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The rapid synthesis of CdS nanorods by optimizing the dodecanethiol proportion for photocatalysis EI
会议论文 | 2025 , 13549 | 2024 International Conference on Optoelectronic Materials and Devices, ICOMD 2024
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Abstract :

Cadmium sulfide (CdS) nanocrystals with diverse morphologies are extensively utilized in various fields. For example, CdS nanorods are widely used in photocatalysis and photodetectors due to their high efficiency in photogenerated carrier separation. However, existing methods for synthesizing CdS nanorods typically require high temperatures and pressures, which limit the application of this material. In this work, an efficient hot injection procedure to control about growth in Cadmium sulfide nanorods by optimizing the proportion of dodecanethiol is reported, demonstrating the effective control of CdS nanorods growth by dodecanethiol. The maximum degradation efficiency of CdS nanorods applied to photodegradation of Rhodamine B (RhB) can reach 96%, indicating that the synthesized CdS nanorods have excellent photocatalytic properties. It is attributed to their broad absorption within the visible spectrum, which results in excellent light harvesting. And their one-dimensional structure facilitates carrier separation. Dodecanethiol act as a selective role within morphology of the CdS nanomaterials, which is anticipated to be utilized in the creation of other sulfides with different morphologies. © 2025 SPIE.

Keyword :

Laser beams Laser beams Nanoclay Nanoclay Nanocrystals Nanocrystals Nanorods Nanorods Photocatalysis Photocatalysis Photodegradation Photodegradation Photodetectors Photodetectors Photonics Photonics Photons Photons Rhodamine B Rhodamine B

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GB/T 7714 Zhang, Liyan , Zhao, Wenxiao , Ye, Yun et al. The rapid synthesis of CdS nanorods by optimizing the dodecanethiol proportion for photocatalysis [C] . 2025 .
MLA Zhang, Liyan et al. "The rapid synthesis of CdS nanorods by optimizing the dodecanethiol proportion for photocatalysis" . (2025) .
APA Zhang, Liyan , Zhao, Wenxiao , Ye, Yun , Lin, Zexi , Wang, Ziyi , Zheng, Xingke et al. The rapid synthesis of CdS nanorods by optimizing the dodecanethiol proportion for photocatalysis . (2025) .
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The rapid synthesis of CdS nanorods by optimizing the dodecanethiol proportion for photocatalysis Scopus
其他 | 2025 , 13549 | Proceedings of SPIE - The International Society for Optical Engineering
Voltage/temperature responsive multimode reflective display devices for information encryption and smart windows EI
会议论文 | 2025 , 13549 | 2024 International Conference on Optoelectronic Materials and Devices, ICOMD 2024
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Abstract :

A cholesteric liquid crystal (CLC) reflective display is a device that employs CLC to reflect external ambient light, thereby facilitating the transfer of information. However, traditional CLC reflective displays exhibit a relatively slow response speed and are unable to be displayed in dark environments. Quantum dots (QDs), which are nanoparticles with excellent luminescence performance, can be doped to enhance device performance and the display effect. This paper proposes a multimode reflective display device (MRDE) that can respond rapidly to temperature and low-frequency AC voltage, and can realise four modes of display: reflective mode, transmissive mode, scattering mode and fluorescent mode. These modes can be converted to enhance the display effect and expand the device's application range in diverse scenarios. In reflective mode, MRDE is capable of shifting between reflective, scattering mode and transmissive modes in response to changes in temperature and voltage, and of encrypting and decrypting information. In fluorescent mode, the device is capable of displaying in dim environments, and the emission wavelength can be red-shifted from 628 nm to 636 nm within the temperature range of 248 K to 373 K. Additionally, it can provide an early warning for low and high temperature environments. The device is capable of providing early warning and encryption of information in low and high temperature environments. This provides a theoretical basis and guidance for the preparation of new devices with improved display performance, multifunctional integration, and temperature-responsive information encryption. © 2025 SPIE.

