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Tape-casting electrode architecture permits low-temperature manufacturing of all-solid-state thin-film microbatteries ESCI
期刊论文 | 2024 | INTERDISCIPLINARY MATERIALS
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Abstract :

Along with the constantly evolving functional microsystems toward more diversification, the more rigorous design deliberation of pursuing higher mass-loading of electrode materials and low-temperature fabrication compatibility have imposed unprecedented demand on integrable all-solid-state thin-film microbatteries. While the classic thin-film intercalation cathode prepared by vacuum-based techniques inevitably encountered a post-annealing process, tape-casting technologies hold great merits both in terms of high-mass loading and low-temperature processing. In this work, a novel microbattery configuration is developed by the combination of traditional tape-casting thick electrodes and sputtered inorganic thin-film solid electrolytes (similar to 3 mu m lithium phosphorus oxynitride). Enabled by physically pressed or vapor-deposited Li as an anode, solid-state batteries with tape-casted LiFePO4 electrodes exhibit outstanding cyclability and stability. To meet integration requirements, LiFePO4/LiPON/Si microbatteries were successfully fabricated at low temperatures and found to achieve a wide operating temperature range. This novel configuration has good prospects in promoting the thin-film microbattery enabling a paradigm shift and satisfying diversified requirements.

Keyword :

all-solid-state batteries all-solid-state batteries lithium phosphorus oxynitride lithium phosphorus oxynitride on-chip integration on-chip integration silicon anodes silicon anodes tape-casting electrodes tape-casting electrodes

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GB/T 7714 Ke, Bingyuan , Zhang, Congcong , Cheng, Shoulin et al. Tape-casting electrode architecture permits low-temperature manufacturing of all-solid-state thin-film microbatteries [J]. | INTERDISCIPLINARY MATERIALS , 2024 .
MLA Ke, Bingyuan et al. "Tape-casting electrode architecture permits low-temperature manufacturing of all-solid-state thin-film microbatteries" . | INTERDISCIPLINARY MATERIALS (2024) .
APA Ke, Bingyuan , Zhang, Congcong , Cheng, Shoulin , Li, Wangyang , Deng, Renming , Zhang, Hong et al. Tape-casting electrode architecture permits low-temperature manufacturing of all-solid-state thin-film microbatteries . | INTERDISCIPLINARY MATERIALS , 2024 .
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Tape-casting electrode architecture permits low-temperature manufacturing of all-solid-state thin-film microbatteries EI
期刊论文 | 2024 , 3 (4) , 621-631 | Interdisciplinary Materials
Multi-functional bilayer carbon structures with micrometer-level physical encapsulation as a flexible cathode host for high-performance lithium-sulfur batteries SCIE
期刊论文 | 2023 , 451 | CHEMICAL ENGINEERING JOURNAL
WoS CC Cited Count: 55
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Abstract :

With the exceptional merits of high energy density, low cost, and environmental friendliness, lithium-sulfur batteries are considered to be one of the most promising next-generation flexible rechargeable batteries. How-ever, the notorious "shuttle effect " has seriously hindered their practical applications. Herein, a strategy for designing multi-functional bilayer carbon structures is proposed, specifically, by employing a micrometer-thick graphene nanoflowers (GF) layer to encapsulate a micrometer-scale hybrid network skeleton composed of metallic Co and carbon nanotubes (CNT) as a flexible sulfur cathode host (Co/CNT@GF). Beneficial from the merits of chemical adsorption, electrocatalysis and volume expansion mitigation from the internal skeleton as well as the micrometer-level physical domain confinement by the external GF layer, the developed host could chemically trap, electrochemically catalyze, physically block and storage the lithium polysulfides. Due to the synergistic effect of these functions, the Co/CNT@GF-S delivers a superior discharge capacity of 799 mAh g(-1) with a decay rate as low as 0.08 % per cycle after 400 cycles at 1 C. Even at a high sulfur loading of 8.16 mg cm(-2), the average discharge capacity is as high as 5.05 mAh cm(-2) in 100 cycles. This work does not only contribute to the rational design of multi-functional bilayer structures but also offers a novel design method for the commercialization of flexible lithium-sulfur batteries with high-energy-density.

