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学者姓名:黄国城
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The global need for clean water and sanitation drives the development of eco-friendly and efficient water treatment technologies to combat biological pollution from pathogens. In this study, a novel heterojunction photocatalyst was synthesized by incorporating ZnIn2S4 into covalent organic frameworks (COFs) to enable environmentally friendly hydrogen peroxide (H2O2) photosynthesis and explore its potential for in situ disinfection. The ZnIn2S4/COF photocatalyst achieved remarkable H2O2 yields of 1325 mu mol center dot g-(1)center dot h-(1), surpassing pristine COF and ZnIn2S4 by factors of 3.12 and 16.2, respectively. The produced H2O2 was efficiently activated into hydroxyl radicals (OH) through reaction with Fe(II), enabling rapid sterilization via a photocatalysis-self-Fenton system. Mechanistic insights, supported by physicochemical characterizations and theoretical calculations, highlighted the role of the internal electric field (IEF) in enhancing carrier separation and transfer, thereby boosting photosynthesis efficiency. This work presents a sustainable approach to H2O2 photosynthesis and activation for disinfection, offering a promising solution to global water treatment challenges.
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GB/T 7714 | Zhuo, Linlin , Dong, Shaofeng , Sham, Yik Tung et al. Internal electric field steering S-scheme charge transfer in ZnIn2S4/COF boosts H2O2 photosynthesis from water and air for sustainable disinfection [J]. | NPJ CLEAN WATER , 2025 , 8 (1) . |
MLA | Zhuo, Linlin et al. "Internal electric field steering S-scheme charge transfer in ZnIn2S4/COF boosts H2O2 photosynthesis from water and air for sustainable disinfection" . | NPJ CLEAN WATER 8 . 1 (2025) . |
APA | Zhuo, Linlin , Dong, Shaofeng , Sham, Yik Tung , Zhang, Jinpeng , Xu, Xiaoying , Ho, Kenrick Chun Kiu et al. Internal electric field steering S-scheme charge transfer in ZnIn2S4/COF boosts H2O2 photosynthesis from water and air for sustainable disinfection . | NPJ CLEAN WATER , 2025 , 8 (1) . |
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Covalent triazine frameworks (CTFs) are emerging as promising platform for photocatalysis, yet their highly symmetric structure leads to significant charge recombination. Herein, we employed a facile non-metallic boron (B) modification with precisely controlled doping site to introduce asymmetric local electron distribution in CTFs, achieving a 15-fold activity enhancement for CO2-to-CH4 conversion. Calculations including frontier orbitals, dipole moments and molecular electrostatic potentials firmly demonstrated the formation of localized polarized electron regions in CTF-1 via B doping. Noteworthily, the primary coordination-activation site for CO2 molecules shifted from triazine ring to benzene ring, with increased adsorption energy (-0.21 vs. -0.55 eV) and a reduced CO2 bond angle (156 degrees vs. 139 degrees). Furthermore, the CO2-to-CH4 pathway was thoroughly clarified based upon the in-situ DRIFTS and energy barriers calculations, where CTF-1 followed the formate route and B-doped CTF utilized the water gas shift reaction. The introduction of B doping lowered energy barrier of *CHO formation for improving CH4 selectivity. This study offers a strategy for enhancing product selectivity by breaking the electronic symmetry of photocatalysts.
