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学者姓名:江献财
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Among many ways that can improve the electrolysis catalysts of seawater, designing the catalyst with hierarchical nanostructure has received extensive attention because it allows a larger surface area and more active sites. In this work, the NC-enveloped CoS/NiS@Cu2S catalyst with multi-level structure was successfully synthesized by using the complex of trithiocyanuric acid and copper as the metal dopant to coat the spherical Co-Ni precursor, and then by a straightforward one-step high-temperature self-vulcanization reaction. Trithiocyanuric acid not only facilitated the sulfurization of metal elements but also served as N and C source coated on the catalyst. This method constructed structure-controllable, multi-level, and yolk-shelled nanostructure in a facile manner, greatly increasing specific surface area, expanded mass transport channels, and enhancing the exposure of active sites. Besides, the coating of N and C elements significantly increased the electrical conductivity and electrochemical activity of the catalyst. As a result, CoS/NiS@Cu2S@NC exhibited excellent hydrogen evolution performance with the small overpotential of 105, 161, and 176 mV at 10 mA cm-2 in alkaline water, simulated alkaline seawater, and alkaline seawater, respectively. The present approach is proposed as an inspirational idea of the design of cobalt-nickel-copper-based multi-level structural nanomaterials as non-platinum electrocatalysts for hydrogen evolution in seawater.
Keyword :
Alkaline seawater Alkaline seawater CoS/NiS@Cu 2 S@NC CoS/NiS@Cu 2 S@NC Hydrogen evolution reaction Hydrogen evolution reaction Non-platinum electrocatalyst Non-platinum electrocatalyst Transition metal chalcogenide Transition metal chalcogenide Yolk-shelled structure Yolk-shelled structure
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GB/T 7714 | Guo, Ming , Luo, Ao , Guan, Guoxiang et al. Multi-level structure-controllable NC-enveloped CoS/NiS@Cu2S yolk-shelled nanospheres as Pt-free catalysts for efficient hydrogen evolution in alkaline water/seawater [J]. | FUEL , 2025 , 389 . |
MLA | Guo, Ming et al. "Multi-level structure-controllable NC-enveloped CoS/NiS@Cu2S yolk-shelled nanospheres as Pt-free catalysts for efficient hydrogen evolution in alkaline water/seawater" . | FUEL 389 (2025) . |
APA | Guo, Ming , Luo, Ao , Guan, Guoxiang , Qian, Xing , Yi, Ting , Chen, Ming et al. Multi-level structure-controllable NC-enveloped CoS/NiS@Cu2S yolk-shelled nanospheres as Pt-free catalysts for efficient hydrogen evolution in alkaline water/seawater . | FUEL , 2025 , 389 . |
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The in-situ polymerization of 1,3-dioxolane (PDOL) in battery cells has attracted extensive attention, however, the differences of Lewis acid initiators on the DOL monomer conversion (C%) and electrochemical properties has been ignored. Here, it is demonstrated that compare with Sn(OTf)(2) Lewis acid initiator, the gelation of DOL is achieved at the lower addition of In(OTf)(3). By optimizing their content in the gelation process, their C% are comparable which are 95.7 % and 93.5 % for In(OTf)(3) and Sn(OTf)(2), respectively. However, the higher ionic conductivity (7.1 x 10(-4) S cm(-1) at room temperature), electrochemical window (similar to 4.5 V) and Li+ transference number (0.42) are obtained for DOL initiated with In(OTf)(3), due to its lower molecular weight which is helpful to the intermolecular Li+ transport along PDOL main chain; In addition, the Li/Li symmetrical cell of In(OTf)(3) can be stably cycled for >500 h at 3 mA cm(-2), with an over-potential of 178mv. The storage and cycling impedances of half cells further proves the stable interface of In(OTf)(3) initiated DOL toward to lithium metal in comparison with those of Sn(OTf)(2). Scanning electron microscopy results show a denser and thinner interface in the DOL catalyzed by In(OTf)(3). Finally, the assembled Li/LiFePO4 battery delivers specific discharge capacity and capacity retention rates of 115.5mAh g(-1) and 85 %, respectively after 300 cycles at 1C. Through the initiator selection, the DOL synthesis and electrochemical properties can be tuned, which further broadens the design idea of PDOL based solid polymer electrolyte.
