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学者姓名:郭进
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Explosion venting technology is an effective means of reducing explosive hazards, and hydrogen volume fraction (chi) is one of the important parameters affecting its effectiveness. The vent covers, as a key part of the explosion venting application, consist of two types: inertia-free (e.g., membranes) and inertial (e.g., panels). chi has been extensively studied using inertial-free vent covers, but very limited work has been done using an inertial vent cover. Hence, the effects of chi, ranging from 0 to 1.0, on the vented H-2/CH4/air explosion were studied in a chamber with a hinged aluminum panel, and the explosion overpressure during venting was simulated by FLACS software. The results show that the flame bubble becomes larger and brighter with increasing chi. However, the time for the flame to travel through the vent (t(out)) and the opening angle of the hinged panel at the time of t(out) constantly decreases as chi increases from 0 to 1.0. In the tests with chi <= 0.6, p(3) caused by acoustically enhanced combustion becomes the pressure peak with the highest amplitude in the internal pressure profile, but the pressure peak p(2) induced by the external explosion dominates the internal pressure trace for chi > 0.6. In comparison to the H-2/CH4/air deflagration experiments using an inertialess vent cover, the shape of the external fireball is quite similar for smaller chi in the current study with an inertial vent panel. However, the use of the inertial vent panel results in a more flattened external fireball for larger chi. The highest amplitude of the external pressure peak (p(ext)) and the maximum reduced overpressure (p(red)) increase with increasing chi. Whether the studies are performed with inertial and inertialess vent covers or FLACS simulations, the formation time (Delta t) of p(ext )decreases linearly with increasing chi, but p(red) increases linearly with S-2(l). The explosion overpressure simulated by FLACS is relatively close to the experimental results, and in particular, the simulated p(red) agrees very well with the experimental value.
Keyword :
Flame propagation Flame propagation H-2/CH4/Air explosion H-2/CH4/Air explosion Hinged vent panel Hinged vent panel Hydrogen volume fraction Hydrogen volume fraction Overpressure Overpressure
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GB/T 7714 | Huang, Shikai , Guo, Jin , Mei, Liang et al. Experiments on vented H2/CH4/air explosion in a chamber with a hinged panel: Effects of hydrogen volume fraction [J]. | JOURNAL OF LOSS PREVENTION IN THE PROCESS INDUSTRIES , 2025 , 94 . |
MLA | Huang, Shikai et al. "Experiments on vented H2/CH4/air explosion in a chamber with a hinged panel: Effects of hydrogen volume fraction" . | JOURNAL OF LOSS PREVENTION IN THE PROCESS INDUSTRIES 94 (2025) . |
APA | Huang, Shikai , Guo, Jin , Mei, Liang , Wang, Fang , Wang, Changjian , Lin, Jin . Experiments on vented H2/CH4/air explosion in a chamber with a hinged panel: Effects of hydrogen volume fraction . | JOURNAL OF LOSS PREVENTION IN THE PROCESS INDUSTRIES , 2025 , 94 . |
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为了氢气‑甲烷混合燃料的安全使用,利用内径和长度皆为300 mm的圆柱形密闭容器进行爆炸实验,研究了掺氢比(XH2=0~100%)和当量比(Φ=0.6~1.4)对火焰演化和爆炸压力特性的影响,并采用CHEMKIN软件分析了氢气‑甲烷‑空气预混气体的层流燃烧速度及其敏感性。结果表明,在当量比(Φ)不变的情况下,随着掺氢比(XH2)的增加,最大爆炸压力(pmax)、最大压力上升速率((dp/dt)max)、爆炸指数(KG)以及层流燃烧速度增大,到达最大压力和最大压力上升速率的时间(tA和tB)逐渐缩短。点火后,火焰表面由最初的较为光滑,逐步形成蜂窝状的火焰胞格结构。在相同当量比(Φ)下,随着掺氢比(XH2)的增加,从点火到爆炸结束的时间大幅缩短,且在同一时刻,火焰半径增大,火焰表面皱褶增多。反应敏感性计算结果表明,基元反应H+O2⇌O+OH(R38)和H+CH3(+M)⇌CH4(+M)(R52)对层流燃烧速度的影响最大;关键自由基(H·、O·、OH·)的最大摩尔分数与层流燃烧速度正相关,且掺氢比(XH2)的增加,使得关键自由基的最大摩尔分数显著增大;基元反应R38和R84是影响关键自由基生成速率(ROP)的最主要反应。