Keyword :
Asymmetric electronic distribution Asymmetric electronic distribution Boron doping Boron doping CO2 reduction CO2 reduction Covalent triazine frameworks Covalent triazine frameworks Photocatalysis Photocatalysis
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GB/T 7714 | Chen, Shaokui , Huang, Guiting , Sheng, Hao et al. Asymmetric electronic distribution induced enhancement in photocatalytic CO2-to-CH4 conversion via boron-doped covalent triazine frameworks [J]. | JOURNAL OF COLLOID AND INTERFACE SCIENCE , 2025 , 685 : 766-773 . |
MLA | Chen, Shaokui et al. "Asymmetric electronic distribution induced enhancement in photocatalytic CO2-to-CH4 conversion via boron-doped covalent triazine frameworks" . | JOURNAL OF COLLOID AND INTERFACE SCIENCE 685 (2025) : 766-773 . |
APA | Chen, Shaokui , Huang, Guiting , Sheng, Hao , Huang, Guocheng , Sa, Rongjian , Chen, Qiaoshan et al. Asymmetric electronic distribution induced enhancement in photocatalytic CO2-to-CH4 conversion via boron-doped covalent triazine frameworks . | JOURNAL OF COLLOID AND INTERFACE SCIENCE , 2025 , 685 , 766-773 . |
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The carrier transfer mechanism of S-scheme heterojunctions has been extensively explored, yet their impact on light absorption performance remains ambiguous. In this work, a finely designed S-scheme heterojunction was developed by coupling oxidation photocatalyst a specific covalent organic framework (COF)-TaTp, and reduction photocatalyst SnS2 (SS) for in-situ H2O2 photo-production and sterilization. The optimized 10% SS/TaTp achieved a 3.45- and 16.87-fold enhancement in H2O2 generation than pure TaTp and SS, respectively, with significant improvements under visible and near-infrared (NIR) light. In-situ XPS, EPR, and Kelvin probe force microscopy (KPFM) verified the S-scheme charge transfer mechanism, underscoring accelerated photo-induced electrons migration and strengthened redox capacity. The internal electric field of 10% SS/TaTp was calculated to be 2.14 and 4.63 times stronger than TaTp and SS. Intriguingly, the electron localization function and partial density of states analyses revealed that the interfacial C-N-S covalent bonds finely tuned the energy band structure and generated hybrid energy levels in the heterojunction, thus improving light harvesting and catalytic performance in both visible-light and NIR region. This work highlights the role of interfacial covalent interactions in tuning energy levels in COF-based S-scheme photocatalysts.
Keyword :
Covalent organic frameworks Covalent organic frameworks Hybrid energy levels Hybrid energy levels In-situ activation In-situ activation Photocatalytic H 2 O 2 production Photocatalytic H 2 O 2 production S -scheme heterojunction S -scheme heterojunction
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GB/T 7714 | Xu, Xiaoying , Dong, Shaofeng , Lv, Jialong et al. Interfacial C-N-S bridged SnS2/COF S-scheme heterojunction with upgraded near-infrared photo-activity for H2O2 synthesis [J]. | APPLIED SURFACE SCIENCE , 2025 , 689 . |
MLA | Xu, Xiaoying et al. "Interfacial C-N-S bridged SnS2/COF S-scheme heterojunction with upgraded near-infrared photo-activity for H2O2 synthesis" . | APPLIED SURFACE SCIENCE 689 (2025) . |
APA | Xu, Xiaoying , Dong, Shaofeng , Lv, Jialong , Huang, Guocheng , Chen, Qiaoshan , Bi, Jinhong . Interfacial C-N-S bridged SnS2/COF S-scheme heterojunction with upgraded near-infrared photo-activity for H2O2 synthesis . | APPLIED SURFACE SCIENCE , 2025 , 689 . |
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Bioelectrocatalysis presents a promising strategy for sustainable nitrogen (N2) fixation to ammonia (NH3), yet the interplay between conductive materials and extracellular polymeric substances (EPS) in biofilms remains underexplored. Here, we demonstrate that boron carbide (B4C900) synergizes with EPS to optimize bioelectrocatalytic nitrogen fixation in Pseudomonas stutzeri A1501. The addition of B4C900 enhanced NH3 production by 164.41 %, driven by a 38 % increase in tightly bound EPS secretion and elevated electron-accepting (0.076 +/- 0.004 mu mol e-) and electron-donating capacities (0.017 +/- 0.001 mu mol e- ). Transcriptomic analyses revealed B4C900-mediated upregulation of riboflavin and cytochrome c biosynthesis pathways within EPS, enriching redox-active mediators critical for electron shuttling. Concurrently, B4C900's intrinsic conductivity facilitated direct electron transport across the abiotic-biotic interface. This dual mechanism-enhancing EPSmediated redox activity and establishing conductive electron transfer pathways-effectively reduced interfacial resistance and upregulated energy metabolism genes, including those associated with ATP synthase and the tricarboxylic acid (TCA) cycle. Our findings establish EPS as a pivotal mediator in conductive material-driven systems, offering a blueprint for efficient N2-to-NH3 conversion and advancing bioelectrocatalytic design principles.