Keyword :

Cholesteric liquid crystals Cholesteric liquid crystals Fiber optic sensors Fiber optic sensors Hadrons Hadrons Laser beams Laser beams Liquid crystal displays Liquid crystal displays Nanocrystals Nanocrystals Photoelectric cells Photoelectric cells Photoelectric microscopes Photoelectric microscopes Photons Photons Red Shift Red Shift

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GB/T 7714 Zhang, Tianning , Zheng, Xingke , Ye, Yun et al. Voltage/temperature responsive multimode reflective display devices for information encryption and smart windows [C] . 2025 .
MLA Zhang, Tianning et al. "Voltage/temperature responsive multimode reflective display devices for information encryption and smart windows" . (2025) .
APA Zhang, Tianning , Zheng, Xingke , Ye, Yun , Chen, Enguo , Guo, Tailiang . Voltage/temperature responsive multimode reflective display devices for information encryption and smart windows . (2025) .
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Voltage/temperature responsive multimode reflective display devices for information encryption and smart windows Scopus
其他 | 2025 , 13549 | Proceedings of SPIE - The International Society for Optical Engineering
Ultrawide-range wearable temperature sensor utilizing reversible luminescence of CsPbBr3/PS composites EI
期刊论文 | 2025 , 142 | Nano Energy
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Abstract :

Exceptional temperature sensitivity and the resulting luminescence response position perovskite materials as potent contenders in wearable sensing devices. However, the mechanisms driving temperature-induced fluorescence reversibility, especially across an ultrawide temperature range or at freezing temperatures, remain poorly understood. In this study, we systematically elucidate the mechanisms governing temperature-induced fluorescence reversibility in CsPbBr3/PS composite and astonishingly observe the reversible fluorescence enhancement under freezing temperatures for the first time. Elevated temperature-induced lattice phase transitions and freezing temperature-associated lattice distortions in CsPbBr3 can modulate the electrons' non-radiative recombination process, leading to temperature-dependent fluorescence quenching and enhancement, respectively. Notably, these structural perturbations can be reversed with temperature cycling, ensuring the reversibility of thermally induced fluorescence phenomena. Leveraging these insights, we develop a CsPbBr3/PS-based wearable temperature sensor that operates over an ultrawide range (263 K ∼ 423 K) with high precision (error margin within ± 10 %). Our findings highlight the significant breakthrough of CsPbBr3 in temperature sensing and wearable applications. © 2025 Elsevier Ltd

Keyword :

Fluorescence quenching Fluorescence quenching Scintillation Scintillation Setting Setting Thermocouples Thermocouples

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GB/T 7714 Cai, Junhu , Lai, Wenzong , Chen, Yu et al. Ultrawide-range wearable temperature sensor utilizing reversible luminescence of CsPbBr3/PS composites [J]. | Nano Energy , 2025 , 142 .
MLA Cai, Junhu et al. "Ultrawide-range wearable temperature sensor utilizing reversible luminescence of CsPbBr3/PS composites" . | Nano Energy 142 (2025) .
APA Cai, Junhu , Lai, Wenzong , Chen, Yu , Ye, Yun , Xu, Sheng , Guo, Tailiang et al. Ultrawide-range wearable temperature sensor utilizing reversible luminescence of CsPbBr3/PS composites . | Nano Energy , 2025 , 142 .
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Ultrawide-range wearable temperature sensor utilizing reversible luminescence of CsPbBr3/PS composites Scopus
期刊论文 | 2025 , 142 | Nano Energy
Ultrawide-range wearable temperature sensor utilizing reversible luminescence of CsPbBr3/PS composites SCIE
期刊论文 | 2025 , 142 | NANO ENERGY
Zn2+-doped CsPbI3 quantum dots for color conversion LEDs(cover paper·invited) EI
期刊论文 | 2025 , 54 (1) | Infrared and Laser Engineering
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Abstract :

