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学者姓名：郑开魁
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ZIF-8 is widely applied in lubrication,adsorption,and catalysis owing to its unique physicochemical properties.Previous experimental studies have demonstrated its feasibility as a lubricant additive.In the present work,the lubricating performance of ZIF-8 as an additive to lithium-based grease is quantitatively and dynamically analyzed at the atomic scale using molecular dynamics simulations.Friction wear experiments are also conducted to elucidate the lubrication mechanism of ZIF-8.The simulation and experimental results indicate that the incorporation of ZIF-8 effectively enhances the antifriction and antiwear characteristics of lithium grease.The most significant improvement in the lubrication performance of the grease is obtained at a mass fraction of 2.0 wt.％ZIF-8,which reduces the friction factor μ of the grease by about 17.0％and the wear by～40.0％.Furthermore,the molecular dynamics simulations reveal that ZIF-8 primarily functions as a ball bearing under low-load conditions.However,under high-load conditions,ZIF-8 undergoes significant deformation and primarily acts as a filler.This explains the experimentally observed significant reduction in friction coefficient after the addition of ZIF-8.The results of this study provide a theoretical foundation for the development of new environmentally friendly grease additives.
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| GB/T 7714 | Ling Pan , Zhi Li , Yunli Wu et al. Study on the sliding tribological behavior of ZIF-8 under lubricating grease conditions [J]. | 纳米技术与精密工程（英文版） , 2025 , 8 (1) : 25-35 . |
| MLA | Ling Pan et al. "Study on the sliding tribological behavior of ZIF-8 under lubricating grease conditions" . | 纳米技术与精密工程（英文版） 8 . 1 (2025) : 25-35 . |
| APA | Ling Pan , Zhi Li , Yunli Wu , Kaikui Zheng , Yuqing Han . Study on the sliding tribological behavior of ZIF-8 under lubricating grease conditions . | 纳米技术与精密工程（英文版） , 2025 , 8 (1) , 25-35 . |
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目的 研究稠化剂组分中二元酸和硼酸对润滑脂在摩擦副表面润滑性能的影响.方法 分别建立具有正弦曲面凸峰的粗糙面边界润滑系统模型,以及光滑壁面的反应力场边界润滑系统模型,通过分子动力学模拟方法研究 12-羟基硬脂酸/壬二酸润滑脂体系(A润滑脂)、12-羟基硬脂酸/十二烷二酸润滑脂体系(B润滑脂)和12-羟基硬脂酸/壬二酸/硼酸润滑脂体系(C润滑脂)的承载能力、抗剪切能力、摩擦性能,并对C润滑脂进行成键和摩擦化学反应膜分析.结合润滑脂的微摩擦磨损试验,揭示二元酸链长和硼酸对润滑脂摩擦性能的影响.结果 在加压阶段,随着压力的增加,润滑脂密度增大,且分层现象越明显.当压力 Pz=50 MPa时,组分中含硼酸的C润滑脂在各处的密度均较小,表现出最佳的承载能力.在剪切过程中,C润滑脂始终将 2 个粗糙峰隔开,油膜不破裂,承载能力最高;含长链二元酸的B润滑脂和含硼酸的C润滑脂的最大应力相较于A润滑脂,分别降低了 27.1%、57.1%.同时,C润滑脂的摩擦因数相对稳定,在 0.075～0.095范围内波动,其均值为 0.090,相较于 B 润滑脂和 A 润滑脂,分别降低了 16.7%、22.2%,具有优良的力学性能.摩擦磨损结果表明,在稠化剂组分中添加硼酸后,润滑脂的理化性能得到显著提升,摩擦因数及均值分别为 0.085～0.095 和 0.091,模拟结果与试验结果一致.结论 相较于稠化剂中含短链二元酸的润滑脂,含长链二元酸的润滑脂表现出较好的抗剪切能力和摩擦性能.在稠化剂中添加硼酸后,稠化剂的结构得到强化,润滑脂表现出更为优异的抗磨减摩性能.这是因为在硼酸的作用下,润滑脂中的锂皂和硼酸基团不仅形成了配位键,而且能在固体壁面上形成摩擦反应膜,显著提高了润滑脂的物理化学性能.