Keyword :
Bioelectrocatalysis Bioelectrocatalysis Boron carbide Boron carbide Extracellular electron transfer Extracellular electron transfer Extracellular polymeric substances Extracellular polymeric substances Redox activity Redox activity
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GB/T 7714 | Li, Lei , Wang, Chao , Hong, Mingqiu et al. Conductive substance as game-changer in mediating bioelectrocatalytic nitrogen fixation: The crucial role of extracellular polymeric substances [J]. | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING , 2025 , 13 (3) . |
MLA | Li, Lei et al. "Conductive substance as game-changer in mediating bioelectrocatalytic nitrogen fixation: The crucial role of extracellular polymeric substances" . | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING 13 . 3 (2025) . |
APA | Li, Lei , Wang, Chao , Hong, Mingqiu , Chen, Piao , Huang, Guocheng , Gu, Wenzhi et al. Conductive substance as game-changer in mediating bioelectrocatalytic nitrogen fixation: The crucial role of extracellular polymeric substances . | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING , 2025 , 13 (3) . |
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Designing photocatalysts with well-defined structure-function relationships is imperative for propelling the progression of desired photocatalytic oxidation. Herein, the efficient conversion of solar energy to H2O2 and subsequently to hydroxyl radicals (•OH) is achieved through a synergistic interplay between olefin linkage (-C[dbnd]C-) and spatially separated benzene-triazine dual reaction sites within covalent organic frameworks (COFs). The upgraded -C[dbnd]C- can increase the conjugation degree of COFs, which establishes an expanded superstructure for boosting charge separation/transfer and stability. This precise modulation renders more opportunities for the hot electrons to migrate to the benzene site for solar-to-H2O2 generation, and to the triazine site for H2O2-to-•OH, separately. The optimized •OH generation pathway enables remarkable oxidation performances against recalcitrant organic pollutants, and pathogenic microorganisms under visible light irradiation. This work provides new insights for tuning the synergistic interactions of various building blocks within the COFs for the selective generation of highly reactive •OH for environmental remediation. © 2024 Elsevier B.V.
Keyword :
Benzene Benzene Hot electrons Hot electrons Microorganisms Microorganisms Organic pollutants Organic pollutants Solar energy Solar energy
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GB/T 7714 | Zhang, Jinpeng , Huang, Guocheng , Chen, Qiaoshan et al. Upgrading structural conjugation in covalent organic framework with spatial dual sites enables boosting solar-to-H2O2-to-•OH for environmental remediation [J]. | Applied Catalysis B: Environmental , 2024 , 356 . |
MLA | Zhang, Jinpeng et al. "Upgrading structural conjugation in covalent organic framework with spatial dual sites enables boosting solar-to-H2O2-to-•OH for environmental remediation" . | Applied Catalysis B: Environmental 356 (2024) . |
APA | Zhang, Jinpeng , Huang, Guocheng , Chen, Qiaoshan , Wu, Ling , Li, Liuyi , Bi, Jinhong . Upgrading structural conjugation in covalent organic framework with spatial dual sites enables boosting solar-to-H2O2-to-•OH for environmental remediation . | Applied Catalysis B: Environmental , 2024 , 356 . |
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Tetracycline (TC) antibiotics, extensively utilized in livestock farming and aquaculture, pose significant environmental challenges. Photocatalysis, leveraging renewable sunlight and reusable photocatalysts, offers a promising avenue for mitigating TC pollution. However, identifying robust photocatalysts remains a formidable challenge. This study introduces a novel hollow -flower -ball -like nanoheterojunction composed of a nitrogen -rich covalent organic framework (N-COF) coupled with BiOBr (BOB), a semiconductor with a higher Fermi level. The synthesized N-COF/BOB S -scheme nanoheterojunction features an expanded contact interface, strengthened chemical bonding, and unique band topologies. The N-COF/BOB composites showcased exceptional TC degradation performance, achieving an 81.2% removal of 60 mg/L TC within 2 h, markedly surpassing the individual efficiencies of N-COF and BOB by factors of 3.80 and 5.96, respectively. Furthermore, the total organic carbon (TOC) removal efficiency highlights a superior mineralization capacity in the N-COF/BOB composite compared to the individual components, N-COF and BOB. The toxicity assessment revealed that the degradation intermediates possess diminished environmental toxicity. This enhanced performance is ascribed to the robust Sscheme nanoheterojunction structure, which promotes efficient photoinduced electron transfer from BOB to NCOF. This process also augments the separation of photogenerated charge carriers, resulting in an increased yield of superoxide radicals (center dot O2 ) and hydroxyl radicals (center dot OH). These reactive species significantly contribute to the degradation and mineralization of TC. Consequently, this study introduces a sustainable approach for addressing emerging antibiotic contaminants, employing COF-based photocatalysts.