Objective Inorganic perovskite quantum dots (PQDs) have garnered significant interest due to their exceptional optical characteristics, including narrow emission spectra and high photoluminescence quantum yield (PLQY). Despite these advantages, PQDs are often hindered by environmental instability, particularly notable in CsPbI3 QDs which exhibit lower PLQY and susceptibility to phase transitions at ambient conditions, compromising optical performance. To address these challenges, enhancing the stability and optical properties of CsPbI3 QDs is crucial. Current research focuses on methods such as ligand exchange, encapsulation, and ion doping, with the latter proving particularly effective in improving PLQY and stability. Ion doping, involving substitution at A, B, or X sites, can mitigate Pb toxicity, alter bond lengths, and enhance phase stability, thereby significantly impacting quantum dot performance. Initial CsPbI3 QDs typically demonstrate a PLQY of 50% to 60% but suffer rapid fluorescence quenching within ten days in environmental settings. This study proposes Zn ion doping as a promising strategy to augment the optical properties of perovskite quantum dots. Methods This article employs a high-temperature thermal injection method for the synthesis of Cs-oleate precursors. Initially, Cs-oleate precursors are synthesized and subsequently rapidly injected into a high-temperature octadecene solution containing PbX2, ZnI2 and ligands. The reaction proceeds for a few seconds before the mixture is quenched in an ice water bath. Various molar ratios of ZnI2/PbI2 can be adjusted to achieve a series of CsPb1-xZnxI3 (0 2 concentration, while the overall cubic structure of the QDs remains unchanged. This modification enhances the radiative recombination rate and effectively mitigates defect states. The maximum enhancement in photoluminescence quantum yield (PLQY) reaches 98%, accompanied by improved stability(Fig.3(b)). Original CsPbI3 QDs exhibit complete fluorescence quenching within ten days at room temperature, whereas Zn-doped CsPbI3 QDs maintain over 80% of their initial PLQY under the same conditions(Fig.3(d)). Transmission electron microscopy (TEM) analysis shows that despite the addition of ZnI2 precursor, the QDs retain their cubic morphology, with the average particle size decreasing from 18.9 nm to 17.6 nm. This size reduction is attributed to the inhibitory effect of I ions on further QD growth. The interplanar spacing of the QDs decreases from 3.16 Å to 3.13 Å, indicating lattice contraction induced by Zn doping. X-ray diffraction (XRD) patterns confirm that Zn-doped CsPbI3 QDs exhibit no new diffraction peaks compared to pure CsPbI3 QDs, but show a gradual shift of peaks towards larger angles, indicating successful substitution of Pb by Zn ions. Analysis of time-resolved photoluminescence (TRPL) spectroscopy reveals that CsPbI3 QDs have an average fluorescence lifetime of 138.44 ns, while Zn-doped CsPbI3 QDs exhibit a shorter lifetime of 103.61 ns(Fig.3(e)), attributed to the suppression of halogen vacancy defects and shallow-level states by Zn doping(Tab.1). This doping strategy effectively passivates surface defects and enhances the optical properties of CsPbI3 QDs. Conclusions In this study, CsPbI3 quantum dots doped with Zn2+ were successfully synthesized using ZnI2 via the thermal injection method. The incorporation of Zn enhanced the phase stability of CsPbI3 quantum dots compared to their undoped counterparts. Photoluminescence quantum yield (PLQY) significantly improved from 56% to 98%, with PLQY retention above 80% after 10 days. Subsequently, narrow-emitting Zn:CsPbI3, CsPbBr3, and CsPbCl3 quantum dots were selected as replacements for conventional phosphors in LED color conversion materials. These quantum dots achieved a color gamut of 135.22% based on the National Television Standards Committee (NTSC) standard(Tab.2), highlighting their promising applications in LED display technologies. Copyright ©2025 Infrared and Laser Engineering. All rights reserved.