Keyword :

Graphene nanoflower Graphene nanoflower Li -S batteries Li -S batteries Lithium polysulfides Lithium polysulfides Metal-organic frameworks Metal-organic frameworks Plasma -enhanced chemical vapor deposition Plasma -enhanced chemical vapor deposition Synergistic effects Synergistic effects

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GB/T 7714 Xie, Yonghui , Ao, Juan , Zhang, Li et al. Multi-functional bilayer carbon structures with micrometer-level physical encapsulation as a flexible cathode host for high-performance lithium-sulfur batteries [J]. | CHEMICAL ENGINEERING JOURNAL , 2023 , 451 .
MLA Xie, Yonghui et al. "Multi-functional bilayer carbon structures with micrometer-level physical encapsulation as a flexible cathode host for high-performance lithium-sulfur batteries" . | CHEMICAL ENGINEERING JOURNAL 451 (2023) .
APA Xie, Yonghui , Ao, Juan , Zhang, Li , Shao, Yeqing , Zhang, Hong , Cheng, Shuying et al. Multi-functional bilayer carbon structures with micrometer-level physical encapsulation as a flexible cathode host for high-performance lithium-sulfur batteries . | CHEMICAL ENGINEERING JOURNAL , 2023 , 451 .
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Multi-functional bilayer carbon structures with micrometer-level physical encapsulation as a flexible cathode host for high-performance lithium-sulfur batteries Scopus
期刊论文 | 2023 , 451 | Chemical Engineering Journal
Multi-functional bilayer carbon structures with micrometer-level physical encapsulation as a flexible cathode host for high-performance lithium-sulfur batteries EI
期刊论文 | 2023 , 451 | Chemical Engineering Journal
All-Solid-State Thin-Film Lithium-Sulfur Batteries SCIE CSCD
期刊论文 | 2023 , 15 (1) | NANO-MICRO LETTERS
WoS CC Cited Count: 56
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Abstract :

Lithium-sulfur (Li-S) system coupled with thin-film solid electrolyte as a novel high-energy micro-battery has enormous potential for complementing embedded energy harvesters to enable the autonomy of the Internet of Things microdevice. However, the volatility in high vacuum and intrinsic sluggish kinetics of S hinder researchers from empirically integrating it into allsolid-state thin-film batteries, leading to inexperience in fabricating all-solid-state thin-film Li-S batteries (TFLSBs). Herein, for the first time, TFLSBs have been successfully constructed by stacking vertical graphene nanosheets-Li2S (VGsLi(2)S) composite thin-film cathode, lithium-phosphorous-oxynitride (LiPON) thin-film solid electrolyte, and Li metal anode. Fundamentally eliminating Lipolysulfide shuttle effect and maintaining a stable VGs-Li2S/LiPON interface upon prolonged cycles have been well identified by employing the solid-state Li-S system with an "unlimited Li" reservoir, which exhibits excellent longterm cycling stability with a capacity retention of 81% for 3,000 cycles, and an exceptional high temperature tolerance up to 60 degrees C. More impressively, VGs-Li2S-based TFLSBs with evaporated-Li thin-film anode also demonstrate outstanding cycling performance over 500 cycles with a high Coulombic efficiency of 99.71%. Collectively, this study presents a new development strategy for secure and high-performance rechargeable all-solid-state thin-film batteries.

Keyword :

All-solid-state thin-film batteries All-solid-state thin-film batteries Li2S Li2S Li-S batteries Li-S batteries Lithium phosphorous oxynitride Lithium phosphorous oxynitride Vertical graphene nanosheets Vertical graphene nanosheets

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GB/T 7714 Deng, Renming , Ke, Bingyuan , Xie, Yonghui et al. All-Solid-State Thin-Film Lithium-Sulfur Batteries [J]. | NANO-MICRO LETTERS , 2023 , 15 (1) .
MLA Deng, Renming et al. "All-Solid-State Thin-Film Lithium-Sulfur Batteries" . | NANO-MICRO LETTERS 15 . 1 (2023) .
APA Deng, Renming , Ke, Bingyuan , Xie, Yonghui , Cheng, Shoulin , Zhang, Congcong , Zhang, Hong et al. All-Solid-State Thin-Film Lithium-Sulfur Batteries . | NANO-MICRO LETTERS , 2023 , 15 (1) .
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All-Solid-State Thin-Film Lithium-Sulfur Batteries Scopus CSCD
期刊论文 | 2023 , 15 (1) | Nano-Micro Letters
All-Solid-State Thin-Film Lithium-Sulfur Batteries EI CSCD
期刊论文 | 2023 , 15 (1) | Nano-Micro Letters
NCM 811/LiPON全固态锂电池的制备与性能研究
期刊论文 | 2023 , 29 (02) , 112-116 | 功能材料与器件学报
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Abstract :

