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学者姓名：邓荣东
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Abstract ：
This paper presents a treatment process for copper smelter dust's chlorinated leaching solution. Addressing the challenge of separating As and valuable metals from this solution, the process utilized SO2 to reduce As(V) to As(III) and NaOH to neutralize Bi(III), resulting in the stepwise formation of As2O3 and BiOCl. The results indicate that, under optimal conditions, the precipitation ratio of As reached 71.23%, and the Bi precipitation ratio reached 98.38%. Following Bi precipitation, two separation strategies were attempted for the recovery of Cu and Zn. The first strategy involves recovery of Cu using a sulfide precipitation method, followed by the recrystallization of ZnSO4. Under optimal conditions, the Cu precipitation ratio can reach 99.81%. The second strategy involves Cu solvent extraction using Lix984N coupled with Zn solvent extraction using P204. Under appropriate conditions, the Cu extraction rate can achieve 98.59%. A comprehensive assessment indicates that using sulfidation - crystallization to separate Cu and Zn is more economical than employing solvent extraction methods. Consequently, the final process is determined as follows: As removal by SO2 reduction > Bi recovery by NaOH neutralization > Cu recovery by sulfidation precipitation > Zn recovery by crystallization.
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| GB/T 7714 | Guo, Zhuzhu , Gao, Chunhui , Wu, Siyuan et al. Removal of As in Copper Smelter Dust's Chlorinated Leaching Solution by SO2 Reduction and the Subsequent Separation of Bi/Cu/Zn [J]. | JOM , 2025 , 77 (5) : 3409-3417 . |
| MLA | Guo, Zhuzhu et al. "Removal of As in Copper Smelter Dust's Chlorinated Leaching Solution by SO2 Reduction and the Subsequent Separation of Bi/Cu/Zn" . | JOM 77 . 5 (2025) : 3409-3417 . |
| APA | Guo, Zhuzhu , Gao, Chunhui , Wu, Siyuan , Guo, Bao , Deng, Rongdong , Jiang, Kaixi . Removal of As in Copper Smelter Dust's Chlorinated Leaching Solution by SO2 Reduction and the Subsequent Separation of Bi/Cu/Zn . | JOM , 2025 , 77 (5) , 3409-3417 . |
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针对辉钼矿在浮选矿浆中易团聚并包裹黄铜矿,导致铜钼浮选分离困难的问题,通过光学显微镜和聚焦光束反射测量仪研究了超声波分散、机械搅拌和添加分散剂六偏磷酸钠3种方式对辉钼矿分散行为的影响;采用红外光谱、扫描电子显微镜、Zeta电位并结合浮选溶液化学技术对分散机理进行了研究。结果表明,3种分散方式都可起到分散辉钼矿团聚体的作用,其中以添加六偏磷酸钠的效果最好;加入400 mg/L六偏磷酸钠,不但能够有效降低辉钼矿团聚体的尺寸、减少其数量,还能降低辉钼矿团聚体内黄铜矿含量,使人工混合矿浮选钼精矿的铜含量由3.86%降低至2.73%;六偏磷酸钠在辉钼矿表面吸附并产生空间位阻排斥力,电离出的阴离子增大了颗粒间的静电斥力,致使辉钼矿表现出较好的分散行为。
Keyword ：
六偏磷酸钠 六偏磷酸钠 分散方式 分散方式 团聚体 团聚体 浮选 浮选 铜钼分离 铜钼分离
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| GB/T 7714 | 肖世洁 , 邓荣东 , 代旺 et al. 铜钼分离过程中辉钼矿的多方式分散效果研究 [J]. | 金属矿山 , 2024 , PageCount-页数: 8 (05) : 250-257 . |
| MLA | 肖世洁 et al. "铜钼分离过程中辉钼矿的多方式分散效果研究" . | 金属矿山 PageCount-页数: 8 . 05 (2024) : 250-257 . |
| APA | 肖世洁 , 邓荣东 , 代旺 , 赵睿祺 , 吴思远 , 郭宝 . 铜钼分离过程中辉钼矿的多方式分散效果研究 . | 金属矿山 , 2024 , PageCount-页数: 8 (05) , 250-257 . |
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在处理含细泥、高硅有色金属矿物时，常出现沉降速率慢、固液分离难等问题，不利于后续的萃取-电积过程，从而影响生产的正常运转。为解决酸浸矿浆中除硅难的问题，本工作以-2000目(6.5μm)高岭土为原料，探究了细粒高岭土在酸性体系下的絮凝沉降行为。结果表明，聚丙烯酰胺(PAM)对高岭土的絮凝性能强于聚乙二醇(PEO)。助凝剂聚苯乙烯磺酸钠(PSS)可以进一步提高絮凝效果，PAM和PEO与100 g/t PSS配合使用时絮凝作用最佳；而单宁酸(TA)的助凝效果不明显；利用聚焦光束反射测量(FBRM)发现，絮凝过程中产生絮团的大小与用药量呈正相关，但絮团越大，抗剪切能力越弱，且絮团的破坏过程是不可逆的；Zeta电位表明，PSS能够有效降低其表面电位，这是高岭土能够在酸性体系下絮凝的主要机理。
Keyword ：
助凝剂 助凝剂 絮凝沉降 絮凝沉降 酸性体系 酸性体系 高岭土 高岭土