Keyword :
化学动力学分析 化学动力学分析 层流燃烧速度 层流燃烧速度 掺氢甲烷 掺氢甲烷 火焰 火焰 爆炸压力 爆炸压力
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GB/T 7714 | 梅亮 , 郭进 , 黄时凯 et al. 密闭容器内氢气‑甲烷‑空气的爆炸特性 [J]. | 含能材料 , 2025 : 1-12 . |
MLA | 梅亮 et al. "密闭容器内氢气‑甲烷‑空气的爆炸特性" . | 含能材料 (2025) : 1-12 . |
APA | 梅亮 , 郭进 , 黄时凯 , 王金贵 , 高毅 . 密闭容器内氢气‑甲烷‑空气的爆炸特性 . | 含能材料 , 2025 , 1-12 . |
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在自主设计的长度和内径均为25 cm的圆柱形容器中,开展了不同掺氢比(x)的氢气-甲烷-空气泄爆实验.实验结果表明:X对容器内部超压有显著影响,容器内共出现三类压力峰值(p1、p2、p3).p1是泄放速率超过了燃烧产物生成率导致的,并出现在x<0.9的实验中,其幅值几乎不受x的影响;P2由声学振荡产生并且出现在0.45≤x≤0.9的实验中;p3是火焰燃烧面积达到最大值产生,仅出现在X=1的情况下.声学振荡造成的超压峰值随着x单调增加,在发生声学振荡时,火焰表面会出现周期性的细小胞格,并且声学振荡的频率与细小胞格出现的频率相近.X<0.3时,容器内只存在一个压力峰值p1;X>0.3时,容器内最大超压随着x单调增加.x>0.15时,外部爆炸的最大超压也随着x的增加而增加.
Keyword :
声学振荡 声学振荡 外部爆炸 外部爆炸 掺氢比 掺氢比 火焰传播 火焰传播 爆炸超压 爆炸超压
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GB/T 7714 | 王昊哲 , 郭进 , 吴佳晗 et al. 掺氢比对氢气-甲烷-空气燃爆特性的影响 [J]. | 工程热物理学报 , 2025 , 46 (2) : 669-678 . |
MLA | 王昊哲 et al. "掺氢比对氢气-甲烷-空气燃爆特性的影响" . | 工程热物理学报 46 . 2 (2025) : 669-678 . |
APA | 王昊哲 , 郭进 , 吴佳晗 , 张瀚文 , 张苏 . 掺氢比对氢气-甲烷-空气燃爆特性的影响 . | 工程热物理学报 , 2025 , 46 (2) , 669-678 . |
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In this study, experiments were conducted in a 1 m -long horizontal rectangular duct at an initial temperature of 285 K and an initial pressure of 100 kPa to investigate the influence of ignition position and hydrogen fraction (x) on the vented deflagration of NH3/H-2/air. A range of x from 0.1 to 0.9, as well as three ignition positions, including FI (front ignition), CI (central ignition), and RI (rear ignition), were employed. It was indicated that the ignition position and x remarkably influenced on the overpressure accumulation and flame evolution inside and outside the duct. With x increasing from 0.1 to 0.9, the maximum explosion overpressure (p(max)) and the maximum external overpressure increased with x at three ignition positions. As x increased from 0.1 to 0.9, p(max) increased from 7 kPa to 22 kPa at FI, from 13 kPa to 50 kPa at CI, and from 13 kPa to 33 kPa at RI. With x increasing from 0.1 to 0.9, the maximum external overpressure increased from 0.15 kPa to 4 kPa in the case of FI, from 0.43 kPa to 16.36 kPa in the case of CI, and from 1 kPa to 35.58 kPa in the case of RI. Left flame front deformation owing to R -T instability was found and was the most severe at FI. In rear ignition explosions, the flame always propagates toward the opening end as x > 0.5, but when x <= 0.5, the flame front may transiently move away from the opening. In the case of RI, the shape of the external combustible cloud transferred from a "mushroom" to a "dumbbell" as x increased from 0.5 to 0.9. Two types of oscillations (Helmholtz -type and acoustic oscillations) could be found. As x increased from 0.3 to 0.7, the Helmholtz -type oscillations could be easily distinguished in the cases of FI and CI. As x increased from 0.3 to 0.7, the frequency of Helmholtz -type oscillations increased from 125 Hz at x = 0.3-140 Hz at x = 0.5-150 Hz at x = 0.7 in the case of FI and from 135 Hz at x = 0.3-160 Hz at x = 0.5-170 Hz at x = 0.7 in the case of CI. Acoustic oscillations could only be observed in tests with x >= 0.7 and were the most intense when x = 0.7.