LiNi_(0.8)Co_(0.1)Mn_(0.1)O_2(NCM 811),具有高比容量、价格低廉以及环境友好等优点在固态电池领域已有较多学者研究。然而,较厚的固态电解质(>20μm)影响了其能量密度。作为一种常见的薄膜固态电解质,锂磷氧氮(LiPON)在薄膜固态电池领域受到普遍的关注。目前,尚未有研究将涂布的NCM 811与LiPON薄膜型电解质组合的固态电池。本工作以商业单面辊压NCM 811为阴极,结合磁控溅射LiPON电解质薄膜,Li箔为阳极成功制备全固态锂电池。循环测试结果表明,NCM 811/LiPON/Li箔全固态锂电池在15μA cm~(-2)电流密度下循环60圈后仍有54.85μAh cm~(-2)的面积比容量。且表现出优异的循环稳定性和倍率性能。此工作证明NCM 811阴极与LiPON电解质薄膜结合的全固态电池的制备是可行的,为NCM 811全固态电池的开发提供了一种新思路。

Keyword :

LiPON LiPON NCM 811 NCM 811 全固态锂电池 全固态锂电池

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GB/T 7714 张聪聪 , 柯秉渊 , 张红 et al. NCM 811/LiPON全固态锂电池的制备与性能研究 [J]. | 功能材料与器件学报 , 2023 , 29 (02) : 112-116 .
MLA 张聪聪 et al. "NCM 811/LiPON全固态锂电池的制备与性能研究" . | 功能材料与器件学报 29 . 02 (2023) : 112-116 .
APA 张聪聪 , 柯秉渊 , 张红 , 王星辉 . NCM 811/LiPON全固态锂电池的制备与性能研究 . | 功能材料与器件学报 , 2023 , 29 (02) , 112-116 .
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NCM 811/LiPON全固态锂电池的制备与性能研究
期刊论文 | 2023 , 29 (02) , 112-116 | 功能材料与器件学报
一种全固态薄膜锂电池的低温制备方法 incoPat
专利 | 2022-05-16 00:00:00 | CN202210529015.1
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本发明公开了一种全固态薄膜锂电池的低温制备方法,该发明以旋涂纳米材料低温制备薄膜电极,并以低温溅射LiPON为固态电解质,实现全固态锂电池的低温制备。该步骤包括:利用旋涂先将纳米结晶电极粉末制备厚度可控、表面光滑和均一性好的薄膜电极,并通过溅射或进一步旋涂低温制备全固态薄膜锂电池。本发明具有可避免高温退火结晶、操作简便、容易实现、低温制备、可利用现有电极材料体系开发全固态薄膜锂离子电池等优点。

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GB/T 7714 王星辉 , 程受麟 , 柯秉渊 et al. 一种全固态薄膜锂电池的低温制备方法 : CN202210529015.1[P]. | 2022-05-16 00:00:00 .
MLA 王星辉 et al. "一种全固态薄膜锂电池的低温制备方法" : CN202210529015.1. | 2022-05-16 00:00:00 .
APA 王星辉 , 程受麟 , 柯秉渊 , 张红 , 程树英 . 一种全固态薄膜锂电池的低温制备方法 : CN202210529015.1. | 2022-05-16 00:00:00 .
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浅析福建省集成电路人才供求现状
期刊论文 | 2022 , 31 (05) , 18-21 | 中国集成电路
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Abstract :

本文基于福建省高校集成电路相关专业近年来的本硕博培养规模和省内代表性企业的近期人才需求调研,就当前福建省集成电路产业人才培养现状,以及人才需求及其供应侧的短板等问题进行了较全面分析。并在此基础上,针对省内高校的人才供给侧改革提出了若干建议。

Keyword :

产业人才 产业人才 福建省 福建省 集成电路产业 集成电路产业

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GB/T 7714 王少昊 , 曾勇杰 , 施隆照 et al. 浅析福建省集成电路人才供求现状 [J]. | 中国集成电路 , 2022 , 31 (05) : 18-21 .
MLA 王少昊 et al. "浅析福建省集成电路人才供求现状" . | 中国集成电路 31 . 05 (2022) : 18-21 .
APA 王少昊 , 曾勇杰 , 施隆照 , 张红 . 浅析福建省集成电路人才供求现状 . | 中国集成电路 , 2022 , 31 (05) , 18-21 .
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浅析福建省集成电路人才供求现状
期刊论文 | 2022 , 31 (5) , 18-21 | 中国集成电路
浅析福建省集成电路人才供求现状
期刊论文 | 2022 , 31 (05) , 18-21 | 中国集成电路
TiO_2缓冲层在SnS薄膜太阳能电池中的数值仿真研究 PKU
期刊论文 | 2022 , 42 (04) , 299-305 | 固体电子学研究与进展
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Abstract :

