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氧化铜矿硫化浮选技术与机理及强化措施研究进展
期刊论文 | 2025 , 41 (2) , 1-4,22 | 现代矿业
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Abstract :

为了解氧化铜矿硫化浮选的技术应用与硫化机理研究现状,针对如何强化氧化铜矿硫化浮选回收效果,从氧化铜矿的硫化方式、硫化作用机理、硫化影响因素等方面展开了综述,总结分析了氧化铜矿浮选药剂强化硫化浮选的措施与机制.针对如何精准调控氧化铜矿分段硫化浮选生产过程中存在的问题,提出应对分段硫化过程中矿物表面硫化相的微观与定量生长机制进行深入研究,并结合矿石分选实践,建立氧化铜矿分段硫化浮选的大数据库,为基因矿物加工工程在氧化铜矿硫化浮选方面研究提供数据参考.

Keyword :

分段硫化 分段硫化 强化硫化 强化硫化 氧化铜矿 氧化铜矿 硫化机理 硫化机理 硫化浮选 硫化浮选

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GB/T 7714 马英强 , 黄鑫 , 宋振国 et al. 氧化铜矿硫化浮选技术与机理及强化措施研究进展 [J]. | 现代矿业 , 2025 , 41 (2) : 1-4,22 .
MLA 马英强 et al. "氧化铜矿硫化浮选技术与机理及强化措施研究进展" . | 现代矿业 41 . 2 (2025) : 1-4,22 .
APA 马英强 , 黄鑫 , 宋振国 , 汪子涵 . 氧化铜矿硫化浮选技术与机理及强化措施研究进展 . | 现代矿业 , 2025 , 41 (2) , 1-4,22 .
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典型阴阳离子与晶质结构性差异菱镁矿在浮选体系下的相互作用 CSCD PKU
期刊论文 | 2024 , 34 (06) , 2084-2098 | 中国有色金属学报
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Abstract :

自然界中的菱镁矿主要以显晶质和隐晶质两种结构存在,晶质结构的差异导致矿物在浮选过程中表现出不同的表面性质,如溶解度和亲疏水性等。在浮选过程中,常用的阴阳离子调整剂会促使两种晶质结构菱镁矿与捕收剂之间产生不同的相互作用,然而对于两种晶质结构的具体影响机理尚不明确。本文以显晶质和隐晶质结构差异作为区分,在十二胺阳离子捕收剂和油酸钠阴离子捕收剂作用下,研究了Fe~(3+)、Ca~(2+)、SiO_3~(2-)和CO_3~(2-)等阴阳离子对于两种晶质菱镁矿的可浮性影响。结果表明:在十二胺体系中,Fe~(3+)对矿物具有明显的抑制作用,显晶质和隐晶质菱镁矿的回收率分别降低70%和10%,Ca~(2+)、SiO_3~(2-)和CO_3~(2-)则产生了一定的活化作用,其中CO_3~(2-)的作用最强,两种晶质菱镁矿的回收率分别提高70%和40%。在油酸钠体系中,Fe~(3+)、Ca~(2+)对矿物的浮选具有抑制作用,Fe~(3+)作用时,两种矿物的回收率分别下降55%和20%;而SiO_3~(2-)和CO_3~(2-)对矿物的浮选则产生了活化作用,在CO_3~(2-)作用下显晶质和隐晶质菱镁矿的回收率分别提高10%和25%。在两种晶质结构菱镁矿的浮选体系中,CO_3~(2-)的加入会促进捕收剂在矿物表面的吸附,从而提高矿物的回收率,Fe~(3+)的加入则会在矿浆中形成亲水性的羟基铁配合物质,并罩盖于颗粒表面,降低矿物可浮性。隐晶质菱镁矿在矿浆中的溶解也会提高矿浆黏度,因此相较于显晶质菱镁矿,其受到的抑制作用相对较弱。在阴阳离子作用下,菱镁矿的浮选特性与其不同的晶质结构有着非常重要的联系。

Keyword :