Keyword :
Flame Flame Ignition position Ignition position NH 3 /H 2 /air deflagration NH 3 /H 2 /air deflagration Overpressure Overpressure Pressure oscillation Pressure oscillation
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GB/T 7714 | Huang, Shikai , Guo, Jin , Mei, Liang et al. Study on the deflagrations of NH3/H2/air in an end-open duct: Effects of ignition position and hydrogen fraction [J]. | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY , 2024 , 60 : 55-65 . |
MLA | Huang, Shikai et al. "Study on the deflagrations of NH3/H2/air in an end-open duct: Effects of ignition position and hydrogen fraction" . | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 60 (2024) : 55-65 . |
APA | Huang, Shikai , Guo, Jin , Mei, Liang , Yang, Zexuan . Study on the deflagrations of NH3/H2/air in an end-open duct: Effects of ignition position and hydrogen fraction . | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY , 2024 , 60 , 55-65 . |
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Although ammonia-hydrogen blended fuel has become a research hotspot, it is essential to recognize that adding hydrogen to ammonia increases the potential explosion hazard before considering the development of ammoniahydrogen fuel. In this study, the effect of vent area on vented deflagrations of ammonia-hydrogen-air mixtures is investigated in a 1-m-long horizontal rectangular duct with a right end opening at an initial temperature of 293 K and an initial pressure of 101 kPa. A dimensionless vent coefficient K-v is used to define the vent area in this work to clarify the evolution of flame structures and overpressure inside and outside the duct. For a specific K-v, the amplitude of the maximum internal explosion overpressure (P-max) monitored at the left end of the duct (LE) has a greater difference compared with other pressure monitoring points. The maximum amplitude of P(max )is always reached at the LE for K-v <= 3.2, while the difference in the maximum amplitude of P(max )between different monitoring points decreased significantly for K-v > 3.2. With the increasing of K(v )from 2.2 to 20.1, P(max )obtained at the right end of the duct (RE) and the center of the duct increases monotonously, but P(max )monitored at the LE shows a non-monotonic increasing trend. A spike structure of penetrating flame bubbles resulting from negative pressure balance is only observed inside the duct for K-v <= 5.6. Two types of oscillations (Helmholtz and Acoustic oscillations) can be distinguished in some tests, and only acoustic oscillations of overpressure can be clearly found in tests with K-v > 7.8. With the increasing of K(v )from 2.2 to 20.1, the shape of the external fireball will change significantly. As Kv increases from 2.2 to 5.6, the external fireball shapes are always mushroom-shaped. However, the shapes of the fireball become elongated for K-v > 7.8, and even the external fireball presents a jet shape for K-v = 20.1. With the increasing of K-v from 2.2 to 20.1, The maximum external overpressure increases first, thereafter decreases, and finally increases.