Keyword :

Crystal defects Crystal defects Crystalline materials Crystalline materials Crystals Crystals Defect engineering Defect engineering Defect states Defect states Durability Durability Ice Ice Optical emission spectroscopy Optical emission spectroscopy Optical materials Optical materials Phase composition Phase composition Semiconductor growth Semiconductor growth Structure (composition) Structure (composition) Synthetic metals Synthetic metals Yield stress Yield stress

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GB/T 7714 Zha, Nan , Cai, Junhu , Ye, Yun et al. Zn2+-doped CsPbI3 quantum dots for color conversion LEDs(cover paper·invited) [J]. | Infrared and Laser Engineering , 2025 , 54 (1) .
MLA Zha, Nan et al. "Zn2+-doped CsPbI3 quantum dots for color conversion LEDs(cover paper·invited)" . | Infrared and Laser Engineering 54 . 1 (2025) .
APA Zha, Nan , Cai, Junhu , Ye, Yun , Xu, Sheng , Guo, Tailiang , Chen, Enguo . Zn2+-doped CsPbI3 quantum dots for color conversion LEDs(cover paper·invited) . | Infrared and Laser Engineering , 2025 , 54 (1) .
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Zn2+-doped CsPbI3 quantum dots for color conversion LEDs(cover paper·invited); [Zn离子掺杂CsPbI3量子点及其色转换LED应用(封面文章·特邀)] Scopus
期刊论文 | 2025 , 54 (1) | Infrared and Laser Engineering
Dual-domain residual CNN for medical image super-resolution with enhanced detail preservation and artifact suppression SCIE
期刊论文 | 2025 , 19 (6) | SIGNAL IMAGE AND VIDEO PROCESSING
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Abstract :

Single image super-resolution (SISR) is an emerging application in medical imaging, as high-quality images need to be obtained with limited radiation dose, such as low-dose computed tomography and low-field magnetic resonance imaging. However, a certain amount of noise and artifacts are frequently present in medical images due to the constraints of imaging equipment and the surrounding environment. This can cause structural distortion and blurring of details in the resulting medical images. This research proposes a dual-domain residual convolutional neural network (DDRN) based super-resolution reconstruction technique for medical images. Firstly, shallow feature extraction is performed on the low-resolution images through convolutional networks. Secondly, a newly designed spatial domain residual block (SDRB) is employed to alleviate gradient vanishing issues while enhancing feature reuse, thereby facilitating the recovery of edge details. Additionally, a coordinate attention (CA) module is incorporated to capture both channel-wise and long-range spatial correlations. By assigning adaptive weights to different channels and capturing global spatial context, CA enables precise restoration of texture and structural details in medical images. Subsequently, parallel wavelet domain residual blocks (WDRB) are employed to capture multi-directional high-frequency information, facilitating the restoration of clear texture details. Lastly, by introducing gradient space loss for training guidance, the network is encouraged to focus more on restoring the geometric structure of the image and suppressing artifacts. Extensive experiments demonstrate the superior performance of DDRN. At a scaling factor of 4, the network achieves a peak signal-to-noise ratio (PSNR) of 37.28 dB and a structural similarity index (SSIM) of 0.9310 on the COVID-19 CT lung segmentation dataset, and a PSNR of 28.85 dB and an SSIM of 0.9012 on the MRBrain2018 dataset.

Keyword :

Deep convolutional neural network Deep convolutional neural network Gradient space loss Gradient space loss Medical image super-resolution Medical image super-resolution Residual blocks Residual blocks