低成本、环保的硫化亚锡(SnS),因具有较高的吸收系数与合适的禁带宽度,成为薄膜太阳能电池中很有潜力的光吸收层材料。但是目前已报道的SnS薄膜太阳能电池效率仍较低。本文对二氧化钛(TiO_2)缓冲层在SnS薄膜太阳能电池中的应用进行数值仿真研究。首先对吸收层的厚度与掺杂浓度、缓冲层的厚度与掺杂浓度进行了讨论,优化后的光电转换效率达到15.66%。然后在此基础上仿真分析了环境温度、背接触金属功函数对电池性能的影响。由仿真结果可知,该电池效率的温度系数为-0.029%/K,当背接触功函数大于5.1 eV时,电池性能较好。这为以后研发高性能的SnS薄膜太阳能电池提供了理论指导与参考。

Keyword :

二氧化钛(TiO_2) 二氧化钛(TiO_2) 太阳能电池 太阳能电池 数值仿真 数值仿真 硫化亚锡(SnS) 硫化亚锡(SnS)

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GB/T 7714 张红 , 张国成 , 宁宇 . TiO_2缓冲层在SnS薄膜太阳能电池中的数值仿真研究 [J]. | 固体电子学研究与进展 , 2022 , 42 (04) : 299-305 .
MLA 张红 et al. "TiO_2缓冲层在SnS薄膜太阳能电池中的数值仿真研究" . | 固体电子学研究与进展 42 . 04 (2022) : 299-305 .
APA 张红 , 张国成 , 宁宇 . TiO_2缓冲层在SnS薄膜太阳能电池中的数值仿真研究 . | 固体电子学研究与进展 , 2022 , 42 (04) , 299-305 .
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TiO_2缓冲层在SnS薄膜太阳能电池中的数值仿真研究 PKU
期刊论文 | 2022 , 42 (04) , 299-305 | 固体电子学研究与进展
TiO2缓冲层在SnS薄膜太阳能电池中的数值仿真研究 PKU
期刊论文 | 2022 , 42 (4) , 299-305 | 固体电子学研究与进展
可充电锌离子电池电解质的研究进展 CSCD PKU
期刊论文 | 2022 , 11 (07) , 2075-2082 | 储能科学与技术
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Abstract :

锌离子电池以其低价、安全、高可用性、生态友好、易于制备等特点而受到了广泛的研究。作为连通锌离子电池其他部分的纽带,电解质与电化学性能的发挥有着重要关系。为了进一步具备应用的可能性,增强电解质对电池电化学性能的释放具有深刻的意义。尽管在电解质方面已经进行了诸多探索并取得了很多优秀的成果,然而对于锌离子电池电解质的一些问题仍然需要引起足够的关注。本文首先阐述了锌离子电池的一般原理。然后分别从水溶液电解质、有机溶液电解质、凝胶电解质、全固态电解质等四个方面回顾了锌离子电池各种电解质的研究进展。其中,水溶液电解质部分重点介绍了对应电解质存在的溶剂化问题、相关的改性策略及添加剂对电极稳定性的提升机理。有...

Keyword :

全固态 全固态 凝胶 凝胶 有机溶液 有机溶液 水溶液 水溶液 电解质 电解质 锌离子电池 锌离子电池

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GB/T 7714 裴英伟 , 张红 , 王星辉 . 可充电锌离子电池电解质的研究进展 [J]. | 储能科学与技术 , 2022 , 11 (07) : 2075-2082 .
MLA 裴英伟 et al. "可充电锌离子电池电解质的研究进展" . | 储能科学与技术 11 . 07 (2022) : 2075-2082 .
APA 裴英伟 , 张红 , 王星辉 . 可充电锌离子电池电解质的研究进展 . | 储能科学与技术 , 2022 , 11 (07) , 2075-2082 .
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可充电锌离子电池电解质的研究进展 CSCD PKU
期刊论文 | 2022 , 11 (07) , 2075-2082 | 储能科学与技术
可充电锌离子电池电解质的研究进展 CSCD PKU
期刊论文 | 2022 , 11 (7) , 2075-2082 | 储能科学与技术
基于1DCNN-LSTM的锂离子电池SOH预测 CSCD PKU
期刊论文 | 2022 , 11 (1) , 240-245 | 储能科学与技术
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Abstract :