Keyword :
Ammonia-hydrogen-air mixtures Ammonia-hydrogen-air mixtures External explosion External explosion Flame behavior Flame behavior Overpressure Overpressure Vent area Vent area
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GB/T 7714 | Huang, Shikai , Guo, Jin , Mei, Liang et al. Effect of vent area on vented ammonia-hydrogen-air deflagrations in a 1-m-long duct [J]. | FUEL , 2024 , 362 . |
MLA | Huang, Shikai et al. "Effect of vent area on vented ammonia-hydrogen-air deflagrations in a 1-m-long duct" . | FUEL 362 (2024) . |
APA | Huang, Shikai , Guo, Jin , Mei, Liang , Yang, Zexuan , Wang, Hongyan , Li, Yiming . Effect of vent area on vented ammonia-hydrogen-air deflagrations in a 1-m-long duct . | FUEL , 2024 , 362 . |
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To investigate the microwave heating mechanism of composite minerals, a circumferential stirring model based on the Arbitrary Lagrangian-Eulerian (ALE) method was established by COMSOL Multiphysics software. This model aims to study the temperature rise characteristics of mineral models with different component structures and proportions. The results show that the heating efficiency and uniformity of the mineral are higher in the stirred heating model with a 5 cm copper disc rotating at (π/3) rad/s compared to the non-stirred heating model; The different component structures of the composite mineral result in different electromagnetic wave distributions, which induces the microwave heating efficiency of the py-rite-enclosed calcite model is lower than the calcite-enclosed pyrite model; In the calcite-en-closed pyrite model, the variation of pyrite thickness changes the phase of electromagnetic wave, leading to the displacement of hot and cold spots in the mineral. Furthermore, when comparing the pyrite thicker and thinner than the penetration depth, there is a significant disparity in the incident electromagnetic wave intensity, resulting in noticeable differences in electric field strength; At the same component proportion, the overall electric field of heterogeneous minerals is lower and more stable, and the electric field intensity between components is closer than in composite homogeneous minerals; With the proportion of pyrite increases, the temperature variation of heterogeneous minerals after 30 s microwave heating can be divided into three regions: small peak region (0-10%), large peak region (10% - 50%), and stable region (50% - 75%), and the temperature differences between components gradually decrease. © 2024 China University of Mining and Technology. All rights reserved.
Keyword :
Calcite Calcite Circular waveguides Circular waveguides Efficiency Efficiency Electric fields Electric fields Electromagnetic waves Electromagnetic waves Microwave heating Microwave heating Mining Mining Pyrites Pyrites
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GB/T 7714 | Long, Shengyi , Hong, Yidu , Sun, Xiaowan et al. Microwave heating temperature rise characteristics of composite minerals under the circumferential stirring model [J]. | Journal of China University of Mining and Technology , 2024 , 53 (2) : 318-333 . |
MLA | Long, Shengyi et al. "Microwave heating temperature rise characteristics of composite minerals under the circumferential stirring model" . | Journal of China University of Mining and Technology 53 . 2 (2024) : 318-333 . |
APA | Long, Shengyi , Hong, Yidu , Sun, Xiaowan , Yang, Fuqiang , Guo, Jin , Nie, Wen . Microwave heating temperature rise characteristics of composite minerals under the circumferential stirring model . | Journal of China University of Mining and Technology , 2024 , 53 (2) , 318-333 . |
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Although ammonia as a carbon-free fuel is regarded as an energy source worthy of significant development, how to address the shortcomings of its poor combustion properties has been a hot topic of research. Hydrogen enrichment is a promising solution to improve the combustion properties of ammonia, but at the same time, the potential explosion risk will inevitably be raised. In this paper, the effects of hydrogen volumetric fraction (chi) in NH3/H-2 on the NH3/H-2/air deflagrations were experimentally investigated in a rectangular duct with an end-opening at an initial pressure and temperature of 101 kPa and 298 K, where chi was varied from 0.1 to 0.9. Results demonstrate that flame propagation and overpressure profiles inside and outside the chamber depend on chi. Buoyancy plays a significant role in flame propagation at chi = 0.1. More prominent deformation of the flame front propagating toward the closed end (CE) was observed in the experiments with higher chi s. Helmholtz oscillations of the flame occurred in all tests, which resulted in pressure oscillations with a decreasing frequency as chi was increased. Acoustically enhanced combustion of NH3/H-2/air remained at the CE, appeared when chi >= 0.7, and acoustic-type oscillations of the internal explosion overpressure and a pressure peak of p(2) formed in these tests. The amplitude of p(2) dropped as chi varied from 0.7 to 0.9. A proportional relationship between the highest explosion overpressure inside the chamber (p(max)) and the square of the laminar burning velocity of NH3/H-2/air (s(l)(2)). When chi >= 0.3, a dominant pressure peak (p(ext)) caused by the external explosion appeared in the external overpressure profiles, and its amplitude increased as chi varied from 0.3 to 0.9.