Keyword :
Antibiotics Antibiotics Covalent organic frameworks Covalent organic frameworks Photocatalytic degradation Photocatalytic degradation S -scheme heterojunction S -scheme heterojunction Tetracycline Tetracycline
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GB/T 7714 | Bi, Jinhong , Zhang, Zhangtong , Tian, Jinjin et al. Interface engineering in a nitrogen-rich COF/BiOBr S-scheme heterojunction triggering efficient photocatalytic degradation of tetracycline antibiotics [J]. | JOURNAL OF COLLOID AND INTERFACE SCIENCE , 2024 , 661 : 761-771 . |
MLA | Bi, Jinhong et al. "Interface engineering in a nitrogen-rich COF/BiOBr S-scheme heterojunction triggering efficient photocatalytic degradation of tetracycline antibiotics" . | JOURNAL OF COLLOID AND INTERFACE SCIENCE 661 (2024) : 761-771 . |
APA | Bi, Jinhong , Zhang, Zhangtong , Tian, Jinjin , Huang, Guocheng . Interface engineering in a nitrogen-rich COF/BiOBr S-scheme heterojunction triggering efficient photocatalytic degradation of tetracycline antibiotics . | JOURNAL OF COLLOID AND INTERFACE SCIENCE , 2024 , 661 , 761-771 . |
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The treatment of emerging contaminants is essential but challenging. Herein, a novel MOF/PAN fibrous composite (TCPP@UiO-66/PAN) was synthesized and used as a self-cleaning membrane for the efficient removal of a typical emerging contaminant, diclofenac sodium (DF). The introduction of the secondary linker tetra(4carboxyphenyl)porphyrin (TCPP) served to expand the pores and enhance its photocatalytic activity. TCPP@UiO-66/PAN shows higher adsorption capacity and initial adsorption rate than UiO-66/PAN. The maximum adsorption capacity of DF on TCPP@UiO-66/PAN reached 202 mg/g by Langmuir model. The DF adsorption mechanism involves the pi-pi/anion-pi interaction, Lewis acid-base interaction, and hydrogen bonding. Based on the dynamic filtration experiment, TCPP@UiO-66/PAN exhibited a remarkable treatment capacity for DF-contaminated water, measuring 3.75 x 104 kg/kg. Given its fibrous membrane structure, TCPP@UiO-66/ PAN could be easily separated from water and reused. In-situ photo-regeneration emerged as a highly effective method for regenerating TCPP@UiO-66/PAN after reaching adsorption saturation, with over 95 % DF degradation achieved under sunlight irradiation. The decomposition of DF primarily resulted from the generation of h+ and 1O2. Additionally, TCPP@UiO-66/PAN exhibited notable antibacterial properties when exposed to visible light. In vitro cytotoxicity assessments further confirmed the safety of these MOF/PAN composites. Combining the advantages of hybrid-linker strategy and fibrous composite, this work provided new insight into constructing MOF-based functional material for wastewater purification.
