025) . |
| APA | Luo, Yaofa , Liu, Guang , Xu, Pingfan , Ding, Ao , Zhang, Peikun , Zhang, Pengfei et al. Structural design and preparation of LED/moisture dual-cured polyurethane acrylate coatings with comprehensive properties . | PROGRESS IN ORGANIC COATINGS , 2025 , 200 . |
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An adaptive Ni-based catalyst derived from soluble nickel-bipyridine [Ni(bpy)3]2+ exhibits increased active sites, and yet is nearly transparent to solar light; hence, this catalyst on nickel-sputtered Si exhibits a 250 mV negative shift of overpotential at 20 mA cm-2 relative to the pristine Ni/Si photoanode.
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| GB/T 7714 | Zhang, Qiu , Zhang, Peikun , Cui, Chunhua . A nearly transparent Ni-based oxygen-evolving catalyst for photoelectrocatalysis [J]. | CHEMICAL COMMUNICATIONS , 2025 , 61 (32) : 5978-5981 . |
| MLA | Zhang, Qiu et al. "A nearly transparent Ni-based oxygen-evolving catalyst for photoelectrocatalysis" . | CHEMICAL COMMUNICATIONS 61 . 32 (2025) : 5978-5981 . |
| APA | Zhang, Qiu , Zhang, Peikun , Cui, Chunhua . A nearly transparent Ni-based oxygen-evolving catalyst for photoelectrocatalysis . | CHEMICAL COMMUNICATIONS , 2025 , 61 (32) , 5978-5981 . |
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Three-dimensional (3D) thermally conductive boron nitride (BN)/polymer composites show significant potential in the field of thermal management. This review surveys current advances and discusses the thermal conductivity mechanisms of BN/polymer composites and the critical factors influencing their performance. A thorough introduction to the construction methods of 3D thermally conductive BN/polymer composites is provided, along with an objective discussion of their advantages and disadvantages. Notably, this review specifically highlights the effects of 3D thermally conductive networks on phonon transmission, interfacial thermal resistance, and thermal conductivity, as well as their interactions, and points out recent innovative trends in constructing 3D thermal composites by integrating BN with other dimensional fillers (0D, 1D, and 2D fillers). These approaches demonstrate promising strategies for optimizing thermal management by leveraging the unique advantages of each dimensional filler. The review concludes with a summary and outlook on the development of 3D thermally conductive BN/polymer composites. This aims to provide theoretical analysis, advance practical applications, and enhance next-generation thermal management systems.
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| GB/T 7714 | Liu, Guang , Xu, Pingfan , Luo, Zhongzhen et al. Dimensional synergy in 3D thermally conductive boron nitride/polymer composites [J]. | APPLIED PHYSICS REVIEWS , 2025 , 12 (2) . |
| MLA | Liu, Guang et al. "Dimensional synergy in 3D thermally conductive boron nitride/polymer composites" . | APPLIED PHYSICS REVIEWS 12 . 2 (2025) . |
| APA | Liu, Guang , Xu, Pingfan , Luo, Zhongzhen , Zhang, Li , Luo, Yaofa , Zhang, Peikun et al. Dimensional synergy in 3D thermally conductive boron nitride/polymer composites . | APPLIED PHYSICS REVIEWS , 2025 , 12 (2) . |
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Janus membranes, characterized by asymmetric wettability, have demonstrated exceptional potential in unidirectional oil transport and oil/water separation. Nevertheless, conventional fabrication strategies relying on bilayer/multilayer composites frequently encounter compromised separation performance due to weak interfacial binding and poor pore connectivity. Herein, we propose a monolayer biodegradable Janus membrane through electrospinning followed by plasma modification. Results indicate that the Janus membrane exhibits pronounced surface wettability contrast, with air-water contact angles of 36.3 degrees (hydrophilic side) and 138.8 degrees (hydrophobic side), coupled with underwater oil contact angles of 151.8 degrees (superoleophobic) and 67.5 degrees (oleophilic), respectively. The Janus membrane achieved 99.28 % separation efficiency and a maximum flux of 2779.9 L m-2 & sdot;h-1 across diverse oil/water mixtures. Notably, Laplace pressure gradients arising from the wettability asymmetry drive unidirectional oil transport from the hydrophobic to hydrophilic interface, enabling continuous oil harvesting in prototype spill recovery systems. Furthermore, the membrane demonstrates full biodegradability under industrial composting conditions (97.67 % biodegradation rate after 90 days), addressing the persistent microplastic pollution caused by conventional non-degradable membranes. This work pioneers a structurally integrated, eco-friendly Janus membrane platform that synergizes high-performance separation with environmental sustainability.