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GB/T 7714 | Huang, Shikai , Guo, Jin , Mei, Liang et al. Experiments on the Vented Ammonia-Hydrogen-Air Deflagrations under Various Hydrogen Volume Fractions [J]. | ENERGY & FUELS , 2024 , 38 (10) : 9110-9119 . |
MLA | Huang, Shikai et al. "Experiments on the Vented Ammonia-Hydrogen-Air Deflagrations under Various Hydrogen Volume Fractions" . | ENERGY & FUELS 38 . 10 (2024) : 9110-9119 . |
APA | Huang, Shikai , Guo, Jin , Mei, Liang , Yang, Zexuan . Experiments on the Vented Ammonia-Hydrogen-Air Deflagrations under Various Hydrogen Volume Fractions . | ENERGY & FUELS , 2024 , 38 (10) , 9110-9119 . |
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In this study, the effects of hydrogen concentration (C) and vent size (AV) on the vented H2/air explosion in an obstructed duct were investigated using experimental methods and FLACS simulation software at an initial pressure and temperature of 101 kPa and 291K, respectively. A vent coefficient KA is chosen to represent AV to illustrate its influence on the explosion venting of H2/air. The results demonstrate that the maximum internal overpressure (pmax) and the maximum external overpressure (pext) increase and then decrease with C increasing from 10% to 60%. The highest pmax and pext are reached at C = 35% in experiments, but achieved at C = 30% in simulations because incomplete chemical reactions were not taken into account. In the tests with C <50%, the flame evolution inside the duct includes five stages: spherical flame, elliptical flame, finger-shaped flame, near-planar flame, and tulip-shaped flame. No tulip flame is observed for C ≥50%. FLACS can simulate the flame structure evolution for various C, but it cannot accurately simulate the flame propagation speed. FLACS overestimates the flame propagation speed in the tests with C ≤25%, but underestimates the flame propagation speed for C ≥35%. Under the initial condition of C = 15%, the above-mentioned five stages of flame evolution can be simulated by FLACS for KA ≤0.4; however, neither the near-plane nor tulip flame is observed in simulations for KA >0.4. © 2024
Keyword :
Flame propagation Flame propagation Hydrogen Hydrogen Overpressure Overpressure Pressure oscillations Pressure oscillations Vented explosion Vented explosion
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GB/T 7714 | Wang, F. , Huang, S. , Xu, C. et al. Experimental and numerical study on vented H2/air explosion in an obstructed duct: Effects of hydrogen concentration and vent size [J]. | International Journal of Hydrogen Energy , 2024 . |
MLA | Wang, F. et al. "Experimental and numerical study on vented H2/air explosion in an obstructed duct: Effects of hydrogen concentration and vent size" . | International Journal of Hydrogen Energy (2024) . |
APA | Wang, F. , Huang, S. , Xu, C. , Wang, C. , Guo, J. , Lin, J. . Experimental and numerical study on vented H2/air explosion in an obstructed duct: Effects of hydrogen concentration and vent size . | International Journal of Hydrogen Energy , 2024 . |
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The effects of the vent burst pressure (Pv) on the vented explosion of hydrogen-methane-air mixtures are investigated in a cylindrical vessel connected with a duct. The results demonstrate that Pv significantly affects the flame behaviors and overpressure inside and outside the venting configuration. The flame front velocity at the vent increases with Pv. Two pressure peaks, Pac, caused by the acoustically enhanced combustion, and Pse, caused by the secondary explosion, dominate within the vessel at Pv < 132 kPa and Pv >= 132 kPa, respectively. The maximum overpressure (Pmax) inside the duct increases with Pv. The maximum pressure rise (dp/dt) of the duct is always higher than that of the vessel. As Pv increases, increased turbulence of unburned gases within the duct results in higher dp/dt. Exit flame speed increases with Pv. When Pv >= 153 kPa, "Mach disk" appears outside the relief duct. Three pressure peaks, Pa, Pb, and Pext, due to vent failure, the secondary explosion, and the external explosion, respectively, occur in the external pressure curve. Pb dominates outside the configuration except for Pv = 153 kPa.