Keyword :
1,3-Dioxolane 1,3-Dioxolane Alloyed protective layer Alloyed protective layer In-situ polymerization In-situ polymerization Lithium metal battery Lithium metal battery Solid polymer electrolyte Solid polymer electrolyte
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GB/T 7714 | Deng, Haoyu , Yang, Xueting , Chen, Hanghang et al. Superior initiator reactivity and electrochemical properties of In(OTf)3 over Sn(OTf)2 for 1,3-dioxolane based solid polymer electrolyte [J]. | JOURNAL OF ENERGY STORAGE , 2024 , 100 . |
MLA | Deng, Haoyu et al. "Superior initiator reactivity and electrochemical properties of In(OTf)3 over Sn(OTf)2 for 1,3-dioxolane based solid polymer electrolyte" . | JOURNAL OF ENERGY STORAGE 100 (2024) . |
APA | Deng, Haoyu , Yang, Xueting , Chen, Hanghang , Ye, Dezhan , Jiang, Xiancai , Chen, Yazhou et al. Superior initiator reactivity and electrochemical properties of In(OTf)3 over Sn(OTf)2 for 1,3-dioxolane based solid polymer electrolyte . | JOURNAL OF ENERGY STORAGE , 2024 , 100 . |
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Synthesizing high-performance of gel polymer electrolytes (GPEs) with simple methods and common materials has long been a crucial concern for lithium-ion batteries. Here, the poor mechanical properties of polyethylene oxide (PEO) based GPEs were overcome by introducing strong hydrogen bond between PEO and polyacrylic acid (PAA). Easy-available PEO/PAA membranes were prepared though hot processing approach without use of organic solvent during all processes. The mechanical properties and crystalline of dry composites could be tuned by the addition content of PAA. After quick absorbing electrolyte in 30 min, the tensile strength and elongation at break of the GPEs composites are ranged from 0.07 to 0.63 MPa, and 525% to 722%. Moreover, the lithium-ion conductivity and transference number with 30 wt% addition of PAA reach up to 1.66 and 0.58 mS/cm, respectively. After 500 cycling at 0.5 C, the discharge specific capacity and the capacity retention rate are still up to 134.1 mAh/g and 88.7%, respectively. This research proves the great possibility of applying environmentally friendly method, low cost, and high electrochemical performances of PEO/PAA based GPEs in the lithium batteries. The poor mechanical properties of polyethylene oxide (PEO) gel polymer electrolytes were overcome by introducing strong hydrogen bond between it and polyacrylic acid (PAA).image
Keyword :
gel polymer electrolyte gel polymer electrolyte hydrogen bond hydrogen bond lithium ion battery lithium ion battery mechanical properties mechanical properties polyethylene oxides polyethylene oxides
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GB/T 7714 | Jin, Bihui , Zhao, Yunyang , Ye, Dezhan et al. Mechanically robust and highly electrochemical performance of polyethylene oxide gel polymer electrolyte [J]. | JOURNAL OF APPLIED POLYMER SCIENCE , 2024 , 141 (14) . |
MLA | Jin, Bihui et al. "Mechanically robust and highly electrochemical performance of polyethylene oxide gel polymer electrolyte" . | JOURNAL OF APPLIED POLYMER SCIENCE 141 . 14 (2024) . |
APA | Jin, Bihui , Zhao, Yunyang , Ye, Dezhan , Jiang, Xiancai , Ye, Xianke , Li, Chen . Mechanically robust and highly electrochemical performance of polyethylene oxide gel polymer electrolyte . | JOURNAL OF APPLIED POLYMER SCIENCE , 2024 , 141 (14) . |
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Polyacrylamide (PAM) is a polymer compound that is widely used in oil extraction, wastewater treatment, food processing and other fields. As a typical polymer flooding agent, PAM has received much attention in the field of oil extraction due to its unique of viscoelastic properties. However, polymer flooding faces several challenges in oil reservoirs, including high injection pressure, high shear loss and crossflow. In an effort to overcome this challenge, we designed a method of coating Ca2+ cross-linked sodium alginate onto the core structure of polyacrylamide, providing shear resistance and sustained release performance for the polymer. The important role of the shell material was indirectly demonstrated by measuring its apparent viscosity using digital rotary viscometer. Moreover, the swelling behavior of microcapsules in water was observed using an optical microscope. The protective shell made the slow release of anionic PAM into water under stirring at 500 rpm, maintaining the viscosity of the fluid below 10 mPa center dot s within 2 h, and the viscosity increased from 1.8 mPa center dot s to 30 mPa center dot s after 35 h. In addition, this work revealed the importance of effective encapsulation by emulsification/external gelation method and a facile shell modification by the layer-by-layer self-assembly method. [GRAPHICS]
Keyword :