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GB/T 7714 Chen, Peihui , Zheng, Xingke , Qiu, Yingyi et al. Dual-domain residual CNN for medical image super-resolution with enhanced detail preservation and artifact suppression [J]. | SIGNAL IMAGE AND VIDEO PROCESSING , 2025 , 19 (6) .
MLA Chen, Peihui et al. "Dual-domain residual CNN for medical image super-resolution with enhanced detail preservation and artifact suppression" . | SIGNAL IMAGE AND VIDEO PROCESSING 19 . 6 (2025) .
APA Chen, Peihui , Zheng, Xingke , Qiu, Yingyi , Liu, Kuanhuang , Chen, Enguo , Xu, Sheng et al. Dual-domain residual CNN for medical image super-resolution with enhanced detail preservation and artifact suppression . | SIGNAL IMAGE AND VIDEO PROCESSING , 2025 , 19 (6) .
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Dual-domain residual CNN for medical image super-resolution with enhanced detail preservation and artifact suppression Scopus
期刊论文 | 2025 , 19 (6) | Signal, Image and Video Processing
Dual-domain residual CNN for medical image super-resolution with enhanced detail preservation and artifact suppression EI
期刊论文 | 2025 , 19 (6) | Signal, Image and Video Processing
Performance Enhancement of MAPbBr3 Perovskite Quantum Dot for Wide Color Gamut LED via Double Short-chain Ligand Modification EI
期刊论文 | 2025 , 46 (1) , 1-11 | Chinese Journal of Luminescence
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Quantum dots(QDs)exhibit excellent optical properties with their size tunability,excellent photoluminescence quantum yield(PLQY),and broad spectral absorption,making them an ideal material choice for full-col- or,wide-gamut LED color conversion layers. In particular,MAPbBr3 quantum dots(PQDs)are not only easy to prepare,but also possess excellent photovoltaic properties,and thus are considered to be a material with great potential for commercialization. However,the ligands on the surface of MAPbBr3 PQDs are highly susceptible to detachment after their synthesis,leading to an increase in the density of surface defect states,which makes them less stable under environmental factors such as water-oxygen and temperature,thus further degrading the PLQY. In this study,we propose an efficient one-step strategy for the synthesis of MAPbBr3 PQDs∶MAPbBr3 PQDs with excellent stability and high PLQY,which were successfully synthesized by ligand-assisted redeposition and the innovative use of 2-hex-yldecanoic acid(DA)ligand to replace the conventional oleic acid(OA)ligand at room temperature,and the double-short-chain DA ligand was able to establish a stronger coordination bond with the MAPbBr3 PQDs compared with that of the single-length carbon chain OA ligand. The strong interactions between the ligands and the PQDs contribute to the overall passivation of the lattice defects,thus mitigating the non-radiative recombination process and enhancing the environmental stability. As a result,the modified MAPbBr3 PQDs not only exhibited up to 87. 8% PLQY,but also showed higher stability in both water and oxygen environments. The PL peak of MAPbBr3 PQDs modified with DA ligands remained at 68. 3% of its original value after being left for half a month in a room temperature environment, whereas OA ligand-modified PQDs exhibited almost complete fluorescence burst. Subsequently,the DA ligand-modified green MAPbBr3 PQDs,red CsPbBrI2 PQDs,and blue CsPbCl1. 5Br1. 5 PQDs were coated and cured in a polystyrene(PS)environment to form a film,which can be used as a color conversion material instead of the traditional phosphors for the backlight of light-emitting diode(LED)displays. The color gamut is 137. 09% under NTSC standard. © 2025 Editorial Office of Chinese Optics. All rights reserved.

Keyword :

Aspect ratio Aspect ratio Atomic emission spectroscopy Atomic emission spectroscopy Carbon Quantum Dots Carbon Quantum Dots Color Color Defect density Defect density Density (optical) Density (optical) Energy efficiency Energy efficiency Grain boundaries Grain boundaries Laser beams Laser beams Layered semiconductors Layered semiconductors Ligands Ligands Light sensitive materials Light sensitive materials Liquid crystals Liquid crystals Metamorphic rocks Metamorphic rocks Nanocrystallization Nanocrystallization Photoluminescence Photoluminescence Quantum yield Quantum yield

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GB/T 7714 Li, Gongming , Cai, Junhu , Lai, Wenzong et al. Performance Enhancement of MAPbBr3 Perovskite Quantum Dot for Wide Color Gamut LED via Double Short-chain Ligand Modification [J]. | Chinese Journal of Luminescence , 2025 , 46 (1) : 1-11 .
MLA Li, Gongming et al. "Performance Enhancement of MAPbBr3 Perovskite Quantum Dot for Wide Color Gamut LED via Double Short-chain Ligand Modification" . | Chinese Journal of Luminescence 46 . 1 (2025) : 1-11 .
APA Li, Gongming , Cai, Junhu , Lai, Wenzong , Chen, Xiaogang , Zha, Nan , Ye, Yun et al. Performance Enhancement of MAPbBr3 Perovskite Quantum Dot for Wide Color Gamut LED via Double Short-chain Ligand Modification . | Chinese Journal of Luminescence , 2025 , 46 (1) , 1-11 .
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Performance Enhancement of MAPbBr3 Perovskite Quantum Dot for Wide Color Gamut LED via Double Short-chain Ligand Modification; [双短链配体调控提升 MAPbBr3量子点性能及广色域 LED 显示应用] Scopus
期刊论文 | 2025 , 46 (1) , 1-11 | Chinese Journal of Luminescence
Micro-LED Retinal Projection for Augmented Reality Near-Eye Displays SCIE
期刊论文 | 2025 , 19 (14) | LASER & PHOTONICS REVIEWS
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Abstract :