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| GB/T 7714 | 俞新煌 , 李世淇 , 展鑫磊 et al. 酸性体系下高岭土的絮凝沉降行为 [J]. | 过程工程学报 , 2024 , 24 (08) : 993-1000 . |
| MLA | 俞新煌 et al. "酸性体系下高岭土的絮凝沉降行为" . | 过程工程学报 24 . 08 (2024) : 993-1000 . |
| APA | 俞新煌 , 李世淇 , 展鑫磊 , 郭宝 , 邓荣东 , 蒋开喜 et al. 酸性体系下高岭土的絮凝沉降行为 . | 过程工程学报 , 2024 , 24 (08) , 993-1000 . |
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我国铅锌浮选尾矿堆存量大，综合利用率低，存在环境污染风险与安全隐患。为推动铅锌尾矿开发利用的技术进步与实践生产，本文系统梳理我国铅锌尾矿资源化利用的研究进展，概述尾矿再选利用与尾矿再加工利用制备水泥、砖、微晶玻璃和胶凝材料等综合利用方法和途径，并重点比较两种方法的优缺点，尾矿再选利用可对其中有价金属提取富集，但成本较高且工艺复杂，且再选后仍存在大量尾矿。而铅锌尾矿中含有硅(Si)、钙(Ca)、铝(Al)和铁(Fe)等氧化矿物可替代黏土、页岩和水泥等原材料通过再加工制备高附加产值的材料，可实现对铅锌尾矿的大量消纳且成本低廉。提出建议提前做好矿区尾矿经济价值评价，以加强对铅锌尾矿的绿色再加工利用，以期实现对矿山尾矿的资源化、无害化和减量化利用。
Keyword ：
再选 再选 减量化 减量化 综合利用 综合利用 资源化 资源化 铅锌尾矿 铅锌尾矿
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| GB/T 7714 | 李鑫 , 王锦荣 , 邓荣东 et al. 我国铅锌尾矿综合利用研究现状及其开发利用意义 [J]. | 地质与勘探 , 2024 , 60 (04) : 724-734 . |
| MLA | 李鑫 et al. "我国铅锌尾矿综合利用研究现状及其开发利用意义" . | 地质与勘探 60 . 04 (2024) : 724-734 . |
| APA | 李鑫 , 王锦荣 , 邓荣东 , 幸鼎权 , 陈钦 . 我国铅锌尾矿综合利用研究现状及其开发利用意义 . | 地质与勘探 , 2024 , 60 (04) , 724-734 . |
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某矿山钼精选尾矿含铜0.526%,铜主要以黄铜矿形式存在，具有综合回收利用价值。尾矿中其它矿物主要为石英、绿泥石和黄铁矿。尾矿粒度极细，且黄铁矿含量高，铜硫分离困难。采用单因素条件试验系统研究了浮选工艺参数条件和药剂制度对铜精矿铜品位和铜回收率的影响，进一步优化工艺参数条件，并分别开展了开路和闭路浮选试验。结果表明，最佳浮选工艺参数条件和药剂用量分别为：矿浆浓度30%、水玻璃用量1 000 g/t、石灰用量500 g/t、硫酸铜用量300 g/t、丁基黄药50 g/t、充气量0.2 m~3/h;采用一次粗选、三次精选、三次扫选(一粗三精三扫)的浮选工艺流程，最终可获得铜品位24.18%、铜回收率85.65%的铜精矿，综合浮选指标较佳，可实现钼精选尾矿中有价金属铜的高效回收。
Keyword ：
尾矿 尾矿 浮选 浮选 钼 钼 钼精选 钼精选 铜回收 铜回收 铜精矿 铜精矿
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| GB/T 7714 | 车文芳 , 杨剑波 , 代旺 et al. 钼精选尾矿浮选回收铜 [J]. | 矿冶 , 2024 , 33 (02) : 210-216,224 . |
| MLA | 车文芳 et al. "钼精选尾矿浮选回收铜" . | 矿冶 33 . 02 (2024) : 210-216,224 . |
| APA | 车文芳 , 杨剑波 , 代旺 , 邓荣东 . 钼精选尾矿浮选回收铜 . | 矿冶 , 2024 , 33 (02) , 210-216,224 . |
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Lead-zinc tailings in China have large stockpiles and a low comprehensive utilization ratio, which have brought potential environmental pollution risks and safety hazards. This work aims to promote the technology progress and practical production of the development and utilization of lead and zinc tailings. The research progress of resource utilization for lead and zinc tailings was systematically analyzed, and the tailings reselection and tailings reprocessing and utilization to prepare cement, bricks, glass-ceramics, and filling materials were overviewed. The advantages and disadvantages of tailing reselection were compared with those of tailing reprocessing and utilization. Tailings reselection and utilization can extract valuable metals, but with high cost and complicated process, and a large amount of tailings still exist after reselection. In contrast, the lead and zinc tailings themselves contain silicon (Si), calcium (Ca), aluminum (Al) and iron (Fe) and other oxidized minerals, and these oxidized minerals can replace clay, shale and cement and other raw materials through reprocess to prepare high-value-added materials, which can achieve a large number of lead and zinc tailings consumption and low cost. It is proposed that the economic value of mine tailings should be evaluated in advance and the green reprocessing and utilization of lead and zinc tailings should be strengthened to achieve tailings recycling, reuse, and reduction. © 2024 Editorial Board of Geology and Exploration. All rights reserved.