可浮性 可浮性 显晶质 显晶质 浮选机理 浮选机理 菱镁矿 菱镁矿 隐晶质 隐晶质

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GB/T 7714 赵伟渲 , 马英强 , 孟迪 et al. 典型阴阳离子与晶质结构性差异菱镁矿在浮选体系下的相互作用 [J]. | 中国有色金属学报 , 2024 , 34 (06) : 2084-2098 .
MLA 赵伟渲 et al. "典型阴阳离子与晶质结构性差异菱镁矿在浮选体系下的相互作用" . | 中国有色金属学报 34 . 06 (2024) : 2084-2098 .
APA 赵伟渲 , 马英强 , 孟迪 , 胡文吉豪 . 典型阴阳离子与晶质结构性差异菱镁矿在浮选体系下的相互作用 . | 中国有色金属学报 , 2024 , 34 (06) , 2084-2098 .
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典型阴阳离子与晶质结构性差异菱镁矿在浮选体系下的相互作用 CSCD PKU
期刊论文 | 2024 , 34 (6) , 2084-2098 | 中国有色金属学报
Selective depression of phenoxyacetyl chloride on magnesite: Implications for effective flotation separation of magnesite from dolomite SCIE
期刊论文 | 2024 , 218 | MINERALS ENGINEERING
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Abstract :

In order to improve the flotation separation of magnesite from dolomite effectively, the organic regulator, phenoxyacetyl chloride (POC), was first introduced as a selective depressant of magnesite, with dodecylamine (DDA) as the collector. The results of single mineral flotation showed that POC could selectively inhibit magnesite but hardly affect dolomite. The results of reverse flotation of a synthetic mixture of magnesite and dolomite were basically consistent with those of single mineral flotation. With DDA as the collector and POC as the depressant, dolomite floated selectively against magnesite. Magnesite and dolomite could be efficiently separated at pH 8.00 with a reagent scheme of 0.50 mg/mL POC and 30.00 mg/L DDA. When the mixed ore for the synthetic mineral, grading 42.60 % MgO and 2.84 % CaO, a magnesite concentrate with 46.85 % MgO and 0.45 % CaO was achieved. Contact angle, Zeta potential, Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and DFT analyses showed that POC selectively adsorbed on the surface of magnesite, by chelating Mg on the surface of magnesite. The results from the contact angle tests indicated that POC selectively reduced the surface hydrophobicity of magnesite in the DDA system. Besides, Zeta-potential measurements and FTIR analyses revealed that the addition of POC prior to DDA had no significant impact on the adsorption of DDA onto dolomite; the addition of POC strongly prevented DDA from being adsorbed onto magnesite, resulting in a significant difference in the flotation performances of the two minerals. Furthermore, XPS analyses and DFT calculations confirmed that the adsorption of POC on the magnesite surface could be attributed to the interaction between the POC electron-rich groups and the Mg exposed to magnesite, POC could be used as a high-performance inhibitor for the magnesite flotation to realize the decalcificationic. Based on these experimental results, a possible model for the flotation separation process of magnesite has been proposed.

Keyword :

Dolomite Dolomite Magnesite Magnesite Phenoxyacetyl chloride Phenoxyacetyl chloride Reverse flotation Reverse flotation Selective depression Selective depression