Keyword ：
分子动力学 分子动力学 摩擦反应膜 摩擦反应膜 摩擦性能 摩擦性能 润滑脂 润滑脂 稠化剂组分 稠化剂组分
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| GB/T 7714 | 潘伶 , 吴允李 , 连金良 et al. 稠化剂组分对润滑脂摩擦性能的影响 [J]. | 表面技术 , 2025 , 54 (5) : 83-92 . |
| MLA | 潘伶 et al. "稠化剂组分对润滑脂摩擦性能的影响" . | 表面技术 54 . 5 (2025) : 83-92 . |
| APA | 潘伶 , 吴允李 , 连金良 , 郑开魁 , 郭锦阳 . 稠化剂组分对润滑脂摩擦性能的影响 . | 表面技术 , 2025 , 54 (5) , 83-92 . |
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This study investigated the fabrication of a strengthened Ti-TiO2 material with adding 0.5 wt.% TiO2 nanoparticles via selective laser melting process in comparison with CP-Ti. Through the process parameters optimized by response surface methodology, the Ti-TiO2 material fabricated by SLM showed remarkable tensile strength of 800.6 MPa and elongation of 14%, as compared to the fabricated CP-Ti with tensile strength of 594.0 MPa and elongation of 21%. The x-ray diffraction patterns of fabricated specimens showed the expansion of the hcp-Ti lattice along the c-axis due to dissolved oxygen atoms from the decomposition of TiO2 nanoparticles. The microstructure analysis observed remains of incompletely decomposed TiO2 and TiO phases in SLMed Ti-TiO2 material, which was distinguished from former studies. Consequently, the decomposition behavior of added TiO2 nanoparticles associated with the dissolved oxygen in the Ti-matrix during the SLM process was discussed. Based on the evaluation of both the solution effect of oxygen atoms and the reinforcing effect of undecomposed nanoparticles, the dissolved oxygen from decomposed TiO2 was considered the primary factor in the intensified strength of SLMed Ti-TiO2 material. These results could offer novel insights into the additive manufacturing of high-strength and biocompatible titanium alloy via the SLM process.
Keyword ：
additive manufacturing additive manufacturing biomaterials biomaterials composites composites metallic matrix metallic matrix strengthening mechanism strengthening mechanism titanium titanium
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| GB/T 7714 | Xiang, Hongliang , Chen, Xiaoyu , Huang, Ye et al. Decomposition Behavior and Strengthening Mechanism of Ti-TiO2 Material in Selective Laser Melting Process [J]. | JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE , 2025 . |
| MLA | Xiang, Hongliang et al. "Decomposition Behavior and Strengthening Mechanism of Ti-TiO2 Material in Selective Laser Melting Process" . | JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE (2025) . |
| APA | Xiang, Hongliang , Chen, Xiaoyu , Huang, Ye , Wu, Chaochao , Mou, Gang , Zheng, Kaikui . Decomposition Behavior and Strengthening Mechanism of Ti-TiO2 Material in Selective Laser Melting Process . | JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE , 2025 . |
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ARTICLE HIGHLIGHTS • The results of friction and wear tests show that when ZIF-8 is used as a lubricant additive for lithium-based grease, the best antifriction and antiwear effects can be achieved when the mass fraction is 2.0 wt. %. • Experimental and simulation results show that ZIF-8 with a mass fraction of 2.0 wt. % reduces the friction coefficient μ of lithium-based grease by about 17% and reduces wear by about 40%. • Molecular dynamics simulations show that ZIF-8 mainly reduces friction and resists wear by increasing the load-bearing capacity of the grease and the role of ball bearings. Additionally, as the load increases, ZIF-8 particles undergo a certain amount of deformation, gradually weakening the action of the ball bearings. © 2024 Author(s).