Retinal projection display enables the direct projection of virtual images onto the retina through the pupil center via a projection engine, showing promise in addressing the vergence-accommodation conflict in augmented reality near-eye displays. However, existing RPD architectures universally employ passive luminous micro-electromechanical systems or spatial light modulators, encountering challenges associated with beam aperture limitations and structural inflexibility. In response to these, this paper presents a novel micro-LED retinal projection display architecture that integrates the active luminous full-color micro-LEDs with a pixel-to-pixel imaging fiber bundle, effectively subverting conventional RPD designs. Additionally, the flexible fiber bundle brings an adaptable design that enables optoelectronic separation capabilities. The design principles and feasibility are thoroughly described and validated through simulations and experiments. A full-color mu RPD prototype is developed, demonstrating sharp imaging across an extensive focal depth range. Remarkably, the mu RPD architecture exhibits a groundbreaking advancement in enabling underwater AR displays without necessitating special waterproof treatments, underscoring its potential versatility and adaptability to challenging environments. This design paves a new way for practical applications of NEDs in complex and demanding conditions, thereby contributing to the evolution of NED systems.

Keyword :

augmented reality augmented reality imaging fiber bundle imaging fiber bundle micro-LED micro-LED optoelectronic separation optoelectronic separation retinal projection display retinal projection display

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GB/T 7714 Jin, Huajian , Lin, Zijian , Lai, Wenzong et al. Micro-LED Retinal Projection for Augmented Reality Near-Eye Displays [J]. | LASER & PHOTONICS REVIEWS , 2025 , 19 (14) .
MLA Jin, Huajian et al. "Micro-LED Retinal Projection for Augmented Reality Near-Eye Displays" . | LASER & PHOTONICS REVIEWS 19 . 14 (2025) .
APA Jin, Huajian , Lin, Zijian , Lai, Wenzong , Jiang, Haonan , Cai, Junhu , Chen, Hao et al. Micro-LED Retinal Projection for Augmented Reality Near-Eye Displays . | LASER & PHOTONICS REVIEWS , 2025 , 19 (14) .
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Micro-LED Retinal Projection for Augmented Reality Near-Eye Displays Scopus
期刊论文 | 2025 , 19 (14) | Laser and Photonics Reviews
CdS Nanorods in Photoelectronic Memristors for Improved Target Recognition Efficiency SCIE
期刊论文 | 2025 , 8 (6) , 2940-2951 | ACS APPLIED NANO MATERIALS
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Abstract :

Optoelectronic memristors have garnered significant attention for their critical applications in neuromorphic computing. The incorporation of materials with excellent absorption efficiency in the fabrication of photoelectric memristors can significantly enhance the image recognition capabilities. CdS nanorods (NRs) are semiconductors with strong UV light absorption that can effectively improve charge transport characteristics, reduce the loss caused by recombination at the crystal surface, and enhance the light absorption characteristics. In this work, an efficient hot injection method for controlling the growth of CdS NRs or nanosquares (NSs) by optimizing the proportion of dodecanethiol (DDT) is reported. Meanwhile, two-terminal optoelectronic memristors based on CdS NSs and CdS NRs are fabricated in which the conductance of the devices can be continuously modulated under electrical and optical stimulations of different widths/spacings/amplitudes. These advantages impart the device with exceptional electrical and optical synaptic functions including excitability, inhibition, paired-pulse facilitation, short-term/long-term plasticity, and memory-forgetting behavior. In addition, the enhancement of the image recognition efficiency of the device by CdS NRs is demonstrated in experiments with the recognition of the optical image "F". This work offers valuable insights for material selection in the development of future neuromorphic devices.