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GB/T 7714 Cheng, Guibin , Ma, Yingqiang , Lopez-Valdivieso, Alejandro et al. Selective depression of phenoxyacetyl chloride on magnesite: Implications for effective flotation separation of magnesite from dolomite [J]. | MINERALS ENGINEERING , 2024 , 218 .
MLA Cheng, Guibin et al. "Selective depression of phenoxyacetyl chloride on magnesite: Implications for effective flotation separation of magnesite from dolomite" . | MINERALS ENGINEERING 218 (2024) .
APA Cheng, Guibin , Ma, Yingqiang , Lopez-Valdivieso, Alejandro , Yin, Wanzhong . Selective depression of phenoxyacetyl chloride on magnesite: Implications for effective flotation separation of magnesite from dolomite . | MINERALS ENGINEERING , 2024 , 218 .
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Selective depression of phenoxyacetyl chloride on magnesite: Implications for effective flotation separation of magnesite from dolomite EI
期刊论文 | 2024 , 218 | Minerals Engineering
Selective depression of phenoxyacetyl chloride on magnesite: Implications for effective flotation separation of magnesite from dolomite Scopus
期刊论文 | 2024 , 218 | Minerals Engineering
山东某金矿浮选尾矿工艺矿物学
期刊论文 | 2024 , 45 (5) , 71-75 | 矿产综合利用
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这是一篇工艺矿物学领域的论文.山东某金矿石含金 2.0 g/t,含硫 1.56%,属于典型低硫含金矿石.选厂采用浮选工艺回收金,金的回收率为 90%,尾矿金品位 0.17 g/t.为进一步降低尾矿中金的流失,提高浮选指标,采用MLA结合传统工艺矿物学手段查明金的流失原因.研究表明:主要的金属矿物为磁黄铁矿和黄铁矿,脉石矿物主要为长石和石英;脉石连生金及脉石包裹金占 77.29%,粒度主要分布在-0.01 mm,这部分采用浮选工艺很难回收;金属硫化物连生金、金属硫化物包裹金及单体金占 22.71%,流失不合理.基于尾矿工艺矿物学分析,下一步应该重点研究磨矿分级,降低有用矿物过磨程度,达到提高浮选指标的目的.

Keyword :

MLA MLA 工艺矿物学 工艺矿物学 浮选 浮选 金尾矿 金尾矿

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GB/T 7714 吴凯 , 马英强 , 王海龙 et al. 山东某金矿浮选尾矿工艺矿物学 [J]. | 矿产综合利用 , 2024 , 45 (5) : 71-75 .
MLA 吴凯 et al. "山东某金矿浮选尾矿工艺矿物学" . | 矿产综合利用 45 . 5 (2024) : 71-75 .
APA 吴凯 , 马英强 , 王海龙 , 董鸿良 , 任瑞辉 , 王淑新 . 山东某金矿浮选尾矿工艺矿物学 . | 矿产综合利用 , 2024 , 45 (5) , 71-75 .
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Study on the Process Mineralogy for the Flotation Tailings of a Gold Mine in Shandong Province; [山东某金矿浮选尾矿工艺矿物学] Scopus
期刊论文 | 2024 , 45 (5) , 71-75 | Multipurpose Utilization of Mineral Resources
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Abstract :

This is anarticle in the field of process mineralogy. The grade of gold and sulfur in a gold mine from Shandong Province was 2.0 g/t and 1.56% respectively, which was a typical gold bearing ore with low sulfur. There covery of gold was made by flotation process in dressing mill, the gold recovery rate was 90%, the gold grade of tailings was 0.17 g/t. To reduce the loss of gold, and improve the flotation performance, MLA(Mineral Liberation Analyser)combined with frequently used process mineralogy method was used to ascertain the reasons for the loss of gold. The study show edpyrrhotite and pyritewere main metal licminerals, feldspar and quartz were a primary gangue miner. The gold locked to gangue and gold included with gangue accounted for 77.29%, of which the size distribution was below 0.01 mm, were difficult to recovered by flotation process. The gold locked or included by metal sulfides and monomer gold accounted for 22.71%, were unreasonable loss. Based on the analysis of process mineralogy of tailings:grinding and classification were the key to further work, which aimed to reduce degree of over grinding of useful minerals, achieve the improvement of beneficiation results. © 2024 Editorial Department of Multipurpose Utilization of Mineral Resources. All rights reserved.

Keyword :

Flotation Flotation Gold tailings Gold tailings MLA MLA Process mineralogy Process mineralogy