Anionic polyacrylamide Anionic polyacrylamide delayed thickening delayed thickening encapsulation encapsulation layer-by-layer self-assembly layer-by-layer self-assembly sodium alginate sodium alginate
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GB/T 7714 | You, Huirong , Jiang, Xiancai , Jiang, Zuming et al. Preparation of sodium alginate encapsulated anionic polyacrylamide microcapsules with delayed thickening performance [J]. | JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY , 2024 , 61 (3) : 175-185 . |
MLA | You, Huirong et al. "Preparation of sodium alginate encapsulated anionic polyacrylamide microcapsules with delayed thickening performance" . | JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY 61 . 3 (2024) : 175-185 . |
APA | You, Huirong , Jiang, Xiancai , Jiang, Zuming , Yuan, Fuqing , Hou, Jian , Wei, Bei . Preparation of sodium alginate encapsulated anionic polyacrylamide microcapsules with delayed thickening performance . | JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY , 2024 , 61 (3) , 175-185 . |
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An available approach to ameliorate the property of electrocatalysts for transition metal selenides (TMSs) is to transform their structure, morphology, and elemental composition, especially for hydrogen evolution reactions (HER), which can be a long-term task. In this work, Ni-Co nanospheres were synthesized by a hydrothermal method, and then in the synchronous processes of selenization and carbonization, it reacted with the peripherally coated melamine-copper complex, which was the reactant between melamine and copper ions. Ultimately, CoSe 2 /NiSe 2 @Cu 2 Se-NC nanospheres with a core-shell structure were synthesized after annealing process. This special structure provided more active attachment sites, enabling CoSe 2 /NiSe 2 @Cu 2 Se-NC to exhibit excellent HER properties under wide-pH range. Especially, in acidic conditions, it had a low initial potential of 41.0 mV, a small Tafel slope value of 48.7 mV dec - 1 , and a long service life. The proposed scheme indicates that a new approach will be added to the synthesis of electrocatalysts based on TMSs.
Keyword :
Core-shell structure Core-shell structure CoSe2/NiSe2@Cu2Se-NC CoSe2/NiSe2@Cu2Se-NC Hydrogen evolution reaction Hydrogen evolution reaction Non-platinum electrocatalysts Non-platinum electrocatalysts Transition metal selenides Transition metal selenides Wide-pH range Wide-pH range
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GB/T 7714 | Guo, Ming , Chen, Siyan , Xiong, Yonglian et al. N-doped carbon-enveloped CoSe2/NiSe2@Cu2Se core-shell nanospheres as non-Pt electrocatalysts for enhanced wide-pH hydrogen evolution reactions [J]. | JOURNAL OF ALLOYS AND COMPOUNDS , 2024 , 1001 . |
MLA | Guo, Ming et al. "N-doped carbon-enveloped CoSe2/NiSe2@Cu2Se core-shell nanospheres as non-Pt electrocatalysts for enhanced wide-pH hydrogen evolution reactions" . | JOURNAL OF ALLOYS AND COMPOUNDS 1001 (2024) . |
APA | Guo, Ming , Chen, Siyan , Xiong, Yonglian , Chen, Ming , Xia, Juan , Chen, Wenbin et al. N-doped carbon-enveloped CoSe2/NiSe2@Cu2Se core-shell nanospheres as non-Pt electrocatalysts for enhanced wide-pH hydrogen evolution reactions . | JOURNAL OF ALLOYS AND COMPOUNDS , 2024 , 1001 . |
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Poly(acrylamide) (PAM) has excellent thickening ability as a conventional flooding agent. However, PAM confronts the problems of high injection pressure and high shear loss in the process of oil extraction, which have limited its application in this field. In this work, 2, 2, 6, 6-Tetramethylpiperidinooxy oxidized cellulose nano- fibers (TOCNFs) enhanced sodium alginate (SA) shell was used to encapsulate PAM to form microcapsule. The composition, morphology, structure and the releasing behaviours of TOCNFs enhanced microcapsules was tested. Mechanical stirring was used to simulate the state of polymer subjected to shear during stratigraphic transport. The release performance of the microcapsules was characterized by measuring the change of viscosity with time. The ratio of the shell material with the best performance was explored, and the enhancement mechanism of the SA shell by TOCNFs was discussed. The experiments showed that the release time of PAM from the microcapsules was significantly prolonged with the addition of TOCNFs. The longest release time was observed when the ratio of SA and TOCNFs was 5: 1, with the release time of the microcapsules from the original 8 h to 16 h. The enhanced shear resistance of the microcapsules was attributed to the semi-interpenetrating network structure of SA and TOCNFs via Ca2+ cross-linking as well as hydrogen bonding. The prepared microcapsules have promising applications in enhancing oil recovery.