Keyword ：
comprehensive utilization comprehensive utilization lead-zinc tailings lead-zinc tailings recycling recycling reduction reduction reselection reselection
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| GB/T 7714 | Li, X. , Wang, J. , Deng, R. et al. Research Status and Significance of Comprehensive Utilization of Lead-Zinc Tailings in China; [我国铅锌尾矿综合利用研究现状及其开发利用意义] [J]. | Geology and Exploration , 2024 , 60 (4) : 724-734 . |
| MLA | Li, X. et al. "Research Status and Significance of Comprehensive Utilization of Lead-Zinc Tailings in China; [我国铅锌尾矿综合利用研究现状及其开发利用意义]" . | Geology and Exploration 60 . 4 (2024) : 724-734 . |
| APA | Li, X. , Wang, J. , Deng, R. , Xing, D. , Chen, Q. . Research Status and Significance of Comprehensive Utilization of Lead-Zinc Tailings in China; [我国铅锌尾矿综合利用研究现状及其开发利用意义] . | Geology and Exploration , 2024 , 60 (4) , 724-734 . |
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Arsenic contamination significantly affects the quality of copper concentrates, presenting challenges during smelting processes. Considering that covellite and enargite have similar surface properties, they are difficult to separate by flotation, resulting in copper concentrates with excessive levels of arsenic. To address this issue, this study systematically investigated the flotation separation of covellite and enargite in microflotation and bench-scale flotation tests using calcium lignosulfonate as a depressant, with the results indicating that calcium lignosulfonate can be used to separate covellite and enargite because it enables the separation of arsenic-bearing copper minerals into high- and low-arsenic (As 0.57%) copper concentrates. According to contact angle and adsorption tests, scanning electron microscopy-energy dispersive spectroscopy, and X-ray photoelectron spectroscopy, the differential adsorption of calcium lignosulfonate onto covellite and enargite is the primary reason for their distinct flotation behaviors in the presence of calcium lignosulfonate. The selective depressive effect of calcium lignosulfonate provides a novel approach for improving the flotation separation of arsenic-bearing minerals from copper sulfide minerals.
Keyword ：
Calcium lignosulfonate Calcium lignosulfonate Covellite Covellite Enargite Enargite Flotation Flotation Separation Separation
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| GB/T 7714 | Lin, Rongping , Liu, Quanjun , Deng, Rongdong . Calcium Lignosulfonate as a Depressant for Enhancing Flotation Separation of Covellite and Enargite [J]. | MINING METALLURGY & EXPLORATION , 2024 , 41 (2) : 1135-1144 . |
| MLA | Lin, Rongping et al. "Calcium Lignosulfonate as a Depressant for Enhancing Flotation Separation of Covellite and Enargite" . | MINING METALLURGY & EXPLORATION 41 . 2 (2024) : 1135-1144 . |
| APA | Lin, Rongping , Liu, Quanjun , Deng, Rongdong . Calcium Lignosulfonate as a Depressant for Enhancing Flotation Separation of Covellite and Enargite . | MINING METALLURGY & EXPLORATION , 2024 , 41 (2) , 1135-1144 . |
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Pb2+ plays a modifying role in the flotation behavior of various sulfide and oxide minerals. However, there is currently no consensus on the use of lead salts as modifiers in mineral flotation. Based on previous research, this article provides a comprehensive review of the activation effect of Pb2+ on common oxide and sulfide minerals flotation from the perspective of interfacial reactions. A theoretical model for Pb2+ activation has been proposed in this article. When the pH is less than 7, Pb2+ replaces the metal atoms in the lattice of sulfide minerals or adsorbs on the mineral surface to form PbS. When pH is in the range of 7 similar to 10, chemical adsorption of Pb(OH)+ occurs on the mineral surface, leading to the formation of Me-O-Pb+. When pH = 10 similar to 11, Pb(OH)(2) precipitates on the mineral surface. Under this condition, it activates the flotation of quartz but inhibits the flotation of sulfide minerals.