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GB/T 7714 Wu, K. , Ma, Y. , Wang, H. et al. Study on the Process Mineralogy for the Flotation Tailings of a Gold Mine in Shandong Province; [山东某金矿浮选尾矿工艺矿物学] [J]. | Multipurpose Utilization of Mineral Resources , 2024 , 45 (5) : 71-75 .
MLA Wu, K. et al. "Study on the Process Mineralogy for the Flotation Tailings of a Gold Mine in Shandong Province; [山东某金矿浮选尾矿工艺矿物学]" . | Multipurpose Utilization of Mineral Resources 45 . 5 (2024) : 71-75 .
APA Wu, K. , Ma, Y. , Wang, H. , Dong, H. , Ren, R. , Wang, S. . Study on the Process Mineralogy for the Flotation Tailings of a Gold Mine in Shandong Province; [山东某金矿浮选尾矿工艺矿物学] . | Multipurpose Utilization of Mineral Resources , 2024 , 45 (5) , 71-75 .
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某卡林型金矿选矿试验研究
期刊论文 | 2024 , (04) , 85-90 | 有色金属(选矿部分)
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某金矿石金品位为3.20 g/t,是主要的回收元素,其中伴生锑可作为综合回收对象。矿石中金的化学物相分析结果表明,矿石中金主要被硫化物包裹,占80.51%,其次被氧化物包裹,占11.58%,单体金和连生金较少,只占4.24%。矿石中主要矿物为石英和方解石、铁白云石,其次为绢云母、长石、黄铁矿及高岭石、伊利石等黏土矿物,此外还含有少量金红石、榍石、毒砂、磷灰石等矿物。针对矿石性质,在原有工艺流程和药剂制度的基础上,开展了浮选条件试验,获得的最佳工艺参数为:磨矿细度-0.074 mm占84.6%、碳酸钠用量为2 000 g/t、硫酸铜用量为200 g/t、硝酸铅用量为150 g/t、丁基黄药用量为150 g/t。当磨矿细度为-0.074 mm占84.6%时,采用最佳药剂制度,通过一粗三精二扫、中矿循序返回工艺流程,获得精矿金品位46.14%、金回收率90.91%,尾矿金品位为0.29 g/t。对尾矿进行镜下鉴定,工艺矿物学分析结果表明,尾矿中流失的金主要是硅酸盐包裹金、单体及连生体金,尤其是硅酸盐包裹的金未能回收。对浮选尾矿进行粒度组成和金的分布研究,结果表明,+0.044 mm粒级产率为30.38%,金的分布率为30.90%,可探讨采用重选工艺回收的可能;-0.025 mm粒级的产率为58.45%,金的分布率为60.07%,粒度过细,很难通过浮选的方法回收。试验结果为该金矿的浮选回收奠定基础,对选矿生产具有指导意义。

Keyword :

卡林型金矿 卡林型金矿 含锑 含锑 浮选 浮选 金物相 金物相

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GB/T 7714 吴凯 , 米文杰 , 窦源东 et al. 某卡林型金矿选矿试验研究 [J]. | 有色金属(选矿部分) , 2024 , (04) : 85-90 .
MLA 吴凯 et al. "某卡林型金矿选矿试验研究" . | 有色金属(选矿部分) 04 (2024) : 85-90 .
APA 吴凯 , 米文杰 , 窦源东 , 邢丹 , 马英强 . 某卡林型金矿选矿试验研究 . | 有色金属(选矿部分) , 2024 , (04) , 85-90 .
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某卡林型金矿选矿试验研究
期刊论文 | 2024 , (4) , 85-90 | 有色金属(选矿部分)
福建某含铜锌高硫多金属金矿石低碱浮选工艺研究
期刊论文 | 2024 , 45 (11) , 94-98 | 黄金
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福建某含铜锌高硫多金属金矿石金品位4.45 g/t、银品位60.10 g/t、铜品位0.47%、锌品位2.96%、含硫8.56%.为提高资源利用率,在原矿工艺矿物学基础上进行浮选试验研究,加入HS-1和HZ-1作为黄铁矿与闪锌矿的选择性抑制剂,减少石灰用量,实现低碱条件下铜、锌、硫分离.试验结果表明:金主要富集在高铜金精矿与含锌金精矿中,高铜金精矿金品位35.47 g/t、银品位614.17 g/t、铜品位5.69%;含锌金精矿金品位14.36 g/t、锌品位16.07%;金、银、铜、锌4种金属的总回收率分别达到91.39%、83.95%、87.11%和76.38%,资源得到充分利用,有效提高了企业经济效益.