Keyword :
Anionic polyacrylamide Anionic polyacrylamide Cellulose nanofibers Cellulose nanofibers Encapsulation Encapsulation Oil recovery Oil recovery Slow release Slow release Sodium alginate Sodium alginate
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GB/T 7714 | Wu, Yaowei , Jiang, Zuming , Wang, Yuhao et al. TEMPO oxidized cellulose nanofiber-reinforced sodium alginate encapsulated poly(acrylamide) microcapsules and its releasing behaviours for enhancing oil recovery [J]. | INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES , 2024 , 281 . |
MLA | Wu, Yaowei et al. "TEMPO oxidized cellulose nanofiber-reinforced sodium alginate encapsulated poly(acrylamide) microcapsules and its releasing behaviours for enhancing oil recovery" . | INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES 281 (2024) . |
APA | Wu, Yaowei , Jiang, Zuming , Wang, Yuhao , Jiang, Xiancai , Hou, Jian , Wei, Bei . TEMPO oxidized cellulose nanofiber-reinforced sodium alginate encapsulated poly(acrylamide) microcapsules and its releasing behaviours for enhancing oil recovery . | INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES , 2024 , 281 . |
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Polyacrylamide (PAM) is a polymer compound that is widely used in oil extraction, wastewater treatment, food processing and other fields. As a typical polymer flooding agent, PAM has received much attention in the field of oil extraction due to its unique of viscoelastic properties. However, polymer flooding faces several challenges in oil reservoirs, including high injection pressure, high shear loss and crossflow. In an effort to overcome this challenge, we designed a method of coating Ca2+ cross-linked sodium alginate onto the core structure of polyacrylamide, providing shear resistance and sustained release performance for the polymer. The important role of the shell material was indirectly demonstrated by measuring its apparent viscosity using digital rotary viscometer. Moreover, the swelling behavior of microcapsules in water was observed using an optical microscope. The protective shell made the slow release of anionic PAM into water under stirring at 500 rpm, maintaining the viscosity of the fluid below 10 mPa·s within 2 h, and the viscosity increased from 1.8 mPa·s to 30 mPa·s after 35 h. In addition, this work revealed the importance of effective encapsulation by emulsification/external gelation method and a facile shell modification by the layer-by-layer self-assembly method.