Keyword ：
Biodegradable Janus membrane Biodegradable Janus membrane Electrospinning Electrospinning Oil/water separation Oil/water separation PBAT/PLA PBAT/PLA Plasma treatment Plasma treatment
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| GB/T 7714 | Lin, Hongshen , Yu, Fangxia , Liang, Jingxi et al. Biodegradable Janus membrane for oil/water separation and unidirectional oil transport via electrospinning and plasma treatment [J]. | JOURNAL OF CLEANER PRODUCTION , 2025 , 525 . |
| MLA | Lin, Hongshen et al. "Biodegradable Janus membrane for oil/water separation and unidirectional oil transport via electrospinning and plasma treatment" . | JOURNAL OF CLEANER PRODUCTION 525 (2025) . |
| APA | Lin, Hongshen , Yu, Fangxia , Liang, Jingxi , Bai, Shenao , Cai, Rongzong , Xu, Pingfan et al. Biodegradable Janus membrane for oil/water separation and unidirectional oil transport via electrospinning and plasma treatment . | JOURNAL OF CLEANER PRODUCTION , 2025 , 525 . |
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A thermal conductive structural adhesive (TCSA) plays a crucial role in battery performance and safety. TCSA made of polyurethane (PU) has not only a good thermal conductivity but also good mechanical strength and substrate bonding strength. However, it has to be cost-effective and easy to be prepared. This work aims to synthesize a series of castor oil-based PU TCSAs with different amounts of thermal conductive powder using commercially available castor oil polyols, isocyanates, Al2O3, and additives. The shear strength of the TCSA containing 88% thermally conductivity powder reached 5.6 MPa, which was similar to that without the thermal conductivity fillers, but its toughness significantly decreased. Its thermal conductivity was as high as 1.8 W/mK, and it was thermally stable below 270 degrees C. Preparation process of castor oil based TCSA and application scenarios in new energy batteries. image
Keyword ：
adhesives adhesives biodegradable biodegradable coatings coatings conducting polymers conducting polymers polyurethane polyurethane
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| GB/T 7714 | Ding, Ao , Liu, Guang , Xu, Pingfan et al. Design of castor oil-based polyurethane thermal conductive structural adhesive for new energy batteries [J]. | JOURNAL OF APPLIED POLYMER SCIENCE , 2024 , 141 (24) . |
| MLA | Ding, Ao et al. "Design of castor oil-based polyurethane thermal conductive structural adhesive for new energy batteries" . | JOURNAL OF APPLIED POLYMER SCIENCE 141 . 24 (2024) . |
| APA | Ding, Ao , Liu, Guang , Xu, Pingfan , Wang, Yixin , Zheng, Yuying , Luo, Yaofa et al. Design of castor oil-based polyurethane thermal conductive structural adhesive for new energy batteries . | JOURNAL OF APPLIED POLYMER SCIENCE , 2024 , 141 (24) . |
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Graphene oxide (GO)-based intelligent fire alarm sensor (FAS) has recently been a sought-after research topic in fire prevention fields. However, it remains a challenge to facilely construct GO-based composite that simultaneously possess mechanical flexibility, excellent flame resistance, highly-sensitive temperature-responsive behavior, rapid fire response and ultra-long fire alarming durability. Here, a nacre-like ternary hybrid paper is conveniently obtained by integrating GO with hexachlorophosphazene-based multi-hydroxyl molecule (HHACP) and tannic acid (TA) via a facile and eco-friendly water evaporation-induced self-assembly method. The resultant composite paper (TA-GO/HHACP) exhibits mechanically flexible property with tensile strength of 103.7 MPa and toughness of 1.51 MJ/m(3), comparable to 2.52 and 5.39 times higher than those of pure GO paper. Further, the TA-GO/HHACP paper displays excellent nonflammability and high-temperature resistance that can withstand continuous butane flame attack (similar to 1200 degree celsius), resulting in ultra-long sustained alarming period of > 1600 s under an open fire. More importantly, benefiting from its rapid electrical resistance reduction capability, such TA-GO/HHACP paper demonstrates ultra-fast fire-triggered response time of similar to 0.6 s, and ultra-sensitive early fire alarm responses to abnormal high temperatures during pre-combustion process, e.g., similar to 1 s at 250 degree celsius and similar to 19 s at 200 degree celsius, respectively, outperforming the best reported GO-based FAS counterparts. This work provides an inventive paradigm to develop high-performance GO-based intelligent materials with reliable and sensitive early fire-warning function.