Keyword :

artificial synapses artificial synapses Cadmium sulfide Cadmium sulfide dodecanethiol dodecanethiol nanorod nanorod optoelectronicmemristor optoelectronicmemristor

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GB/T 7714 Zhang, Liyan , Zhao, Wenxiao , Lin, Zexi et al. CdS Nanorods in Photoelectronic Memristors for Improved Target Recognition Efficiency [J]. | ACS APPLIED NANO MATERIALS , 2025 , 8 (6) : 2940-2951 .
MLA Zhang, Liyan et al. "CdS Nanorods in Photoelectronic Memristors for Improved Target Recognition Efficiency" . | ACS APPLIED NANO MATERIALS 8 . 6 (2025) : 2940-2951 .
APA Zhang, Liyan , Zhao, Wenxiao , Lin, Zexi , Wang, Ziyi , Zheng, Xingke , Chen, Enguo et al. CdS Nanorods in Photoelectronic Memristors for Improved Target Recognition Efficiency . | ACS APPLIED NANO MATERIALS , 2025 , 8 (6) , 2940-2951 .
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CdS Nanorods in Photoelectronic Memristors for Improved Target Recognition Efficiency Scopus
期刊论文 | 2025 , 8 (6) , 2940-2951 | ACS Applied Nano Materials
CdS Nanorods in Photoelectronic Memristors for Improved Target Recognition Efficiency EI
期刊论文 | 2025 , 8 (6) , 2940-2951 | ACS Applied Nano Materials
In Situ Ring Opening Polymerization of High-Performance Full-Color CsPbX3@PDMS (X = Cl, Br, I) Nanospheres Toward Wide-Color-Gamut Displays SCIE
期刊论文 | 2025 , 21 (11) | SMALL
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Abstract :

Optimizing the three-primary-color perovskite quantum dots (TPC PQDs) is crucial for achieving ultra-wide color gamut displays. Although encapsulation is an effective strategy to improve the stability and optical performance of the TPC PQDs, the chemicals or environment employed in the coating procedure may attack the CsPbX3 PQDs and generate defects, damage, and ligand loss. Herein, a mild, facile and universal hexamethylcyclotrisiloxane (D3) in situ ring opening polymerization strategy is successfully developed for efficiently synthesizing high-brightness and extremely stable TPC CsPbX3@PDMS (X = Cl, Br, I) nanospheres, with particularly friendlyness for fragile red and blue. The formation of Pb & horbar;O bond between polydimethylsiloxane (PDMS) and CsPbX3 passivates the lattice defects, resulting in photoluminescence quantum yields (PLQYs) improvement of approximate to 1.5 times for green and red, astonishingly 2 times for blue PQDs. Also, PDMS shell effectively blocks threats from the environment. Finally, the synthesized CsPbX3@PDMS nanospheres are successfully applied in fabrication of the TPC light emitting diodes (LEDs) and full-color liquid crystal displays (LCDs), achieving impressive ultra-wide color gamuts of 132% and 118% National Television Standards Committee (NTSC), respectively. These findings support the new strategy for synthesizing emerging full-color perovskite nanomaterials and shows great potentieal for high color-rendering displays.

Keyword :

CsPbBr3 CsPbBr3 polydimethylsiloxane polydimethylsiloxane ring opening polymerization ring opening polymerization wide-color-gamut displays wide-color-gamut displays