Keyword :
Duct-vented explosion Duct-vented explosion Explosion overpressure Explosion overpressure Hydrogen/methane/air mixture Hydrogen/methane/air mixture Reverse flow Reverse flow Vent burst pressure Vent burst pressure
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GB/T 7714 | Yang, Zexuan , Wang, Fang , Xu, Caijun et al. Effects of the vent burst pressure on the duct-vented explosion of hydrogen-methane-air mixtures [J]. | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY , 2024 , 67 : 776-785 . |
MLA | Yang, Zexuan et al. "Effects of the vent burst pressure on the duct-vented explosion of hydrogen-methane-air mixtures" . | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 67 (2024) : 776-785 . |
APA | Yang, Zexuan , Wang, Fang , Xu, Caijun , Guo, Jin , Mei, Liang , Huang, Shikai . Effects of the vent burst pressure on the duct-vented explosion of hydrogen-methane-air mixtures . | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY , 2024 , 67 , 776-785 . |
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Explosion venting is the most commonly used technique to reduce the hazard from accidental deflagration of combustible gases. Since less attention is paid to the influence of inertial vent on vented H2/CH4/air deflagration, the effects of area density (Ws) of a hinged inertial cover on the pressure profile and flame behavior during H2/ CH4/air deflagration, with hydrogen volume fraction in fuel (chi H2) being 0.5 and 0.8, were investigated by covering the vent using aluminum plates with various thicknesses. The results show that the interval between ignition and the moment the flame just travels through the vent (tout) is almost independent of Ws, but the opening angle of the panel at the time of tout is closely related to Ws. For a given chi H2, the opening angle at the time of tout decreases with an increase in Ws. For a certain Ws, the opening angle of the panel is smaller for chi H2 = 0.8 in comparison with the tests at chi H2 = 0.5. In the test with higher Ws, the external fireball becomes more flattened. In tests at chi H2 = 0.5, p3 induced by acoustic oscillations dominates the internal overpressure, but p2 resulting from the external explosion becomes the dominant pressure peak at chi H2 = 0.8. The maximum reduced overpressure (pred) and maximum external overpressure (pext) are almost independent of Ws at chi H2 = 0.5. However, in tests at chi H2 = 0.8, pred and pext increase sharply with an increase in Ws from 0 kg/m2 to 2.7 kg/m2, but there is relatively little variation in pred and pext as Ws continues to increase from 2.7 kg/m2 to 24.3 kg/m2. Except for the test with Ws = 0 kg/m2, for a specific Ws, pred and pext at chi H2 = 0.8 are always greater than those at chi H2 = 0.5.
Keyword :
Flame Flame Hinged vent panel Hinged vent panel Hydrogen/methane/air explosion Hydrogen/methane/air explosion Overpressure Overpressure
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GB/T 7714 | Guo, Jin , Huang, Shikai , Wang, Fang et al. Effects of area density of a hinged inertial cover on H2/CH4/air deflagrations in a vented chamber [J]. | FUEL , 2024 , 374 . |
MLA | Guo, Jin et al. "Effects of area density of a hinged inertial cover on H2/CH4/air deflagrations in a vented chamber" . | FUEL 374 (2024) . |
APA | Guo, Jin , Huang, Shikai , Wang, Fang , Xu, Caijun , Wu, Zelong , Zhang, Fan et al. Effects of area density of a hinged inertial cover on H2/CH4/air deflagrations in a vented chamber . | FUEL , 2024 , 374 . |
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