Keyword ：
Ball bearings Ball bearings Friction Friction Lubricating greases Lubricating greases Tribology Tribology Wear of materials Wear of materials
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| GB/T 7714 | Pan, Ling , Li, Zhi , Wu, Yunli et al. Study on the sliding tribological behavior of ZIF-8 under lubricating grease conditions [J]. | Nanotechnology and Precision Engineering , 2025 , 8 (1) . |
| MLA | Pan, Ling et al. "Study on the sliding tribological behavior of ZIF-8 under lubricating grease conditions" . | Nanotechnology and Precision Engineering 8 . 1 (2025) . |
| APA | Pan, Ling , Li, Zhi , Wu, Yunli , Zheng, Kaikui , Han, Yuqing . Study on the sliding tribological behavior of ZIF-8 under lubricating grease conditions . | Nanotechnology and Precision Engineering , 2025 , 8 (1) . |
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The surface of the TC11 titanium alloy is significantly strengthened through the ultrasonic tumbling process. The effect of ultrasonic tumbling process parameters on the microstructure and surface roughness of a titanium alloy using multiple techniques are investigated, including OM, white light interferometry, SEM, EDS, and XRD. The hardness, friction, and wear properties of the rolling surface are analyzed using a microhardness tester and a multifunctional friction-wear tester. The results indicate that the surface roughness of the titanium alloy decreases initially and then increases with an increase in rolling power, rolling times, static pressure, reduction, spindle speed, and feed rate. The lowest value is achieved with the following parameters: 660 W rolling power, 5 rolling times, static pressure of 0.20 MPa, reduction of 0.15 mm, spindle speed of 200 r·min−1, and feed rate of 0.10 mm·r−1. With an increase in power, the surface hardness of titanium alloy increases, which leads to a reduction in friction coefficient and wear loss. As the rolling times, static pressure, reduction, spindle speed, and feed rate increase, the surface hardness initially increases and then decreases. Meanwhile, the friction coefficient and wear loss tend to decrease initially and then increase. When the rolling power is set to 990 W, the rolling frequency is 5 times, the static pressure is 0.20 MPa, the reduction is 0.15 mm, the spindle speed is 200 r·min−1, and the feed rate is 0.10 mm·r−1, the hardness reaches its maximum value, while the friction coefficient and wear loss reach their minimum values. Response surface optimization was conducted to obtain the optimal process parameters, including a rolling power of 990 W, rolling frequency of 5 times, static pressure strength of 0.20 MPa, reduction of 0.15 mm, spindle speed of 198 r·min−1, and feed rate of 0.10 mm·r−1. Compared to the surface of the titanium alloy before rolling, the hardness increased by 36.4% from 337 HV to 461 HV, the surface roughness decreased by 89.9% from 1.88 μm to 0.19 μm, and the wear loss decreased by 83.3% from 0.60 mg to 0.10 mg. © 2024 Chinese Mechanical Engineering Society. All rights reserved.
Keyword ：
Friction Friction Hardness Hardness Rolling Rolling Surface properties Surface properties Surface roughness Surface roughness Titanium alloys Titanium alloys Wear of materials Wear of materials
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| GB/T 7714 | Zheng, Kaikui , Zhao, Xinzhe , Mou, Gang et al. Surface Quality, Friction and Wear Properties of TC11 Titanium Alloy Strengthened Using Ultrasonic Rolling [J]. | Journal of Mechanical Engineering , 2024 , 60 (9) : 137-151 . |
| MLA | Zheng, Kaikui et al. "Surface Quality, Friction and Wear Properties of TC11 Titanium Alloy Strengthened Using Ultrasonic Rolling" . | Journal of Mechanical Engineering 60 . 9 (2024) : 137-151 . |
| APA | Zheng, Kaikui , Zhao, Xinzhe , Mou, Gang , Ren, Zhiying . Surface Quality, Friction and Wear Properties of TC11 Titanium Alloy Strengthened Using Ultrasonic Rolling . | Journal of Mechanical Engineering , 2024 , 60 (9) , 137-151 . |
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Inertial-based upper limb motion capture technology is widely applied in directly controlling robots through human motions due to its low cost and portability. Most upper limb motion capture models typically focus solely on estimating the wrist position (WP) while neglecting the motion of the wrist. Moreover, these models struggle to precisely estimate joint positions, especially in the presence of magnetic disturbances. In this article, a two-layer upper limb motion capture model is proposed. In the upper layer of the model, a hand center position estimation method (HCPEM) is presented to estimate accurately hand center position (HCP) regardless of magnetic field interference. In the lower layer of the model, an optimized sensor-to-segment alignment algorithm based on physical constraints (OABPCs) is proposed to align sensors and segments with the aim of improving the precision of the estimated HCPs. The UR3 robotic experiment platform was designed to verify the accuracy of the HCPs. For different motion tasks and different mounting positions of the inertial measurement units (IMUs), the performance of the proposed two-layer model was further investigated through experiments. The results show that the HCP estimated by the proposed two-layer model achieves root-mean-square errors (RMSEs) below 2.5 cm for different motion tasks and various IMU mounting positions, even in the presence of magnetic field disturbances. Compared with the existing algorithm, the RMSE of the joint position measurements is improved by 1 cm. This study enables flexible, accurate, and convenient control of the robot through human motion.