Keyword ：
Activation Activation Lead ion Lead ion Mineral flotation Mineral flotation Reaction mechanism Reaction mechanism
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| GB/T 7714 | Miao, Yu , Ding, Xuemin , Min, Jiarui et al. A Review on the Activation Effect of Lead Ions in Mineral Flotation [J]. | MINING METALLURGY & EXPLORATION , 2024 , 41 (3) : 1477-1483 . |
| MLA | Miao, Yu et al. "A Review on the Activation Effect of Lead Ions in Mineral Flotation" . | MINING METALLURGY & EXPLORATION 41 . 3 (2024) : 1477-1483 . |
| APA | Miao, Yu , Ding, Xuemin , Min, Jiarui , Deng, Rongdong , Guo, Bao , Yu, Chun . A Review on the Activation Effect of Lead Ions in Mineral Flotation . | MINING METALLURGY & EXPLORATION , 2024 , 41 (3) , 1477-1483 . |
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Flotation is a potential method for extracting residual copper sulfide (CuS) from the acid-leaching residue of copper smelting dust; however, the inhibitory impact of Bi(III) in the flotation pulp significantly hampers its practical application. In this study, we systematically investigated the inhibition mechanism of Bi(III) on CuS flotation and propose a method to prevent inhibition. Microflotation test results show that a pulp environment with pH 3 and a Bi(III) concentration greater than 1 x 10-2 mol/L significantly depresses the floatability of CuS. Scanning electron microscopy and energy-dispersive spectroscopy results confirmed that Bi(III) hydrolyzes on the surface of CuS to form a precipitate cover layer, which adsorbs onto the surface of CuS. This precipitate was confirmed by X-ray photoelectron spectroscopy analysis and thermodynamic calculations to be BiOCl. Fourier transform infrared analysis revealed that BiOCl reduces the recovery of CuS by hindering the adsorption of xanthate. Finally, the pre-treatment of the leaching residue with H2SO4 + NaCl solution can dissolve BiOCl precipitates on the surface of CuS, eliminate the influence of Bi(III), and result in efficient flotation recovery of CuS from leaching residue.
Keyword ：
Bi(III) Bi(III) Copper smelting dust Copper smelting dust Copper sulfide Copper sulfide Flotation Flotation Leaching residue Leaching residue
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| GB/T 7714 | Wu, Siyuan , Gao, Chunhui , Chen, Hang et al. Effect of Bi(III) on flotation of copper sulfide from leaching residue of copper smelting dust [J]. | MINERALS ENGINEERING , 2024 , 220 . |
| MLA | Wu, Siyuan et al. "Effect of Bi(III) on flotation of copper sulfide from leaching residue of copper smelting dust" . | MINERALS ENGINEERING 220 (2024) . |
| APA | Wu, Siyuan , Gao, Chunhui , Chen, Hang , Wu, Tuoxiu , Guo, Bao , Deng, Rongdong et al. Effect of Bi(III) on flotation of copper sulfide from leaching residue of copper smelting dust . | MINERALS ENGINEERING , 2024 , 220 . |
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思想政治教育要贯穿到高校教育教学的全过程,成为课程教育不可缺少的重要组成部分.探讨思政课程和课程思政的含义,回溯历史上思想道德教育转变为当代思想政治教育的过程,从工科专业角度认识课程思政与专业教学的辩证关系,思考专业教学中可挖掘提取的多种思政元素,并阐述课程教学环境下思政内容创新教学改革模式、切实提高教学质量的相关探索,以及工科专业课程与思政的融合和统一,提出了开展工科课程思政教育的若干建议,以期为工科课程思政教学改革提供借鉴与参考.
Keyword ：
工科 工科 思想政治 思想政治 教学 教学
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| GB/T 7714 | 晏全香 , 库建刚 , 邓荣东 . 工科专业课程思政的自由探索 [J]. | 教育教学论坛 , 2023 , (19) : 169-172 . |
| MLA | 晏全香 et al. "工科专业课程思政的自由探索" . | 教育教学论坛 19 (2023) : 169-172 . |
| APA | 晏全香 , 库建刚 , 邓荣东 . 工科专业课程思政的自由探索 . | 教育教学论坛 , 2023 , (19) , 169-172 . |
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