Keyword :

低碱 低碱 多金属 多金属 浮选 浮选 选择性抑制剂 选择性抑制剂 金矿 金矿 铜硫分离 铜硫分离

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GB/T 7714 王智聪 , 马英强 , 黄丽亚 et al. 福建某含铜锌高硫多金属金矿石低碱浮选工艺研究 [J]. | 黄金 , 2024 , 45 (11) : 94-98 .
MLA 王智聪 et al. "福建某含铜锌高硫多金属金矿石低碱浮选工艺研究" . | 黄金 45 . 11 (2024) : 94-98 .
APA 王智聪 , 马英强 , 黄丽亚 , 陈波 . 福建某含铜锌高硫多金属金矿石低碱浮选工艺研究 . | 黄金 , 2024 , 45 (11) , 94-98 .
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次氯酸钠强化赤铜矿硫化浮选的影响及机理 PKU
期刊论文 | 2024 , 6 (02) , 157-162 | 金属矿山
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Abstract :

表面适度氧化可以提高赤铜矿硫化浮选的效果。通过纯矿物浮选试验,探究了次氯酸钠对赤铜矿硫化浮选的影响,并采用X射线光电子能谱分析、矿物表面Zeta电位测定等方法,探讨了次氯酸钠强化赤铜矿浮选行为的机理。结果表明:与直接硫化浮选相比,次氯酸钠能使赤铜矿的硫化浮选回收率增加8.95个百分点;次氯酸钠能够促进赤铜矿表面的Cu(Ⅰ)组分转变为Cu(Ⅱ)组分,可以增强铜组分与硫化剂的反应活性,强化赤铜矿的硫化效果,对赤铜矿的硫化浮选具有促进作用。

Keyword :

强化硫化 强化硫化 氧化剂 氧化剂 硫化浮选 硫化浮选 表面吸附 表面吸附 赤铜矿 赤铜矿

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GB/T 7714 马英强 , 于翔州 , 罗进 et al. 次氯酸钠强化赤铜矿硫化浮选的影响及机理 [J]. | 金属矿山 , 2024 , 6 (02) : 157-162 .
MLA 马英强 et al. "次氯酸钠强化赤铜矿硫化浮选的影响及机理" . | 金属矿山 6 . 02 (2024) : 157-162 .
APA 马英强 , 于翔州 , 罗进 , 宋振国 , 印万忠 , 饶峰 . 次氯酸钠强化赤铜矿硫化浮选的影响及机理 . | 金属矿山 , 2024 , 6 (02) , 157-162 .
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甘肃某金矿浮选药剂优化试验研究
期刊论文 | 2024 , (02) , 98-103 | 有色金属(选矿部分)
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Abstract :

某金矿石金品位为3.25 g/t,银、铜等其他金属含量太低,不具备回收价值。矿石中单体金和裸露金含量很低,仅为4.24%;金主要以包裹体嵌布在金属硫化物和氧化物矿物中,约92.09%;其余为硅酸盐包裹金,仅占3.67%。针对该矿石性质,结合现场浮选工艺流程和药剂制度,开展浮选药剂优化条件试验。获得粗选最佳工艺参数:磨矿细度-0.074 mm含量占84.6%、硅酸钠用量为1 600 g/t、硫酸铜用量为200 g/t、丁基黄药用量为100 g/t、丁基铵黑药用量为30 g/t、松醇油用量为100 g/t。当磨矿细度-0.074 mm含量占84.6%时,采用最佳药剂制度,通过一粗二精二扫、中矿循序返回工艺流程,获得精矿金品位47.85 g/t、金回收率91.88%,尾矿品位为0.28 g/t。精矿和尾矿的X荧光半定量分析结果显示,铁、硫、砷、锑等元素含量差别明显,其在精矿中的含量远高于尾矿,说明此浮选工艺对黄铁矿、毒砂、辉锑矿分选效果很好。试验结果对该金矿浮选药剂优化奠定基础,对其选矿生产具有指导意义。

Keyword :