Keyword ：
Estimation Estimation Inertial measurement unit (IMU) Inertial measurement unit (IMU) magnetic field disturbances magnetic field disturbances motion capture motion capture Motion capture Motion capture position estimate position estimate Robot kinematics Robot kinematics Robots Robots Robot sensing systems Robot sensing systems Task analysis Task analysis Wrist Wrist
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| GB/T 7714 | Xue, Kuikui , Zheng, Kaikui , Yang, Jinxing et al. An Inertia-Based Upper Limb Motion Capture Model for Accurate Position Estimation in Magnetic Field Disturbances [J]. | IEEE SENSORS JOURNAL , 2024 , 24 (3) : 3756-3765 . |
| MLA | Xue, Kuikui et al. "An Inertia-Based Upper Limb Motion Capture Model for Accurate Position Estimation in Magnetic Field Disturbances" . | IEEE SENSORS JOURNAL 24 . 3 (2024) : 3756-3765 . |
| APA | Xue, Kuikui , Zheng, Kaikui , Yang, Jinxing , Xie, Yinhui , Zhao, Mingyang , Li, Jun . An Inertia-Based Upper Limb Motion Capture Model for Accurate Position Estimation in Magnetic Field Disturbances . | IEEE SENSORS JOURNAL , 2024 , 24 (3) , 3756-3765 . |
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The surface of TC11 titanium alloy was polished and strengthened using ultrasonic rolling process (USRP) technology. The effects of USRP on the surface quality, friction and wear properties, corrosion resistance, and wear mechanisms of TC11 titanium alloy at room temperature, low temperature (-60 degrees C), high temperature (400 degrees C), and in corrosive environments were investigated by using optical microscope, microhardness tester, electrochemical workstation, multifunctional friction and wear tester, SEM, EDS, XRD, and XPS. The results indicate that USRP can effectively refine the surface grains of titanium alloy, reducing its surface roughness parameter by 80.4 % and increasing surface hardness and residual compressive stress by 21.7 % and 97.1 %, respectively. USRP is advantageous for producing a layer of TiO2 on the surface of titanium alloys, effectively enhancing the corrosion resistance of titanium alloy surfaces. USRP technology can improve the stability of surface hardness values of titanium alloys in harsh environments. The results of dry friction and wear tests using GCr15 steel balls as the counter material show that the USRP technology can effectively reduce the friction coefficient and wear loss at room, high and low temperatures. The results of corrosion and wear tests using Si3N4 as the counter material indicate that the USRP technology can effectively reduce the friction coefficient and wear volume in seawater corrosion environments. The USRP technology is most effective in reducing the hightemperature friction coefficient of titanium alloys and improving their wear resistance in low-temperature and corrosive environments. The primary wear form of TC11 titanium alloy after USRP has shifted from adhesive wear to abrasive wear.