为了提高锂离子电池健康状态(SOH)的预测精准度和稳定性,针对常规特征选取复杂且无法有效利用等问题,提出了一种联合一维卷积(1DCNN)与长短记忆网络(LSTM)的电池SOH预测方法.首先采用多通道串联电压、电流、温度构建多维特征,然后采用1DCNN从样本数据中提取高级数据特征输入LSTM中以有效利用历史信息,最后通过全连接层输出电池SOH的预测结果.采用NASA锂离子电池容量衰减数据,对所应用的联合算法进行验证,结果表明,相较于其他预测算法,基于1DCNN-LSTM的算法具有更准确的SOH预测结果,其平均绝对误差(MAE)为0.01左右,且失效点误差周期(RUL)小于2个周期.

Keyword :

1DCNN 1DCNN LSTM LSTM 多通道特征 多通道特征 电池寿命 电池寿命 锂电池 锂电池

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GB/T 7714 王英楷 , 张红 , 王星辉 . 基于1DCNN-LSTM的锂离子电池SOH预测 [J]. | 储能科学与技术 , 2022 , 11 (1) : 240-245 .
MLA 王英楷 et al. "基于1DCNN-LSTM的锂离子电池SOH预测" . | 储能科学与技术 11 . 1 (2022) : 240-245 .
APA 王英楷 , 张红 , 王星辉 . 基于1DCNN-LSTM的锂离子电池SOH预测 . | 储能科学与技术 , 2022 , 11 (1) , 240-245 .
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基于1DCNN-LSTM的锂离子电池SOH预测 CSCD PKU
期刊论文 | 2022 , 11 (01) , 240-245 | 储能科学与技术
基于1DCNN-LSTM的锂离子电池SOH预测 CSCD PKU
期刊论文 | 2022 , 11 (01) , 240-245 | 储能科学与技术
Numerical Simulation Study of SnS Thin Film Solar Cells with TiO2 Buffer Layer [TiO2缓冲层在SnS薄膜太阳能电池中的数值仿真研究] Scopus PKU
期刊论文 | 2022 , 42 (4) , 299-305 | Research and Progress of Solid State Electronics
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Abstract :

SnS is a non-toxic, low-cost material and becomes one of the most promising absorber materials in thin film solar cells for the high absorption coefficient and near-optimal bandgap. However, the reported efficiencies of SnS devices are low. the numerical simulation of SnS thin film solar cells equipped with TiO2 buffer layer was investigated in this paper.Firstly, the cell parameters such as thickness and doping concentration of absorber layer and buffer layer were discussed. After optimization, the maximum power conversion efficiency of 15.66% has been reached. Then, the effect of working temperature and back contact metal work function on the performance parameters of SnS based solar cell was studied. The simulation results show that the temperature coefficient of the conversion efficiency is -0.029%/K. When the back contact metal work function is larger than 5.1 eV, the cell performance is better. All these simulations provide theoretical guidance for the research and development of SnS thin film solar cell with highly efficient energy harvesting. © 2022, Editorial Office of «Res. Prog. SSE». All right reserved.

Keyword :

Numerical simulation Numerical simulation Solar cells Solar cells Stannous sulfide(SnS) Stannous sulfide(SnS) Titanium dioxide(TiO2) Titanium dioxide(TiO2)

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GB/T 7714 Zhang, H. , Zhang, G. , Ning, Y. . Numerical Simulation Study of SnS Thin Film Solar Cells with TiO2 Buffer Layer [TiO2缓冲层在SnS薄膜太阳能电池中的数值仿真研究] [J]. | Research and Progress of Solid State Electronics , 2022 , 42 (4) : 299-305 .
MLA Zhang, H. et al. "Numerical Simulation Study of SnS Thin Film Solar Cells with TiO2 Buffer Layer [TiO2缓冲层在SnS薄膜太阳能电池中的数值仿真研究]" . | Research and Progress of Solid State Electronics 42 . 4 (2022) : 299-305 .
APA Zhang, H. , Zhang, G. , Ning, Y. . Numerical Simulation Study of SnS Thin Film Solar Cells with TiO2 Buffer Layer [TiO2缓冲层在SnS薄膜太阳能电池中的数值仿真研究] . | Research and Progress of Solid State Electronics , 2022 , 42 (4) , 299-305 .
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