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学者姓名:江义平
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Abstract :
In this paper, isobaric (vapor + liquid) equilibrium (VLE) data for the binary system methanol + 2-butyl alcohol and the quaternary system methyl acetate + methanol + 2-butyl alcohol + 2-butyl acetate were determined at P = 101.33 kPa in a modified Rose still. The binary VLE data were found to be thermodynamic consistency by the Herrington method. The VLE data for the binary system were correlated by the Wilson and NRTL equations respectively, which were used to predict the VLE data of the quaternary system. The results showed that the Wilson and NRTL models matched well with the (vapor + liquid) phase equilibrium data. The deviations for the vapor-phase compositions and the equilibrium temperatures are reasonably small and the models are both suitable for these systems. (C) 2013 Elsevier Ltd. All rights reserved.
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2-Butyl alcohol 2-Butyl alcohol Quaternary Quaternary Transesterification Transesterification (Vapor plus liquid) equilibrium (Vapor plus liquid) equilibrium
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GB/T 7714 | Wang, Hong-xing , Bu, Xiang-wei , Yang, Jin-bei et al. Isobaric (vapor plus liquid) equilibrium data for the binary system methanol+2-butyl alcohol and the quaternary system methyl acetate plus methanol+2-butyl alcohol+2-butyl acetate at P=101.33 kPa [J]. | JOURNAL OF CHEMICAL THERMODYNAMICS , 2014 , 74 : 85-90 . |
MLA | Wang, Hong-xing et al. "Isobaric (vapor plus liquid) equilibrium data for the binary system methanol+2-butyl alcohol and the quaternary system methyl acetate plus methanol+2-butyl alcohol+2-butyl acetate at P=101.33 kPa" . | JOURNAL OF CHEMICAL THERMODYNAMICS 74 (2014) : 85-90 . |
APA | Wang, Hong-xing , Bu, Xiang-wei , Yang, Jin-bei , Jiang, Yi-ping , Li, Ling . Isobaric (vapor plus liquid) equilibrium data for the binary system methanol+2-butyl alcohol and the quaternary system methyl acetate plus methanol+2-butyl alcohol+2-butyl acetate at P=101.33 kPa . | JOURNAL OF CHEMICAL THERMODYNAMICS , 2014 , 74 , 85-90 . |
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Abstract :
In the title compound, C14H26ClN5, the triazine ring is almost planar and both pendant alkyl chains are disordered; the site occupancy ratios are 0.5:0.5 for the tert-butyl chain and approximately 0.6:0.4 for the n-propyl chain. The crystal packing is consolidated by N - H...N hydrogen bonds, resulting in infinite chains propagating along [001].
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GB/T 7714 | Jiang, Yi-Ping , Qiu, Ting , Wang, Liang-En et al. 6-Chloro-N-2-propyl-N-4-(2,4,4-trimethylpentan-2-yl)-1,3,5-triazine-2,4-diamine [J]. | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS , 2007 , 63 : O3096-U2514 . |
MLA | Jiang, Yi-Ping et al. "6-Chloro-N-2-propyl-N-4-(2,4,4-trimethylpentan-2-yl)-1,3,5-triazine-2,4-diamine" . | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS 63 (2007) : O3096-U2514 . |
APA | Jiang, Yi-Ping , Qiu, Ting , Wang, Liang-En , Wang, Jia-Ning . 6-Chloro-N-2-propyl-N-4-(2,4,4-trimethylpentan-2-yl)-1,3,5-triazine-2,4-diamine . | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS , 2007 , 63 , O3096-U2514 . |
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The title compound, C15H26ClN5O, was synthesized by the reaction of 2,4,6-trichloro-1,3,5-triazine with 2,4,4-trimethylpentan-2-amine and morpholine. The triazine ring is planar and the morpholine ring displays a typical chair conformation. Intermolecular N-H center dot center dot center dot O hydrogen bonding is present in the crystal structure.
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GB/T 7714 | Jiang, Yi-Ping , Qiu, Ting , Wang, Liang-En et al. 4-Chloro-6-morpholino-N-2-(2,4,4trimethylpentan-2-yl)-1,3,5-triazin-2amine [J]. | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS , 2007 , 63 : O3173-U3161 . |
MLA | Jiang, Yi-Ping et al. "4-Chloro-6-morpholino-N-2-(2,4,4trimethylpentan-2-yl)-1,3,5-triazin-2amine" . | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS 63 (2007) : O3173-U3161 . |
APA | Jiang, Yi-Ping , Qiu, Ting , Wang, Liang-En , Wang, Jia-Ning . 4-Chloro-6-morpholino-N-2-(2,4,4trimethylpentan-2-yl)-1,3,5-triazin-2amine . | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS , 2007 , 63 , O3173-U3161 . |
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