Keyword ：
Fire warning Fire warning Flame resistance Flame resistance Graphene oxide Graphene oxide Mechanical flexibility Mechanical flexibility Tannic acid Tannic acid Temperature response Temperature response
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| GB/T 7714 | Zhang, Peikun , Wang, Yueyan , Mao, Cong et al. Mechanically flexible graphene oxide network for highly-sensitive and ultra-long fire warning [J]. | CHEMICAL ENGINEERING JOURNAL , 2024 , 494 . |
| MLA | Zhang, Peikun et al. "Mechanically flexible graphene oxide network for highly-sensitive and ultra-long fire warning" . | CHEMICAL ENGINEERING JOURNAL 494 (2024) . |
| APA | Zhang, Peikun , Wang, Yueyan , Mao, Cong , Mao, Shuai , Peng, Jinyan , Zhang, Li et al. Mechanically flexible graphene oxide network for highly-sensitive and ultra-long fire warning . | CHEMICAL ENGINEERING JOURNAL , 2024 , 494 . |
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Polymer matrix composites with excellent thermal management performance have emerged as remarkable materials in the realms of microelectronic devices and wireless communication technologies. However, achieving high thermal conductivity in most composites often requires a high filling load, which will compromise other desirable properties. Herein, utilizing physical foaming and vacuum infiltration methods, we introduce a 3D honeycomb composite consisting of surface-hydroxylated hexagonal boron nitride (OH-BN) and epoxy. The 3D OH-BN honeycomb foam in the composite features a lightweight design (0.33 g/cm3), high strength (7178 times its own weight) and prominent heat transfer performance. Significantly, these composites achieve notable thermal properties, including high through-plane thermal conductivity (2.073 W m- 1 K-1) and relatively low thermal resistance (0.995 degrees C/W) at a reduced filling load (17.2 vol%). In comparison with pure epoxy, the through-plane thermal conductivity is enhanced by an impressive 894 %, while the thermal resistance is reduced to 1/9.4 of that observed in pure epoxy. Besides, the 3D honeycomb composites combine outstanding mechanical performance, low dielectric properties and excellent insulation, underscoring their potential in the field of thermal management applications in microelectronic devices, wireless communication systems and integrated circuits.
Keyword ：
3D thermal conduction networks 3D thermal conduction networks Boron nitride Boron nitride Epoxy composites Epoxy composites Thermal management Thermal management Thermal resistance Thermal resistance
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| GB/T 7714 | Liu, Guang , Ding, Ao , Xu, Pingfan et al. Thermal conductivity of epoxy composites containing 3D honeycomb boron nitride filler [J]. | CHEMICAL ENGINEERING JOURNAL , 2024 , 489 . |
| MLA | Liu, Guang et al. "Thermal conductivity of epoxy composites containing 3D honeycomb boron nitride filler" . | CHEMICAL ENGINEERING JOURNAL 489 (2024) . |
| APA | Liu, Guang , Ding, Ao , Xu, Pingfan , Zhu, Minmin , Zhang, Haizhong , Zheng, Yuying et al. Thermal conductivity of epoxy composites containing 3D honeycomb boron nitride filler . | CHEMICAL ENGINEERING JOURNAL , 2024 , 489 . |
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采用硅烷偶联剂为桥梁将聚六亚甲基双胍盐酸盐(PHMB)接枝在纳米二氧化钛(TiO2)表面制备了 TiO2-PHMB抗菌剂,再将其与聚己二酸-对苯二甲酸丁二酯/聚乳酸(PBAT/PLA)熔融共混造粒并吹制得到PBAT/PLA/TiO2-PHMB生物降解抗菌保鲜膜,研究了不同含量抗菌剂对保鲜膜形态结构、力学性能、热稳定性能、水蒸气透过率及抗菌性能的影响.结果表明,当TiO2-PHMB抗菌剂添加量为1％时,PBAT/PLA/TiO2-PHMB生物降解抗菌保鲜膜的纵横向拉伸强度分别提升了 11.7％和13.7％,断裂伸长率维持在658％和536％,水蒸气透过率降低了 12.50％,对大肠杆菌(E.coli)和金黄色葡萄球菌(S.aureus)的抑菌率分别达到62.70％和84.54％,对新鲜樱桃展现了良好的保鲜效果.