Keyword ：
Corrosion Corrosion Surface strengthening Surface strengthening Titanium alloy Titanium alloy Ultrasonic rolling Ultrasonic rolling Wear resistance Wear resistance
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| GB/T 7714 | Zheng, Kaikui , Zhao, Xinzhe , Pan, Ling et al. Ultrasonic rolling strengthening of TC11 titanium alloy surface: Corrosion and wear properties under extreme conditions [J]. | WEAR , 2024 , 550-551 . |
| MLA | Zheng, Kaikui et al. "Ultrasonic rolling strengthening of TC11 titanium alloy surface: Corrosion and wear properties under extreme conditions" . | WEAR 550-551 (2024) . |
| APA | Zheng, Kaikui , Zhao, Xinzhe , Pan, Ling , Ren, Zhiying . Ultrasonic rolling strengthening of TC11 titanium alloy surface: Corrosion and wear properties under extreme conditions . | WEAR , 2024 , 550-551 . |
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Copper particles emitted from braking have become a significant source of environmental pollution. However, copper plays a crucial role in resin-based braking materials. Developing high-performance braking materials without copper has become a significant challenge. In this paper, the resin-based braking materials were filled with fly-ash cenospheres to develop copper-free braking materials. The effects of fly-ash cenospheres on the physical properties, mechanical and friction and wear properties of braking materials were studied. Furthermore, the wear mechanism of copper-free resin-based braking materials filled with fly-ash cenospheres was discussed. The results indicate that the inclusion of fly-ash cenospheres in the braking materials improved their thermal stability, hardness and impact strength, reduced their density, effectively increased the friction coefficient at medium and high temperatures, and enhanced the heat-fade resistance of the braking materials. The inclusion of fly-ash cenospheres contributed to the formation of surface friction film during the friction process of the braking materials, and facilitated the transition of form from abrasive wear to adhesive wear. At 100-350 celcius, the friction coefficient of the optimal formulation is in the range of 0.57-0.61, and the wear rate is in the range (0.29-0.65) x 10-7 cm3 center dot N-1 center dot m-1, demonstrating excellent resistance to heat-fade and stability in friction coefficient. This research proposes the use of fly-ash cenospheres as a substitute for environmentally harmful and expensive copper in brake materials, which not only improves the performance of braking materials but also reduces their costs.
Keyword ：
Braking materials Braking materials Fly-ash cenospheres Fly-ash cenospheres Friction and wear Friction and wear Heat-fade resistance Heat-fade resistance Wear form Wear form
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| GB/T 7714 | Zheng, Kaikui , Lin, Youxi , You, Shanmin et al. Copper-Free Resin-Based Braking Materials: A New Approach for Substituting Copper with Fly-Ash Cenospheres in Composites [J]. | CHINESE JOURNAL OF MECHANICAL ENGINEERING , 2024 , 37 (1) . |
| MLA | Zheng, Kaikui et al. "Copper-Free Resin-Based Braking Materials: A New Approach for Substituting Copper with Fly-Ash Cenospheres in Composites" . | CHINESE JOURNAL OF MECHANICAL ENGINEERING 37 . 1 (2024) . |
| APA | Zheng, Kaikui , Lin, Youxi , You, Shanmin , Ren, Zhiying , Huang, Jianmeng . Copper-Free Resin-Based Braking Materials: A New Approach for Substituting Copper with Fly-Ash Cenospheres in Composites . | CHINESE JOURNAL OF MECHANICAL ENGINEERING , 2024 , 37 (1) . |
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Copper particles emitted from braking have become a significant source of environmental pollution.However,copper plays a crucial role in resin-based braking materials.Developing high-performance braking materials with-out copper has become a significant challenge.In this paper,the resin-based braking materials were filled with fly-ash cenospheres to develop copper-free braking materials.The effects of fly-ash cenospheres on the physical properties,mechanical and friction and wear properties of braking materials were studied.Furthermore,the wear mechanism of copper-free resin-based braking materials filled with fly-ash cenospheres was discussed.The results indicate that the inclusion of fly-ash cenospheres in the braking materials improved their thermal stability,hard-ness and impact strength,reduced their density,effectively increased the friction coefficient at medium and high temperatures,and enhanced the heat-fade resistance of the braking materials.The inclusion of fly-ash cenospheres contributed to the formation of surface friction film during the friction process of the braking materials,and facilitated the transition of form from abrasive wear to adhesive wear.At 100-350 ℃,the friction coefficient of the optimal for-mulation is in the range of 0.57-0.61,and the wear rate is in the range(0.29-0.65)× 10-7cm3·N-1·m-1,demonstrating excellent resistance to heat-fade and stability in friction coefficient.This research proposes the use of fly-ash ceno-spheres as a substitute for environmentally harmful and expensive copper in brake materials,which not only improves the performance of braking materials but also reduces their costs.