Keyword :
Anionic polyacrylamide Anionic polyacrylamide delayed thickening delayed thickening encapsulation encapsulation layer-by-layer self-assembly layer-by-layer self-assembly sodium alginate sodium alginate
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GB/T 7714 | Huirong You , Xiancai Jiang , Zuming Jiang et al. Preparation of sodium alginate encapsulated anionic polyacrylamide microcapsules with delayed thickening performance [J]. | Journal of Macromolecular Science, Part A , 2024 , 61 (3) : 175-185 . |
MLA | Huirong You et al. "Preparation of sodium alginate encapsulated anionic polyacrylamide microcapsules with delayed thickening performance" . | Journal of Macromolecular Science, Part A 61 . 3 (2024) : 175-185 . |
APA | Huirong You , Xiancai Jiang , Zuming Jiang , Fuqing Yuan , Jian Hou , Bei Wei . Preparation of sodium alginate encapsulated anionic polyacrylamide microcapsules with delayed thickening performance . | Journal of Macromolecular Science, Part A , 2024 , 61 (3) , 175-185 . |
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Among the various non-precious metal catalysts that drive hydrogen evolution reactions (HERs) and dyesensitized solar cells (DSSCs), transition metal selenides (TMSs) stand out due to their unique electronic properties and tunable morphology. Herein, the multicomponent selenide CuSe-Co 3 Se 4 @VSe 2 was successfully synthesized by doping with metal element vanadium and selenization on the copper-cobalt carbonate hydroxide (CuCo-CH) template. CuSe-Co 3 Se 4 @VSe 2 exhibited the dandelion-like cluster structure composed of hollow nanotubes doped with VSe 2 nanoparticles. Due to the unique structure and the synergistic effect of various elements, CuSe-Co 3 Se 4 @VSe 2 showed excellent alkaline HER and DSSC performances. The DSSC based on CuSeCo 3 Se 4 @VSe 2 exhibited an impressive power conversion efficiency (PCE) of 9.64 %, which was much higher than that of Pt (8.39 %). Besides, it possessed a low HER overpotential of 76 mV@10 mA cm-2 and a small Tafel slope of 88.9 mV dec- 1 in 1.0 M KOH.
Keyword :
Bifunctional catalyst Bifunctional catalyst CuSe-Co3Se4@VSe2 CuSe-Co3Se4@VSe2 Dye-sensitized solar cell Dye-sensitized solar cell Hollow nanotube cluster Hollow nanotube cluster Hydrogen evolution reaction Hydrogen evolution reaction Transition metal selenide Transition metal selenide
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GB/T 7714 | Qian, Xing , Yu, Hao , Chen, Wenbin et al. Dandelion-like VSe 2-embellished CuSe-Co 3 Se 4 hollow nanotube clusters as bifunctional catalysts for high-performance alkaline hydrogen evolution and solar cells [J]. | JOURNAL OF COLLOID AND INTERFACE SCIENCE , 2024 , 675 : 761-771 . |
MLA | Qian, Xing et al. "Dandelion-like VSe 2-embellished CuSe-Co 3 Se 4 hollow nanotube clusters as bifunctional catalysts for high-performance alkaline hydrogen evolution and solar cells" . | JOURNAL OF COLLOID AND INTERFACE SCIENCE 675 (2024) : 761-771 . |
APA | Qian, Xing , Yu, Hao , Chen, Wenbin , Wu, Jianhua , Xia, Juan , Chen, Ming et al. Dandelion-like VSe 2-embellished CuSe-Co 3 Se 4 hollow nanotube clusters as bifunctional catalysts for high-performance alkaline hydrogen evolution and solar cells . | JOURNAL OF COLLOID AND INTERFACE SCIENCE , 2024 , 675 , 761-771 . |
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1,3-dioxolane (DOL) shows low interfacial impedance and high Coulombic efficiency, thus its polymer electrolytes have attracted extensive attention. In order to initiate DOL polymerization, catalyst amount of LiPF6 is usually used rather than as the main lithium salt. Totally replacement of LiTFSI with low cost of LiPF6 could bring the heat explosion and high viscosity when mixing DOL with 0.9 M LiPF6 electrolyte (carbonate ester solvent). Here, based on the Lewis acid-base interaction, a new type of Lewis base, pyridine, is added to control the explosive polymerization of 1,3-dioxolane in LiPF6 electrolyte. Through tuning the pyridine content, the gelling process and electrochemical properties could be controlled. It is demonstrated that the optimized monomer conversion and electrochemical window are up to 85.2 % and 4.6 V; meanwhile, the optimized conductivity and transfer number are 0.99 x 10(-3) S/cm (25 degrees C) and 0.68, respectively. The stable interface between PDOL and lithium metal anode could be proved by the stable over-potential (50mv, 700 h) at current density of 0.5 mA cm(-2). After 500 cycles at 2C, the assembled Li/PDOL@py(0.125)/LiFePO4 battery delivers 115 mAh/g and 90 % capacity retention, with high average Coulombic efficiency of 99.83 %. The present results demonstrate the heat suppression role of pyridine toward mixing DOL with 0.9 M LiPF6 electrolyte, which solves the heat and viscosity problems for PDOL based gelling polymer electrolytes.