Keyword :
Adsorption Adsorption Emerging contaminants Emerging contaminants Fibrous composites Fibrous composites Metal -organic frameworks Metal -organic frameworks Self-cleaning Self-cleaning
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GB/T 7714 | Gao, Yanxin , Cheng, Ting , Zhao, Fankang et al. A hybrid linker-MOF fibrous composite for efficient diclofenac removal and self-cleaning [J]. | SEPARATION AND PURIFICATION TECHNOLOGY , 2024 , 337 . |
MLA | Gao, Yanxin et al. "A hybrid linker-MOF fibrous composite for efficient diclofenac removal and self-cleaning" . | SEPARATION AND PURIFICATION TECHNOLOGY 337 (2024) . |
APA | Gao, Yanxin , Cheng, Ting , Zhao, Fankang , Huang, Guocheng , Bi, Jinhong . A hybrid linker-MOF fibrous composite for efficient diclofenac removal and self-cleaning . | SEPARATION AND PURIFICATION TECHNOLOGY , 2024 , 337 . |
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The serious combination of abundant electrons/holes in bulk primarily hinders the efficiency in the photocatalytic reaction. It is crucial to control the spatial charge dynamics through delicately designing the crystal configuration of photocatalyst. In this work, a modified tungsten trioxide nanosheet colloid (M-WO3) was synthesized by an ion exchange method. Compared to pristine WO3 (P-WO3), the crystal lattice vibration frequency of M-WO3 increases from 2.8 meV to 4.3 meV, which effectively prohibits electron-phonon coupling and powerfully accelerates the separation and transfer of photoinduced charge carriers. Irradiated by visible-light, M-WO3 shows much higher photocatalytic bacterial inactivation performance than P-WO3. In addition, this regulation method increases the surface charges of the WO3 colloid to improve its stability, which endows this colloid photocatalyst with broad prospects in practical photocatalytic antibacterial applications. This work offers guidance to construct efficiently separated photoinduced electron/hole pairs of the colloid photocatalyst by designing its crystal structure.
Keyword :
Colloid photocatalyst Colloid photocatalyst Colloid stability Colloid stability Crystal lattice vibration frequency Crystal lattice vibration frequency Photocatalytic disinfection Photocatalytic disinfection WO(6)octahedra distortion WO(6)octahedra distortion
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GB/T 7714 | Qiu, Chengwei , Liu, Zhihua , Rao, Qin et al. Prohibiting the electron-phonon coupling effect in tungsten trioxide nanosheet colloid with enhanced photocatalytic antibacterial capacity [J]. | JOURNAL OF COLLOID AND INTERFACE SCIENCE , 2024 , 678 : 1135-1147 . |
MLA | Qiu, Chengwei et al. "Prohibiting the electron-phonon coupling effect in tungsten trioxide nanosheet colloid with enhanced photocatalytic antibacterial capacity" . | JOURNAL OF COLLOID AND INTERFACE SCIENCE 678 (2024) : 1135-1147 . |
APA | Qiu, Chengwei , Liu, Zhihua , Rao, Qin , Yang, Hui , He, Yuxin , Li, Dongmiao et al. Prohibiting the electron-phonon coupling effect in tungsten trioxide nanosheet colloid with enhanced photocatalytic antibacterial capacity . | JOURNAL OF COLLOID AND INTERFACE SCIENCE , 2024 , 678 , 1135-1147 . |
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Designing photocatalysts with well-defined structure-function relationships is imperative for propelling the progression of desired photocatalytic oxidation. Herein, the efficient conversion of solar energy to H2O2 and subsequently to hydroxyl radicals (center dot OH) is achieved through a synergistic interplay between olefin linkage (-C = C-) and spatially separated benzene-triazine dual reaction sites within covalent organic frameworks (COFs). The upgraded -C = C- can increase the conjugation degree of COFs, which establishes an expanded superstructure for boosting charge separation/transfer and stability. This precise modulation renders more opportunities for the hot electrons to migrate to the benzene site for solar-to-H2O2 generation, and to the triazine site for H2O2-to-center dot OH, separately. The optimized center dot OH generation pathway enables remarkable oxidation performances against recalcitrant organic pollutants, and pathogenic microorganisms under visible light irradiation. This work provides new insights for tuning the synergistic interactions of various building blocks within the COFs for the selective generation of highly reactive center dot OH for environmental remediation.