Keyword ：
保鲜膜 保鲜膜 抗菌 抗菌 生物降解 生物降解 纳米二氧化钛 纳米二氧化钛 聚六亚甲基双胍盐酸盐 聚六亚甲基双胍盐酸盐
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| GB/T 7714 | 孙文涛 , 龚佳荣 , 刘新宇 et al. 聚胍接枝二氧化钛抗菌剂改性聚己二酸-对苯二甲酸丁二酯/聚乳酸生物降解保鲜膜的制备与性能 [J]. | 高分子材料科学与工程 , 2024 , 40 (11) : 29-39 . |
| MLA | 孙文涛 et al. "聚胍接枝二氧化钛抗菌剂改性聚己二酸-对苯二甲酸丁二酯/聚乳酸生物降解保鲜膜的制备与性能" . | 高分子材料科学与工程 40 . 11 (2024) : 29-39 . |
| APA | 孙文涛 , 龚佳荣 , 刘新宇 , 许平凡 , 刘源森 , 罗耀发 et al. 聚胍接枝二氧化钛抗菌剂改性聚己二酸-对苯二甲酸丁二酯/聚乳酸生物降解保鲜膜的制备与性能 . | 高分子材料科学与工程 , 2024 , 40 (11) , 29-39 . |
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Due to the fact that single UV-cured coatings frequently fail to fulfill the requirements in terms of depth and chroma, and do not reach the ideal state in terms of comprehensive performance. In order to solve these painpoints more effectively, the sulfhydryl-modified castor oil (COME) was successfully synthesized by introducing beta-mercaptoethanol onto the plant-based material castor oil (CO) through the thiol-ene clink reaction. Subsequently, the synthesized polyurethane acrylate prepolymer (COPUA), monomer, photoinitiator and thermocuring agent were used as A component, and COME was used as B component. The two were mixed evenly according to a certain proportion, and the modified castor oil based polyurethane acrylate (COMEPUA) coatings were fabricated by UV/thermal dual-curing technology. Based on a series of performance test outcomes, the coating demonstrates excellent comprehensive properties, encompassing mechanical properties (where the shear strength, tensile strength, elongation at break, and hardness can respectively reach 5.26 MPa, 9.92 MPa, 132.55 %, and 47.77 Shore D), coating properties (where the absorption rates after 72 h immersion in water, ethanol, 10 wt% HCl, and 10 wt% NaOH solvents are respectively 0.66, 17.98, 1.89, and 0.71 %, and the volume resistivity and breakdown voltage are respectively 1.74x1016 Omega & sdot;cm and 10 KV) and curing properties (where the curing depth can reach 9.82 mm, which is significantly higher than 3.51 mm of single UV curing, and the colored curing is complete). It can exert protective functions such as anti-corrosion, anti-fouling, and insulation on circuit boards, electronic packaging, and device surfaces, and holds great potential in the application of coating materials.
Keyword ：
Comprehensive performance Comprehensive performance Modified castor oil Modified castor oil Polyurethane acrylate Polyurethane acrylate Thiol-ene clink reaction Thiol-ene clink reaction UV/thermal dual-curing system UV/thermal dual-curing system
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| GB/T 7714 | Luo, Yaofa , Liu, Guang , Zhang, Pengfei et al. Modified castor oil-based UV/thermal dual-curing polyurethane acrylate coatings with outstanding comprehensive properties [J]. | MATERIALS TODAY COMMUNICATIONS , 2024 , 41 . |
| MLA | Luo, Yaofa et al. "Modified castor oil-based UV/thermal dual-curing polyurethane acrylate coatings with outstanding comprehensive properties" . | MATERIALS TODAY COMMUNICATIONS 41 (2024) . |
| APA | Luo, Yaofa , Liu, Guang , Zhang, Pengfei , Zhou, Bing , Zhang, Peikun , Xu, Pingfan et al. Modified castor oil-based UV/thermal dual-curing polyurethane acrylate coatings with outstanding comprehensive properties . | MATERIALS TODAY COMMUNICATIONS , 2024 , 41 . |
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