Keyword :
3-dioxolane 3-dioxolane Gelling polymer electrolyte Gelling polymer electrolyte Heat release Heat release In-situ polymerization In-situ polymerization lithium metal battery lithium metal battery
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GB/T 7714 | Yang, Xueting , Deng, Haoyu , Xu, Jie et al. Control the explosive polymerization of 1,3-dioxolane in LiPF6 electrolyte by Lewis acid-base interactions [J]. | JOURNAL OF ENERGY STORAGE , 2024 , 101 . |
MLA | Yang, Xueting et al. "Control the explosive polymerization of 1,3-dioxolane in LiPF6 electrolyte by Lewis acid-base interactions" . | JOURNAL OF ENERGY STORAGE 101 (2024) . |
APA | Yang, Xueting , Deng, Haoyu , Xu, Jie , Ye, Dezhan , Jiang, Xiancai , Chen, Yazhou et al. Control the explosive polymerization of 1,3-dioxolane in LiPF6 electrolyte by Lewis acid-base interactions . | JOURNAL OF ENERGY STORAGE , 2024 , 101 . |
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Conductive hydrogels have shown a great potential in the field of flexible electronics. However, it is difficult to combine high strength and high toughness in conductive hydrogels prepared by conventional methods, which limits their applications in various fields. In this work, we pioneered a facile and cost-effective strategy to prepare soy protein isolate/poly(vinyl alcohol) (SPI/PVA) conductive hydrogels with high strength, toughness, low- temperature resistance, and recyclability by introducing all the salts into the prescuor solution directly. To solve the problem of unable to directly introducing high concentration Na3Cit into the soy protein isolate/PVA solution, MgCl2 was used to alleviate the strong salting-out effect of Na3Cit. Thus the stable SPI/PVA/EG/MgCl2/ Na3Cit complex solution was obtained and the SPI/PVA/EG/MgCl2/Na3Cit (SPEMS) organohydrogel was prepared by the freezing/thawing process. The optimum tensile strength of the SPEMS organohydrogel was 1.1 +0.07 MPa, and the elongation at break was 701.3+23.67 %, respectively. Meanwhile, the ionic conductivity of the organohydrogel was as high as 1.7+0.01 S/m. Finally, the EG/H2O binary solvent system endowed the organohydrogel with excellent low-temperature resistance (freezing point of-19.4 degrees C). The strain sensors assembled with SPEMS organohydrogels were characterized by high sensitivity (GF = 3.2, strain range from 20 %-500 %) and long-term stability. The flexible all-solid-state supercapacitor assembled with SPEMS organohydrogel as the electrolyte and activated carbon as the electrodes has a high area specific capacitance (113.76 mF/cm2) and good cycling stability (capacitance retention of 81.62 % after 1,000 charging and discharging cycles) at room temperature.
Keyword :
Hofmeister effect Hofmeister effect One-pot preparation One-pot preparation Poly(vinyl alcohol) Poly(vinyl alcohol) Soy protein isolate Soy protein isolate Strain sensor Strain sensor
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GB/T 7714 | Hu, Mingqiang , Deng, Yingxue , Qian, Xing et al. One-pot preparation of strong, tough, frost-resistant and recyclable organohydrogels via Hofmeister effect and its application for electronic devices [J]. | EUROPEAN POLYMER JOURNAL , 2024 , 221 . |
MLA | Hu, Mingqiang et al. "One-pot preparation of strong, tough, frost-resistant and recyclable organohydrogels via Hofmeister effect and its application for electronic devices" . | EUROPEAN POLYMER JOURNAL 221 (2024) . |
APA | Hu, Mingqiang , Deng, Yingxue , Qian, Xing , Ye, Dezhan , Jiang, Xiancai , Xiao, Gao . One-pot preparation of strong, tough, frost-resistant and recyclable organohydrogels via Hofmeister effect and its application for electronic devices . | EUROPEAN POLYMER JOURNAL , 2024 , 221 . |
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