Keyword :
Covalent organic frameworks Covalent organic frameworks H2O2 activation H2O2 activation Hydroxyl radicals Hydroxyl radicals Photocatalysis Photocatalysis Spatial dual sites Spatial dual sites
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GB/T 7714 | Zhang, Jinpeng , Huang, Guocheng , Chen, Qiaoshan et al. Upgrading structural conjugation in covalent organic framework with spatial dual sites enables boosting solar-to-H2O2-to-•OH for environmental remediation [J]. | APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY , 2024 , 356 . |
MLA | Zhang, Jinpeng et al. "Upgrading structural conjugation in covalent organic framework with spatial dual sites enables boosting solar-to-H2O2-to-•OH for environmental remediation" . | APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY 356 (2024) . |
APA | Zhang, Jinpeng , Huang, Guocheng , Chen, Qiaoshan , Wu, Ling , Li, Liuyi , Bi, Jinhong . Upgrading structural conjugation in covalent organic framework with spatial dual sites enables boosting solar-to-H2O2-to-•OH for environmental remediation . | APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY , 2024 , 356 . |
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Semiconductor-based solar-driven CO2 to fuels has been widely reckoned as an ingenious approach to tackle energy crisis and climate change simultaneously. However, the high carrier recombination rate of the photocatalyst severely dampens their photocatalytic uses. Herein, an inorganic-organic heterojunction was constructed by in-situ growing a dioxin-linked covalent organic framework (COF) on the surface of rod-shaped beta-Ga2O3 for solar-driven CO2 to fuel. This novel heterojunction is featured with an ultra-narrow bandgap COF-318 (absorption edge = 760 nm), which is beneficial for fully utilizing the visible light spectrum, and a wide bandgap beta-Ga2O3 (absorption edge = 280 nm) to directional conduct electrons from COF to reduce CO2 without electron-hole recombination occurred. Results showed that the solar to fuels performance over beta-Ga2O3/COF was much superb than that of COF. The optimized Ga2O3/COF achieved an outstanding CO evolution rate of 85.8 mu mol h(-1).g(-1) without the need of any sacrificial agent or cocatalyst, which was 15.6 times more efficient than COF. Moreover, the analyses of photoluminescence electrochemical characterizations and density functional theory (DFT) calculations revealed that the fascinate construction of beta-Ga2O3/COF heterojunction significantly favored charge separation and the directional transfer of photogenerated electrons from COF to beta-Ga2O3 followed by CO2. This study paves the way for developing effective COF-based semiconductor photocatalysts for solar-to-fuel conversion.
Keyword :
beta-Ga2O3 beta-Ga2O3 CO2 reduction CO2 reduction Covalent organic framework Covalent organic framework Narrow-wide bandgap heterojunction Narrow-wide bandgap heterojunction
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GB/T 7714 | Yang, Rong , Chen, Qiaoshan , Huang, Guocheng et al. Interfacial engineering of novel inorganic-organic beta-Ga2O3/COF heterojunction for accelerated charge transfer towards artificial photosynthesis [J]. | ENVIRONMENTAL RESEARCH , 2023 , 216 . |
MLA | Yang, Rong et al. "Interfacial engineering of novel inorganic-organic beta-Ga2O3/COF heterojunction for accelerated charge transfer towards artificial photosynthesis" . | ENVIRONMENTAL RESEARCH 216 (2023) . |
APA | Yang, Rong , Chen, Qiaoshan , Huang, Guocheng , Bi, Jinhong . Interfacial engineering of novel inorganic-organic beta-Ga2O3/COF heterojunction for accelerated charge transfer towards artificial photosynthesis . | ENVIRONMENTAL RESEARCH , 2023 , 216 . |
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