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GB/T 7714 Cai, Junhu , Ren, Xinxin , Zhang, Xiang et al. In Situ Ring Opening Polymerization of High-Performance Full-Color CsPbX3@PDMS (X = Cl, Br, I) Nanospheres Toward Wide-Color-Gamut Displays [J]. | SMALL , 2025 , 21 (11) .
MLA Cai, Junhu et al. "In Situ Ring Opening Polymerization of High-Performance Full-Color CsPbX3@PDMS (X = Cl, Br, I) Nanospheres Toward Wide-Color-Gamut Displays" . | SMALL 21 . 11 (2025) .
APA Cai, Junhu , Ren, Xinxin , Zhang, Xiang , Lai, Wenzong , Chen, Yu , Chen, Xiaogang et al. In Situ Ring Opening Polymerization of High-Performance Full-Color CsPbX3@PDMS (X = Cl, Br, I) Nanospheres Toward Wide-Color-Gamut Displays . | SMALL , 2025 , 21 (11) .
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In Situ Ring Opening Polymerization of High-Performance Full-Color CsPbX3@PDMS (X = Cl, Br, I) Nanospheres Toward Wide-Color-Gamut Displays EI
期刊论文 | 2025 , 21 (11) | Small
In Situ Ring Opening Polymerization of High-Performance Full-Color CsPbX3@PDMS (X = Cl, Br, I) Nanospheres Toward Wide-Color-Gamut Displays Scopus
期刊论文 | 2025 , 21 (11) | Small
In Situ Ring Opening Polymerization of High-Performance Full-Color CsPbX3@PDMS (X = Cl, Br, I) Nanospheres Toward Wide-Color-Gamut Displays Scopus
期刊论文 | 2025 | Small
Neuron-inspired CsPbBr3/PDMS nanospheres for multi-dimensional sensing and interactive displays SCIE
期刊论文 | 2025 , 14 (1) | LIGHT-SCIENCE & APPLICATIONS
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Multifunctional materials have attracted tremendous attention in intelligent and interactive devices. However, achieving multi-dimensional sensing capabilities with the same perovskite quantum dot (PQD) material is still in its infancy, with some considering it currently challenging and even unattainable. Drawing inspiration from neurons, a novel multifunctional CsPbBr3/PDMS nanosphere is devised to sense humidity, temperature, and pressure simultaneously with unique interactive responses. The carefully engineered polydimethylsiloxane (PDMS) shell enables the reversible activity of the core CsPbBr3, serving a dual role similar to dendrites in conveying and evaluating external stimuli with high sensitivity. Molecular dynamics analysis reveals that the PDMS shell with proper pore density enhances the conductivity in water and heat, imparting CsPbBr3 with sensitive but reversible properties. By tailoring the crosslinking density of the PDMS shell, nanospheres can surprisingly show customized sensitivity and reversible responses to different level of stimuli, achieving over 95% accuracy in multi-dimensional and wide-range sensing. The regular pressure-sensitive property, discovered for the first time, is attributed to the regular morphology of the nanosphere, the inherent low rigidity of the PDMS shell, and the uniform distribution of the CsPbBr3 core material in combination. This study breaks away from conventional design paradigms of perovskite core-shell materials by customizing the cross-linked density of the shell material. The reversible response mechanism of nanospheres with gradient shell density is deeply explored in response to environmental stimuli, which offers fresh insights into multi-dimensional sensing and interactive display applications.

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GB/T 7714 Cai, Junhu , Zhang, Xiang , Chen, Yu et al. Neuron-inspired CsPbBr3/PDMS nanospheres for multi-dimensional sensing and interactive displays [J]. | LIGHT-SCIENCE & APPLICATIONS , 2025 , 14 (1) .
MLA Cai, Junhu et al. "Neuron-inspired CsPbBr3/PDMS nanospheres for multi-dimensional sensing and interactive displays" . | LIGHT-SCIENCE & APPLICATIONS 14 . 1 (2025) .
APA Cai, Junhu , Zhang, Xiang , Chen, Yu , Lai, Wenzong , Ye, Yun , Xu, Sheng et al. Neuron-inspired CsPbBr3/PDMS nanospheres for multi-dimensional sensing and interactive displays . | LIGHT-SCIENCE & APPLICATIONS , 2025 , 14 (1) .
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Neuron-inspired CsPbBr3/PDMS nanospheres for multi-dimensional sensing and interactive displays Scopus
期刊论文 | 2025 , 14 (1) | Light: Science and Applications
Neuron-inspired CsPbBr3/PDMS nanospheres for multi-dimensional sensing and interactive displays EI
期刊论文 | 2025 , 14 (1) | Light: Science and Applications
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