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| GB/T 7714 | Kaikui Zheng , Youxi Lin , Shanmin You et al. Copper-Free Resin-Based Braking Materials:A New Approach for Substituting Copper with Fly-Ash Cenospheres in Composites [J]. | 中国机械工程学报 , 2024 , 37 (2) : 401-412 . |
| MLA | Kaikui Zheng et al. "Copper-Free Resin-Based Braking Materials:A New Approach for Substituting Copper with Fly-Ash Cenospheres in Composites" . | 中国机械工程学报 37 . 2 (2024) : 401-412 . |
| APA | Kaikui Zheng , Youxi Lin , Shanmin You , Zhiying Ren , Jianmeng Huang . Copper-Free Resin-Based Braking Materials:A New Approach for Substituting Copper with Fly-Ash Cenospheres in Composites . | 中国机械工程学报 , 2024 , 37 (2) , 401-412 . |
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Ti-steel laminated metal composites have been widely used in shipbuilding and the chemical industry due to the superior corrosion resistance of Ti and the favorable mechanical properties of stainless steel. In this paper, Tisteel laminated metal composites without Ti-Fe IMCs have been fabricated by directed energy deposition-arc method using a Cu-Ni transition interlayer. Based on the analysis of microstructure analysis, the crosssectional microstructure can be divided into 304SS / Cu-Ni interface containing (Fe, Cr) and (Cu) solid solution, Cu-Ni deposition layer containing (Fe, Cr) and (Cu) solid solution, and TA2/Cu-Ni interface containing Ti2FeCu and Ti-Cu IMCs. Besides, the Cu-Ni deposition layer contains a small content of recrystallized grains with {100}<100> texture and a large content of deformed grains with{100}<110> texture due to the impact of arc and droplets during continuous depositions. Furthermore, the peak hardness is decreased to 518 Hv and the mean value of compressive shear strength is enhanced to 195.27 MPa, which can be attributed to the elimination of interfacial Ti-Fe IMCs, defect-free microstructure, and residual stress relief. Based on polarization curves and electrochemical impedance spectroscopy, the corrosion resistance reduction of the cross-section is due to the formation of a mass of primary battery systems. Furthermore, based on the thermodynamics calculation of Fe-CuNi, Ti-Fe-Cu, and Ti-Ni-Cu ternary systems, the alloying mechanism is that Ti-based IMCs with lower Gibbs free energy will be formed instead of brittle Ti-Fe IMCs, resulting in the elimination of Ti-Fe IMCs and the formation of less brittle phases at both 304SS / Cu-Ni interface and TA2 / Cu-Ni interface.
Keyword ：
Additive manufacturing Additive manufacturing Interfacial alloying Interfacial alloying Laminated metal composite Laminated metal composite Mechanical property Mechanical property Microstructure Microstructure
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| GB/T 7714 | Mou, Gang , Sheng, Haiyang , Zheng, Kaikui et al. Dual-interfacial alloying mechanism in Ti-steel laminated metal composite fabricated by wire-arc directed energy deposition using a Cu-Ni interlayer [J]. | JOURNAL OF ALLOYS AND COMPOUNDS , 2024 , 1010 . |
| MLA | Mou, Gang et al. "Dual-interfacial alloying mechanism in Ti-steel laminated metal composite fabricated by wire-arc directed energy deposition using a Cu-Ni interlayer" . | JOURNAL OF ALLOYS AND COMPOUNDS 1010 (2024) . |
| APA | Mou, Gang , Sheng, Haiyang , Zheng, Kaikui , Xiang, Hongliang , Ren, Wenjie , Ding, Yuhan . Dual-interfacial alloying mechanism in Ti-steel laminated metal composite fabricated by wire-arc directed energy deposition using a Cu-Ni interlayer . | JOURNAL OF ALLOYS AND COMPOUNDS , 2024 , 1010 . |
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