微细嵌布 微细嵌布 浮选 浮选 药剂优化 药剂优化 金矿石 金矿石

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GB/T 7714 吴凯 , 马英强 , 窦源东 et al. 甘肃某金矿浮选药剂优化试验研究 [J]. | 有色金属(选矿部分) , 2024 , (02) : 98-103 .
MLA 吴凯 et al. "甘肃某金矿浮选药剂优化试验研究" . | 有色金属(选矿部分) 02 (2024) : 98-103 .
APA 吴凯 , 马英强 , 窦源东 , 邢丹 . 甘肃某金矿浮选药剂优化试验研究 . | 有色金属(选矿部分) , 2024 , (02) , 98-103 .
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甘肃某金矿浮选药剂优化试验研究
期刊论文 | 2024 , (2) , 98-103 | 有色金属(选矿部分)
Interaction between typical anions/cations and structural differences in crystal structure of magnesite in flotation systems EI CSCD PKU
期刊论文 | 2024 , 34 (6) , 2084-2098 | Chinese Journal of Nonferrous Metals
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Abstract :

Magnesite in nature mainly exists in two structures, crystalline and cryptocrystalline. The difference in crystal structure causes minerals to exhibit different surface properties, such as solubility and hydrophobicity, during the flotation process. In the flotation process, the commonly used anion and cation regulators will promote different interactions between the two crystalline structures magnesite and the collector, but the specific influence mechanism on the two crystal structures is not clear. In this paper, the effects of anions and cations, such as Fe3+, Ca2+ , SiO23- and CO23-, on the floatability of two crystalline magnesites were studied under the action of dodecamine cation collector and sodium oleate anion collector. The results show that Fe3+ has obvious inhibitory effect on minerals in dodecamine system, the recovery rates of crystalline magnesite and cryptocrystalline magnesite decrease by 70% and 10%, respectively. Ca2+, SiO23- and CO23- have certainly activating effects, among which CO23- has the strongest effect, and the recovery rates of two crystalline magnesites increases by 70% and 40%, respectively. In the sodium oleate system, Fe3+ and Ca2+ have inhibitory effects on the flotation of minerals, the recovery rates of the two minerals decreases by 55% and 20%, respectively, when Fe3+ is reacted. Ca2+ and Mg2+ have the activating effect on the surface of minerals, and the recovery rates of crystalline and cryptocrystalline magnesite increase by 10% and 25%, respectively. The different crystalline structures of magnesite affect its flotation characteristics under ionic conditions. The addition of CO23- will promote the adsorption of sodium oleate on the surface of the mineral, thereby improve the recovery rates of the minerals. The addition of Fe3+ will promote the dissolution of magnesite and form a hydration layer on the surface of the particles, hinder the adsorption of collectors on the surface of the particles, thereby reduce the recovery rates of minerals. © 2024 Central South University of Technology. All rights reserved.

Keyword :

Chemical activation Chemical activation Crystal structure Crystal structure Flotation Flotation Magnesite Magnesite Negative ions Negative ions Positive ions Positive ions Sodium Sodium

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GB/T 7714 Zhao, Weixuan , Ma, Yingqiang , Meng, Di et al. Interaction between typical anions/cations and structural differences in crystal structure of magnesite in flotation systems [J]. | Chinese Journal of Nonferrous Metals , 2024 , 34 (6) : 2084-2098 .
MLA Zhao, Weixuan et al. "Interaction between typical anions/cations and structural differences in crystal structure of magnesite in flotation systems" . | Chinese Journal of Nonferrous Metals 34 . 6 (2024) : 2084-2098 .
APA Zhao, Weixuan , Ma, Yingqiang , Meng, Di , Hu, Wenjihao . Interaction between typical anions/cations and structural differences in crystal structure of magnesite in flotation systems . | Chinese Journal of Nonferrous Metals , 2024 , 34 (6) , 2084-2098 .
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Interaction between typical anions/cations and structural differences in crystal structure of magnesite in flotation systems; [典型阴阳离子与晶质结构性差异菱镁矿在浮选体系下的相互作用] Scopus CSCD PKU
期刊论文 | 2024 , 34 (6) , 2084-2098 | Chinese Journal of Nonferrous Metals
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